Criteria

Text:
Display:

Results

Viewing 1 to 30 of 247
Technical Paper
2014-10-13
Brian C. Kaul, Benjamin J. Lawler, Charles E.A. Finney, Michelle L. Edwards, Robert M. Wagner
Advances in engine controls and sensor technology are making advanced, direct, high-speed control of engine combustion more feasible. Control of combustion rate and phasing in low-temperature combustion regimes and active control of cyclic variability in dilute SI combustion are being pursued in laboratory environments with high-quality data acquisition systems, using metrics calculated from in-cylinder pressure. In order to implement these advanced combustion controls in production, lower-quality data will need to be tolerated even if indicated pressure sensors are made available. This paper examines the effects of several data quality issues, including phase shifting (incorrect TDC location), reduced data resolution, pressure pegging errors, and random noise on calculated combustion metrics that are used for control feedback. Combustion phasing, mean effective pressure, and cycle-total heat release are considered. Symbolic data analysis has been shown to be an effective technique for identifying underlying patterns in noisy data, and has been applied to cyclic variability of dilute SI combustion, identifying deterministic effects that underlie the stochastic variations that are present.
Technical Paper
2014-10-13
John Thomas
Vehicle manufacturers among others are putting great emphasis on improving fuel economy (FE) of light-duty vehicles in the U.S. market, with significant FE gains being realized in recent years. The U.S. Environmental Protection Agency (EPA) data indicates that the aggregate FE of vehicles produced for the U.S. market has improved by 20% from model year (MY) 2005 to 2013. This steep climb in FE includes changes in vehicle choice, improvements in engine and transmission technology, and reducing aerodynamic drag, rolling resistance, and parasitic losses. The powertrain related improvements focus on optimizing in-use efficiency of the transmission and engine as a system, and may make use of what is termed downsizing and/or downspeeding. This study explores quantifying recent improvements in powertrain efficiency, viewed separately from other vehicle alterations and attributes (noting that most vehicle changes are not completely independent). A methodology is outlined to estimate powertrain efficiency for the U.S city and highway cycle tests using data from the EPA vehicle database.
Technical Paper
2014-09-30
Zhiming Gao, Charles Finney, Charles Daw, Tim J. LaClair, David Smith
Two hybrid powertrain configurations, including parallel and series hybrids, were simulated for fuel economy, component energy loss, and emissions control in Class 8 trucks over both city and highway driving conditions. A comprehensive set of component models describing engine fuel consumption, emissions control, battery energy, and accessory power demand interactions was developed and integrated with the simulated hybrid trucks to identify heavy-duty (HD) hybrid technology barriers. The results show that series hybrid is absolutely negative for fuel-economy improvement of long-haul trucks due to an efficiency penalty associated with the dual-step conversions of energy (i.e. mechanical to electric to mechanical). The current parallel hybrid technology combined with 50% auxiliary load reduction could improve fuel economy by 5-7% in long-haul trucks, but a profound improvement of long-haul truck fuel economy requires innovative technologies for reducing aerodynamic drag and rolling resistance.
Article
2014-06-26
The Department of Energy’s Oak Ridge National Laboratory (ORNL) has launched its new Institute for Functional Imaging of Materials, which aims to accelerate discovery, design, and deployment of new materials, according to a release from the laboratory.
Article
2014-05-04
A new electrolyte developed the U.S. Department of Energy's Oak Ridge National Laboratory (ORNL) serves not only as an ion conductor, but also as a cathode supplement in batteries. Potential uses of the technology include remote keyless entry systems, cardiac pacemakers, sensors, and other applications "where replacing or recharging a battery is not possible or desirable."
Technical Paper
2014-04-01
Michael D. Kass, Mark W. Noakes, Brian Kaul, Dean Edwards, Timothy Theiss, Lonnie Love, Ryan Dehoff, John Thomas
Abstract The performance of a 4cc two-stroke single cylinder glow plug engine was assessed at wide open throttle for speeds ranging from 2000 to 7000RPM. The engine performance was mapped for the stock aluminum head and one composed of titanium, which was printed using additive manufacturing. The engine was mounted to a motoring dynamometer and the maximum torque was determined by adjusting the fuel flow. Maximum torque occurred around 3000 to 3500RPM and tended to be higher when using the aluminum head. At slower speeds, the titanium head produced slightly higher torque. For each test condition, maximum torque occurred at leaner conditions for the titanium head compared to the stock aluminum one. Higher efficiencies were observed with the aluminum head for speeds greater than 3000RPM, but the titanium heads provided better efficiency at the lower speed points. The titanium head was equipped with an in-cylinder pressure sensor and the combustion performance was assessed at maximum torque for speeds of 4000, 6000, and 7000RPM.
Technical Paper
2014-04-01
Jan-Mou Li, David Smith
Abstract Driver is a key component in vehicle simulation. An ideal driver model simulates driving patterns a human driver may perform to negotiate road profiles. There are simulation packages having the capability to simulate driver behavior. However, it is rarely documented how they work with road profiles. This paper proposes a new truck driver model for vehicle simulation to imitate actual driving behavior in negotiating road grade and curvature. The proposed model is developed based upon Gipps' car-following model. Road grade and curvature were not considered in the original Gipps' model although it is based directly on driver behavior and expectancy for vehicles in a stream of traffic. New parameters are introduced to capture drivers' choice of desired speeds that they intend to use in order to negotiating road grade and curvature simultaneously. With the new parameters, the proposed model can emulate behaviors like uphill preparation for different truck drivers. Speed variation while cruising can be explained by the empirical model and therefore facilitating a better estimation of performance in vehicle simulation.
Technical Paper
2014-04-01
Jing Dong, Zhenhong Lin, Changzheng Liu, Yanghe Liu
Abstract This paper utilizes GPS tracked multiday travel activities to estimate the temporal distribution of electricity loads and assess battery electric vehicle (BEV) grid impacts at a significant market penetration level. The BEV load and non-PEV load vary by time of the day and day of the week. We consider two charging preferences: home priority assumes BEV drivers prefer charging at home and would not charge at public charging stations unless the state of charge (SOC) of the battery is not sufficient to cover the way back to home; and charging priority does not require drivers to defer charging to home and assumes drivers will utilize the first available charging opportunity. Both home and charging priority scenarios show an evening peak demand. Charging priority scenario also shows a morning peak on weekdays, possibly due to workplace charging. Assuming a significant percentage of the vehicle population in Seattle is displaced by BEVs, the BEV electricity demand is added to the non-PEV load.
Technical Paper
2014-04-01
Zhenhong Lin, Jan-Mou Li, Jing Dong
Abstract This study attempts to establish a quantitative linkage between deployment of dynamic wireless power transfer (DWPT) and the market adoption of plug-in electric vehicles (PEV). This linkage can be useful for analyzing the societal benefits of DWPT and justifying investments in its research, development, demonstration and deployment. Spatial relationships between charging opportunity and DWPT availability are estimated for four metropolitan areas. The consumer value of DWPT is formulated as a function of key DWPT deployment parameters and then integrated into an existing validated consumer choice model, where sales of PEVs are endogenous. Results indicate significant impacts on PEV sales of DWPT deployment, even only at 0.5% of road length by 2050. Significant impact heterogeneity is observed. Larger impacts appear to be on battery electric vehicles (BEV) as opposed to plug-in hybrid electric vehicles (PHEV), on short-range BEVs as opposed to long-range ones, and on consumers with charging challenges, such as consumers without adequate home or workplace charging and consumers with high driving intensity.
Technical Paper
2014-04-01
Adam Dempsey, Scott Curran, John Storey, Mary Eibl, Josh Pihl, Vitaly Prikhodko, Robert Wagner, James Parks
Abstract Low temperature combustion (LTC) has been shown to yield higher brake thermal efficiencies with lower NOx and soot emissions, relative to conventional diesel combustion (CDC). However, while demonstrating low soot carbon emissions it has been shown that LTC operation does produce particulate matter whose composition appears to be much different than CDC. The particulate matter emissions from dual-fuel reactivity controlled compression ignition (RCCI) using gasoline and diesel fuel were investigated in this study. A four cylinder General Motors 1.9L ZDTH engine was modified with a port-fuel injection system while maintaining the stock direct injection fuel system. The pistons were modified for highly premixed operation and feature an open shallow bowl design. RCCI operation was carried out using a certification grade 97 research octane gasoline and a certification grade diesel fuel. To study the particulate matter emissions from RCCI operation, particle size distributions were measured with a Scanning Mobility Particle Sizer (SMPS) and total particulate concentration in the exhaust was determined using membrane filters.
Technical Paper
2014-04-01
Krishna Kamasamudram, Ashok Kumar, Jinyong Luo, Neal Currier, Aleksey Yezerets, Thomas Watkins, Larry Allard
Abstract An operational challenge associated with SCR catalysts is the NH3 slip control, particularly for commercial small pore Cu-zeolite formulations as a consequence of their significant ammonia storage capacity. The desorption of NH3 during increasing temperature transients is one example of this challenge. Ammonia slipping from SCR catalyst typically passes through a platinum based ammonia oxidation catalyst (AMOx), leading to the formation of the undesired byproducts NOx and N2O. We have discovered a distinctive characteristic, an overlapping NH3 desorption and oxidation, in a state-of-the-art Cu-zeolite SCR catalyst that can minimize NH3 slip during temperature transients encountered in real-world operation of a vehicle. In this work we show new insights, gained from NH3 temperature programmed desorption and oxidation experiments, into the Cu-zeolite catalyst functions responsible for the overlap of NH3 desorption and oxidation characteristics and the impact of hydrothermal treatment on these functions.
Technical Paper
2014-04-01
Sujit Das
Advanced lightweight materials are increasingly being incorporated into new vehicle designs by automakers to enhance performance and assist in complying with increasing requirements of corporate average fuel economy standards. To assess the primary energy and carbon dioxide equivalent (CO2e) implications of vehicle designs utilizing these materials, this study examines the potential life cycle impacts of two lightweight material alternative vehicle designs, i.e., steel and aluminum of a typical passenger vehicle operated today in North America. LCA for three common alternative lightweight vehicle designs are evaluated: current production (“Baseline”), an advanced high strength steel and aluminum design (“LWSV”), and an aluminum-intensive design (AIV). This study focuses on body-in-white and closures since these are the largest automotive systems by weight accounting for approximately 40% of total curb weight of a typical passenger vehicle. Secondary mass savings resulting from body lightweighting are considered for the vehicles' engine, driveline and suspension.
Technical Paper
2014-04-01
John Thomas, Shean Huff, Brian West
To quantify the fuel economy (FE) effect of some common vehicle accessories or alterations, a compact passenger sedan and a sport utility vehicle (SUV) were subjected to SAE J2263 coastdown procedures. Coastdowns were conducted with low tire pressure, all windows open, with a roof top or hitch-mounted cargo carrier, and with the SUV pulling an enclosed cargo trailer. From these coastdowns, vehicle dynamometer coefficients were developed which enabled the execution of vehicle dynamometer experiments to determine the effect of these changes on vehicle FE and emissions over standard drive cycles and at steady highway speeds. In addition, two minivans were subjected to coastdowns to examine the similarity in derived coefficients for two duplicate vehicles of the same model. The FE penalty associated with the rooftop cargo box mounted on the compact sedan was as high as 25-27% at higher speeds, where the aerodynamic drag is most pronounced. For both vehicles, use of a hitch mounted cargo tray carrying a similar load resulted in very small FE penalties, unlike the rooftop cargo box.
Technical Paper
2014-04-01
Zhiming Gao, Tim J. LaClair, C. Stuart Daw, David E. Smith, Oscar Franzese
We present simulated fuel economy and emissions of city transit buses powered by conventional diesel engines and diesel-hybrid electric powertrains of varying size. Six representative city drive cycles were included in the study. In addition, we included previously published aftertreatment device models for control of CO, HC, NOx, and particulate matter (PM) emissions. Our results reveal that bus hybridization can significantly enhance fuel economy by reducing engine idling time, reducing demands for accessory loads, exploiting regenerative braking, and shifting engine operation to speeds and loads with higher fuel efficiency. Increased hybridization also tends to monotonically reduce engine-out emissions, but tailpipe (post-aftertreatment) emissions are affected by complex interactions between engine load and the transient catalyst temperatures, and the emissions results were found to depend significantly on motor size and details of each drive cycle.
Technical Paper
2014-04-01
Vitaly Y. Prikhodko, James E. Parks, Josh A. Pihl, Todd J. Toops
A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at λ=0.96 for nearly all conditions studied. At the λ=0.96 condition, HC emissions were relatively minimal, but CO emissions were significant. Operation at AFRs richer than λ=0.96 did not provide more NH3 yield and led to higher HC and CO emissions.
Technical Paper
2014-04-01
Michael D. Kass, Timothy Theiss, Steve Pawel, James Baustian, Les Wolf, Wolf Koch, Chris Janke
The compatibility of elastomeric materials used in fuel storage and dispensing applications was determined for test fuels representing neat gasoline and gasoline blends containing 10 and 17 vol.% ethanol, and 16 and 24 vol.% isobutanol. The actual test fuel chemistries were based on the aggressive formulations described in SAE J1681 for oxygenated gasoline. Elastomer specimens of fluorocarbon, fluorosilicone, acrylonitrile rubber (NBR), polyurethane, neoprene, styrene butadiene rubber (SBR) and silicone were exposed to the test fuels for 4 weeks at 60°C. After measuring the wetted volume and hardness, the specimens were dried for 20 hours at 60°C and then remeasured for volume and hardness. Dynamic mechanical analysis (DMA) was also performed to determine the glass transition temperature (Tg). Comparison to the original values showed that all elastomer materials experienced volume expansion and softening when wetted by the test fuels. The fluorocarbons underwent the least amount of swelling (<25 %) while the SBR and silicone samples exhibited the highest level of expansion (>100%).
Technical Paper
2014-04-01
Michael D. Kass, Chris Janke, Timothy Theiss, Steve Pawel, James Baustian, Les Wolf, Wolf Koch
The compatibility of plastic materials used in gasoline storage and dispensing applications was determined for test fuels representing neat gasoline (Fuel C), and blends containing 25% ethanol (CE25a), 16% isobutanol (CiBu16a), and 24% isobutanol (CiBu24a). A solubility analysis was also performed and compared to the volume swell results obtained from the test fuel exposures. The plastic specimens were exposed to each test fuel for16 weeks at 60°C. After measuring the wetted volume and hardness, the specimens were dried for 65 hours at 60°C and then remeasured for volume and hardness. Dynamic mechanical analysis (DMA), which measures the storage modulus as a function of temperature, was also performed on the dried specimens to determine the temperature associated with the onset of the glass-to-rubber transition (Tg). For many of the plastic materials, the solubility analysis was able to predict the relative volume swell for each test fuel. Those plastic materials commonly used as permeation barriers exhibited the least amount of volume and hardness change (<5%) when exposed to the test fuels.
Technical Paper
2014-04-01
Aaron Williams, Robert McCormick, Michael Lance, Chao Xie, Todd Toops, Rasto Brezny
Small impurities in the fuel can have a significant impact on the emissions control system performance over the lifetime of the vehicle. Of particular interest in recent studies has been the impact of sodium, potassium, and calcium that can be introduced either through fuel constituents, such as biodiesel, or as lubricant additives. In a collaboration between the National Renewable Energy Laboratory and the Oak Ridge National Laboratory, a series of accelerated aging studies have been performed to understand the potential impact of these metals on the emissions control system. This paper explores the effect of the rate of accelerated aging on the capture of fuel-borne metal impurities in the emission control devices and the subsequent impact on performance. Aging was accelerated by doping the fuel with high levels of the metals of interest. Three separate evaluations were performed, each with a different rate of accelerated aging. The aged emissions control systems were evaluated through vehicle testing and then dissected for a more complete analysis of the devices.
Technical Paper
2014-04-01
John M. Storey, Sam Lewis, James Szybist, John Thomas, Teresa Barone, Mary Eibl, Eric Nafziger, Brian Kaul
Gasoline direct injection (GDI) engines can offer improved fuel economy and higher performance over their port fuel-injected (PFI) counterparts, and are now appearing in increasingly more U.S. and European vehicles. Small displacement, turbocharged GDI engines are replacing large displacement engines, particularly in light-duty trucks and sport utility vehicles, in order for manufacturers to meet more stringent fuel economy standards. GDI engines typically emit the most particulate matter (PM) during periods of rich operation such as start-up and acceleration, and emissions of air toxics are also more likely during this condition. A 2.0 L GDI engine was operated at lambda of 0.91 at typical loads for acceleration (2600 rpm, 8 bar BMEP) on three different fuels; an 87 anti-knock index (AKI) gasoline (E0), 30% ethanol blended with the 87 AKI fuel (E30), and 48% isobutanol blended with the 87 AKI fuel. E30 was chosen to maximize octane enhancement while minimizing ethanol-blend level and iBu48 was chosen to match the same fuel oxygen level as E30.
Technical Paper
2014-04-01
C. Scott Sluder, Brian H. West, Aron D. Butler, Arvon L. Mitcham, William J. Ruona
During the 1980s, the U.S. Environmental Protection Agency (EPA) incorporated the R factor into fuel economy calculations in order to address concerns about the impacts of test fuel property variations on corporate average fuel economy (CAFE) compliance, which is determined using the Federal Test Procedure (FTP) and Highway Fuel Economy Test (HFET) cycles. The R factor is defined as the ratio of the percent change in fuel economy to the percent change in volumetric heating value for tests conducted using two differing fuels. At the time the R-factor was devised, tests using representative vehicles initially indicated that an appropriate value for the R factor was 0.6. Reassessing the R factor has recently come under renewed interest after EPA's March 2013 proposal to adjust the properties of certification gasoline to contain significant amounts of ethanol. This proposed change will likely result in a significant deviation from the CAFE baseline test fuel heating value, and thus increased importance of the R factor.
Technical Paper
2014-04-01
Forrest Jehlik, Tim Laclair
Response surface methodology (RSM) techniques were applied to develop a predictive model of electric vehicle (EV) energy consumption over the Environmental Protection Agency's (EPA) standardized drive cycles. The model is based on measurements from a synthetic composite drive cycle. The synthetic drive cycle is a minimized statistical composite of the standardized urban (UDDS), highway (HWFET), and US06 cycles. The composite synthetic drive cycle is 20 minutes in length thereby reducing testing time of the three standard EPA cycles by over 55%. Vehicle speed and acceleration were used as model inputs for a third order least squared regression model predicting vehicle battery power output as a function of the drive cycle. The approach reduced three cycles and 46 minutes of drive time to a single test of 20 minutes. Application of response surface modeling to the synthetic drive cycle is shown to predict energy consumption of the three EPA cycles within 2.6% of the actual measured values.
Technical Paper
2014-01-15
Matthew Langholtz, Mark Downing, Robin Graham, Fred Baker, Alicia Compere, William Griffith, Raymond Boeman, Martin Keller
Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%. Using lignin-derived carbon fiber in 15 million vehicles per year in the US could reduce fossil fuel consumption by 2-5 billion liters year−1, reduce CO2 emissions by about 6.7 million Mg year−1, and realize fuel savings through vehicle lightweighting of $700 to $1,600 per Mg biomass processed.
Article
2013-08-29
Scientists at the U.S. Department of Energy's Oak Ridge National Laboratory have developed a new oxygen "sponge" that can easily absorb or shed oxygen atoms at low temperatures. Materials with these novel characteristics would be useful in devices such as rechargeable batteries, sensors, gas converters, and fuel cells.
Article
2013-06-10
Oak Ridge National Laboratory (ORNL) is preparing to open a Vehicle Systems Integration Laboratory in July, with a focus on powertrain. Manufacturers will be able to test different designs under real-world conditions, which helps save time and cost. 
Article
2013-04-17
The lab runs fuel-economy tests with A/C on maximum vs. A/C "comfort level," A/C-off and with windows open and closed. Some results are surprising, including an unexpected "crossover" point in testing on a Toyota Corolla.
Technical Paper
2013-04-08
Zhiming Gao, C. Stuart Daw, David E. Smith
We summarize results from comparative simulations of hybrid electric vehicles with either stoichiometric gasoline or diesel engines. Our simulations utilize previously published models of transient engine-out emissions and models of aftertreatment devices for both stoichiometric and lean exhaust. Fuel consumption and emissions were estimated for comparable gasoline and diesel light-duty hybrid electric vehicles operating over single and multiple urban drive cycles. Comparisons between the gasoline and diesel vehicle fuel consumptions and emissions were used to identify potential advantages and technical barriers for diesel hybrids.
Technical Paper
2013-04-08
Brian West, C. Scott Sluder
Automobile manufacturers strive to minimize oil consumption from their engines due to the need to maintain emissions compliance over the vehicle life. Engine oil can contribute directly to organic gas and particle emissions as well as accelerate emissions degradation due to catalyst poisoning. During the Department of Energy Intermediate Ethanol Blends Catalyst Durability program, vehicles were aged using the Standard Road Cycle (SRC). In this program, matched sets of three or four vehicles were acquired; each vehicle of a set was aged on ethanol-free retail gasoline, or the same base gasoline blended with 10, 15, or 20% ethanol (E0, E10, E15, E20). The primary purpose of the program was to assess any changes in tailpipe emissions due to the use of increased levels of ethanol. Oil consumption was tracked during the program so that any measured emissions degradation could be appropriately attributed to fuel use or to excessive oil consumption. In addition, excessive oil consumption was used to help diagnose potential engine maintenance problems.
Technical Paper
2013-04-08
Aaron Williams, Jonathan Burton, Robert L. McCormick, Todd Toops, Andrew A. Wereszczak, Ethan E. Fox, Michael J. Lance, Giovanni Cavataio, Douglas Dobson, Jim Warner, Rasto Brezny, K. Nguyen, D. William Brookshear
Alkali and alkaline earth metal impurities found in diesel fuels are potential poisons for diesel exhaust catalysts. Using an accelerated aging procedure, a set of production exhaust systems from a 2011 Ford F250 equipped with a 6.7L diesel engine have been aged to an equivalent of 150,000 miles of thermal aging and metal exposure. These exhaust systems included a diesel oxidation catalyst (DOC), selective catalytic reduction (SCR) catalyst, and diesel particulate filter (DPF). Four separate exhaust systems were aged, each with a different fuel: ULSD containing no measureable metals, B20 containing sodium, B20 containing potassium and B20 containing calcium. Metals levels were selected to simulate the maximum allowable levels in B100 according to the ASTM D6751 standard. Analysis of the aged catalysts included Federal Test Procedure emissions testing with the systems installed on a Ford F250 pickup, bench flow reactor testing of catalyst cores, and electron probe microanalysis (EPMA).
Technical Paper
2013-04-08
Michael J. Lance, John Storey, C. Scott Sluder, Harry Meyer III, Brad Watkins, Michele Kaiser, Ponnaiyan Ayyappan
Exhaust gas recirculation (EGR) cooler fouling has become a significant issue for compliance with NOX emissions standards and has negative impacts on cooler sizing and engine performance. In order to improve our knowledge of cooler fouling as a function of engine operating parameters and to predict and enhance performance, 19 tube-in-shell EGR coolers were fouled using a 5-factor, 3-level design of experiments with the following variables: (1) EGR flow rate, (2) EGR inlet gas temperature, (3) coolant temperature, (4) soot level, and (5) hydrocarbon concentration. A 9-liter engine and ULSD fuel were used to form the cooler deposits. Coolers were run until the effectiveness stabilized, and then were cooled down to room temperature and run for an additional few hours in order to measure the change in effectiveness due to shut down. The coolers were cut open and the mass per unit area of the deposit was measured as a function of distance down the tube. Microstructural analysis revealed that the deposit mass and thickness were generally lowest both at the cooler outlet and on the upstream side of the turbulators for all the coolers.
Technical Paper
2013-04-08
Maruthi Devarakonda, Jong Lee, George Muntean, Josh Pihl, Stuart Daw
Urea-selective catalytic reduction (SCR) catalysts are the leading aftertreatment technology for diesel engines, but there are major challenges associated with meeting future NO x emission standards, especially under transient drive cycle conditions that include large swings in exhaust temperatures. Here we present a simplified, transient, one-dimensional integral model of NO x reduction by NH₃ on a commercial small-pore Cu-zeolite urea-SCR catalyst for which detailed kinetic parameters have not been published. The model was developed and validated using data acquired from bench reactor experiments on a monolith core, following a transient SCR reactor protocol. The protocol incorporates NH₃ storage, NH₃ oxidation, NO oxidation and three global SCR reactions under isothermal conditions, at three space velocities and at three NH₃/NO x ratios. NH₃ storage parameters were obtained from separate TPD experiments and were used in the individual kinetic models to identify the rate parameters of various SCR reaction pathways.
Viewing 1 to 30 of 247

Filter

  • Range:
    to:
  • Year: