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Technical Paper

Next Generations of Gasoline Particulate Filters for Catalyzed Applications

2024-04-09
2024-01-2384
Gasoline particulate filters (GPF) have become a standard aftertreatment component in Europe, China, and since recently, India, where particulate emissions are based on a particle number (PN) standard. The anticipated evolution of regulations in these regions towards future EU7, CN7, and BS7 standards further enhances the needs with respect to the filtration capabilities of the GPFs used. Emission performance has to be met over a broader range in particle size, counting particles down to 10nm, and over a broader range of boundary conditions. The requirements with respect to pressure drop, aiming for as low as possible, and durability remain similar or are also enhanced further. To address these future needs new filter technologies have been developed. New technologies for uncatalyzed GPF applications have been introduced in our previous publications.
Technical Paper

Three Way Catalyst with Faster Light-Off Substrates – A Promising Approach to Reduce Tailpipe Emissions

2024-01-16
2024-26-0142
The ever-tightening regulation norms across the world emphasize the magnitude of the air pollution problem. The decision to leapfrog from BS4 to BS6 – with further reduction in emission limits -showed India’s commitment to clean up its atmosphere. The overall cycle emissions were reduced significantly to meet BS6 targets [1]. However, the introduction of RDE norms in BS6.2 [1] demanded further reduction in emissions under real time operating conditions – start-stop, hard acceleration, idling, cold start – which was possible only through strategies that demanded a cost effective yet robust solutions. The first few seconds of the engine operation after start contribute significantly to the cycle gaseous emissions. This is because the thermal inertia of the catalytic converter restricts the rate at which temperature of the catalyst increases and achieves the desired “light-off” temperature.
Technical Paper

GPF: An Effective Technology to Minimize Two Wheeler (2Wh) Particulate Emission

2024-01-16
2024-26-0140
India is the world’s largest two-wheeler (2Wh) market. With the proportion of its middle class rapidly rising, 2Wh sales and the resulting emissions, are expected to grow exponentially. The decision to leap-frog from BSIV to BSVI emission norms shows India’s commitment to clean up its atmosphere. As of now, the regulation mandates Gaseous Pollutant (CO, HC, NOx) emission limits for all 2Whs and a particulate limit (PM & PN) for 2Whs powered by Direct Injection (DI) engines. Most of the 2Whs manufactured in India are powered by gasoline engines using the Port Fuel Injection (PFI) technology, and hence by definition particulate emission limits do not apply to them. Particulates when inhaled - especially of the ultrafine sizes capable of entering the blood stream - pose a serious health risk. This was the primary motivation to investigate the particulate emission levels of the 2Whs, which as on date, do not come under the purview of BSVI regulation.
Technical Paper

Impact from a variety of E10 and E20 gasoline formulations on PN10 and PN23 emissions evaluated in combination with advanced GPF technology generations

2023-09-29
2023-32-0028
The study was aimed at assessing the impact of fuel quality on the PN10 and PN23 emissions. A total of 6 fuels having different level of ethanol, renewable components, additives, and aromatic hydrocarbons were tested on the test vehicle. In the first phase of the study, the emission tests were conducted removing the GPF present in the original aftertreatment system to measure the direct impact of different fuels on the tailpipe particle emissions. The emission results showed that heavy aromatics components lead to a significant increase in particle emissions while the fuel with renewable components and E20 emit less PN comparing to the E10 reference fuel. However, those fuel impacts became very small with a GPF present due to a high filtration efficiency independent of fuel type.
Technical Paper

Challenges and Solutions to Meeting Eu VII Particle Number Requirements during Aggressive Field Operation

2023-04-11
2023-01-0386
The heavy duty (HD) Eu VII regulations, going into effect starting 2027, has aggressive particle number (PN) emissions limits under extended operating conditions compared to existing Eu VI framework. In addition to the proposed hot-start PN limit of 2.0E+11 #/kWh, which is a >65% reduction vs. Eu VI E, the particle size cut-off is being extended from 23nm+ to 10nm+ while also including nearly all field operating conditions such as regeneration events, wider ambient boundaries etc. The tighter limits coupled with a work-based window approach to evaluate emissions is driving the need for the next generation of ultra-high filtration efficiency (FE), diesel particulate filter (DPF) technologies. The current study evaluates the FE performance of different DPF solutions under development, over a range of challenging on-road conditions characterized by frequent high temperature events which are not actively triggered.
Technical Paper

Sub-23nm Particle Emissions from China6 Gasoline Vehicles over Various Driving Cycles

2023-04-11
2023-01-0395
Sub-23nm particles emission from the light-duty vehicle is widely discussed now and possible to be counted into the next stage emission legislation, such as Euro7. In this article, 16 China6 gasoline vehicles were tested over the WLTC and two surrogate RDE lab cycles for particulate number (PN) emission, the difference between PN23 (particle size >23nm) and PN10 (particle size>10nm) emission was analyzed. Testing results showed that the average PN10 emission increased 59% compared to PN23, which will bring great challenges for those vehicles to meet the future regulation requirement if sub-23nm particle is counted. The sub-23nm particles emission was proportional to the PN23 particles emission and generated mostly from the cold start or the transient engine conditions with rich combustion. Compared to the proposal of Euro 7, PN10 emission from some tested vehicles will need further two orders of magnitude reduction.
Technical Paper

Challenges of Particulate Number above 10nm Emissions for a China 6 Compliant Vehicle to Meet Future Regulation

2023-04-11
2023-01-0377
As the official proposal for emission regulation Euro 7 has been released by European Commission, PN above 10nm is taken into consideration for the ultrafine particulate emissions control. The challenges of GPF filtration efficiency emerge for the light-duty manufactures to meet the future emission standards. In the present study, a China 6 compliant vehicle was tested to reveal its performance over the China 6 standards and potential to meet the upcoming Euro 7. Three GPF product types (Gen 1, Gen 2, and concept Gen 3) were mounted to the tested vehicle. WLTC tests were conducted on chassis dynamometer in laboratory as well as a self-designed aggressive cycle (“Base Cycle”) tests. To explore the GPFs performance for PN emissions above 10nm against the proposed limit 6.0E11 #/km, PN emission above 10nm were measured in our laboratory tests for both engine out and tailpipe as well as the PN emission above 23nm.
Technical Paper

Validation Test on a Light Duty Vehicle Equipped with a GDI Engine to Meet China 6b RDE Regulation for PN

2022-08-30
2022-01-1020
China 6 (CN6) emission legislation for light duty vehicles was published in 2016, which introduced real driving emissions (RDE) requirements for new type-approval content. Nitrogen oxides (NOx) and particle number (PN) of RDE test are required to be monitored and reported from July 2020 in CN6a phase, fulfilled from July 2023 in CN6b phase. To meet the PN limitation of CN6 RDE, the optimized engine combustion and advanced emission control system like gasoline particle filter (GPF) are encouraged. Compared to traditional vehicle platform emission compliance which could be done in lab, much more vehicle development and validation efforts are expected on the open road for RDE compliance. High cost and complexity are expected to conduct a complete validation test matrix covering all the RDE critical boundary conditions on the open road.
Journal Article

Next Generation Gasoline Particulate Filters for Uncatalyzed Applications and Lowest Particulate Emissions

2021-04-06
2021-01-0584
With the introduction of EU6d and CN6 all vehicles with gasoline direct injection and many with port fuel injection engine will be equipped with a gasoline particulate filter (GPF). A range of first generation filter technologies has been introduced successfully, helping to significantly reduce the tailpipe particulate number emissions. The continued focus on particulate emissions and the increasing understanding of their impact on human health, combined with the advanced emission regulations under RDE conditions results in the desire for filters with even higher filtration efficiency, especially in the totally fresh state. At the same time, to balance with the requirements on power and CO2, limitations exist with respect to the tolerable pressure drop of filters. In this paper we will report on a new generation of gasoline particulate filters for uncatalyzed applications.
Technical Paper

Cost Effective Catalyst Solutions with Application of Low Mass Substrate to Meet China 6b Regulation Requirement

2021-04-06
2021-01-0581
With upcoming China 6b emission regulation set for full implementation in July 2023, significant efforts are being made within China OEMs to meet the stringent gaseous emission requirements, which reduce gaseous emission limits by 29 to 50% from China 6a for NOx, THC, and CO over the worldwide harmonized light-duty test cycle (WLTC). With current engine and aftertreatment technology, cold-start emissions generated in the first 200 seconds of the WLTC typically makes up most of the total tailpipe emissions result, thus the reduction of cold-start emissions becomes vital to meet regulation requirements. Besides further improvement on engine technology with optimized calibration, a common method to improve cold-start performance is to add more platinum group metals (PGM) into three-way catalyst (TWC). An alternative approach to improve cold-start performance involves using a low mass substrate to enable faster heat up of the TWC.
Technical Paper

Soot Load Monitoring in Gasoline Particulate Filter Applications with RF-Sensors

2020-09-15
2020-01-2171
With the start of Euro 6d regulations, gasoline particulate filters (GPF) have become standard equipment in European vehicles with gasoline-direct-injection engines. GPFs will also be broadly applied to meet the upcoming China 6 regulations. An existing challenge with GPFs is accurate soot load detection to manage the pressure loss across the exhaust system and to protect the GPFs from soot overload, which could potentially cause damage as result of uncontrolled soot oxidations. Systems with the GPF located in the under-floor position have a higher potential risk of soot overload due to lower temperatures, which can result in higher soot accumulation rates. The accuracy of existing soot estimation methods such as evaluation of the pressure drop of the soot-loaded GPF or model-based balancing of soot accumulation versus soot oxidation rates are sensitive to transient operating condition of a vehicle.
Technical Paper

Coated Gasoline Particulate Filter Technology Development to Meet China6 PN Regulation

2020-04-14
2020-01-0387
With the introduction of stringent particulate number (PN) limits and real driving emission (RDE) requirements, gasoline particulate filters (GPFs) have been widely adopted in Europe and China. GPFs can be coated with different amounts of three-way catalyst (TWC) coating. Some applications use large amounts of washcoat (>100g/L) whereas some don’t use at all. Pressure drop (DP) and PN filtration efficiency (FE) are the top two design criteria. It is important to understand how various coating technologies can be applied to GPF technologies for optimized FE/DP performance. To study filter and coating interaction, a matrix of coated GPFs was prepared and tested for lab DP and vehicle PN based FE. The matrix includes samples with a wide range of washcoat loadings (WCLs), differing coating technologies that target more coating inside GPF filter walls (Tech A) or more on the surface of filter walls (Tech B), and GPF technologies with high and low mean pore size (MPS).
Journal Article

Analysis of the Emission Conversion Performance of Gasoline Particulate Filters Over Lifetime

2019-09-09
2019-24-0156
Gasoline particulate filters (GPF) recently entered the market, and are already regarded a state-of-the-art solution for gasoline exhaust aftertreatment systems to enable EU6d-TEMP fulfilment and beyond. Especially for coated GPF applications, the prognosis of the emission conversion performance over lifetime poses an ambitious challenge, which significantly influences future catalyst diagnosis calibrations. The paper presents key-findings for the different GPF application variants. In the first part, experimental GPF ash loading results are presented. Ash accumulates as thin wall layers and short plugs, but does not penetrate into the wall. However, it suppresses deep bed filtration of soot, initially decreasing the soot-loaded backpressure. For the emission calibration, the non-linear backpressure development complicates the soot load monitoring, eventually leading to compromises between high safety against soot overloading and a low number of active regenerations.
Technical Paper

On-Vehicle Fuel Cut Testing for Gasoline Particulate Filter Applications

2019-04-02
2019-01-0968
With the introduction of a stringent particulate number (PN) limit and real driving emission (RDE) requirements, gasoline particulate filters (GPF) are widely adopted for gasoline engines in Europe and China. The filter collects soot and ash. Like in diesel applications, the collected soot will continuously burn under favorable exhaust conditions. However, at extreme conditions, there could be large amounts of soot build-up, which may induce a highly exothermal event, potentially damaging the filter. Thus, it is important to understand what drives the over-heating in application, and develop counter measures. In this study, an on-vehicle fuel cut (FC) testing procedure was developed. The testing was conducted on two vehicles, one gasoline direct injection (GDI) vehicle and one multiple port injection (MPI) vehicle, with different exhaust systems designs (a close coupled GPF and an under floor GPF) and catalyst coating levels (bare and heavily coated GPFs).
Technical Paper

A Study into the Impact of Engine Oil on Gasoline Particulate Filter Performance through a Real-World Fleet Test

2019-04-02
2019-01-0299
Increasingly stringent vehicle emissions legislation is being introduced throughout the world, regulating the allowed levels of particulate matter emitted from vehicle tailpipes. The regulation may prove challenging for gasoline vehicles equipped with modern gasoline direct injection (GDI) technology, owing to their increased levels of particulate matter production. It is expected that gasoline particulate filters (GPFs) will soon be fitted to most vehicles sold in China and Europe, allowing for carbonaceous particulate matter to be effectively captured. However, GPFs will also capture and accumulate non-combustible inorganic ash within them, mainly derived from engine oil. Studies exist to demonstrate the impact of such ash on GPF and vehicle performance, but these commonly make use of accelerated ash loading methods, which themselves introduce significant variation.
Book

Reducing Particulate Emissions in Gasoline Engines

2018-11-28
For years, diesel engines have been the focus of particulate matter emission reductions. Now, however, modern diesel engines emit less particles than a comparable gasoline engine. This transformation necessitates an introduction of particulate reduction strategies for the gasoline-powered vehicle. Many strategies can be leveraged from diesel engines, but new combustion and engine control technologies will be needed to meet the latest gasoline regulations across the globe. Particulate reduction is a critical health concern in addition to the regulatory requirements. This is a vital issue with real-world implications. Reducing Particulate Emissions in Gasoline Engines encompasses the current strategies and technologies used to reduce particulates to meet regulatory requirements and curtail health hazards - reviewing principles and applications of these techniques.
Technical Paper

Severe Soot Oxidations in Gasoline Particulate Filter Applications

2018-09-10
2018-01-1699
With the start of EU6 in 2017 gasoline particulate filters (GPF) have been introduced to production vehicles. It is expected that by 2019 all gasoline direct injection engines sold in Europe will be equipped with a GPF. A similar trend is observed in China with a slight delay compared to Europe, but covering all gasoline engines, including those with port fuel injection technology. With the introduction of GPFs, new requirements are introduced to the management of gasoline engines and their aftertreatment. One requirement is to protect the aftertreatment components from excessive temperatures and damage as result of uncontrolled soot oxidations. While the general fundamentals are similar to those in diesel applications, significant differences exist in the relevant details.
Technical Paper

Acoustic Modeling for Three-Dimensional Lightweight Windshields

2018-04-03
2018-01-0141
In the auto industry, lightweight window designs are drawing more attention for improved gas mileage and reduced exhaust emission. Corning’s Gorilla® Glass used in laminate design enables more than 30% weight reduction compared to conventional soda-lime glass laminates. In addition, Gorilla® Glass hybrid laminates (which are a laminate construction of a thick soda-lime glass outer play, a middle polyvinyl butyral interlayer, and a thin Gorilla Glass inner ply) also show significantly improved toughness due to advanced ion-exchange technology that provides high-surface compression. However, the reduced mass also allows increased transmission of sound waves through the windshield into the vehicle cabin. A system-level measurement approach has always been employed to assess overall vehicle acoustic performance by measuring sound pressure levels (SPL) at the driver’s ears. The measured sound signals are usually a superimposition of a variety of noise sources and transmission paths.
Technical Paper

Next Generation Cordierite Thin Wall DPF for Improved Pressure Drop and Lifetime Pressure Drop Solution

2016-04-05
2016-01-0940
Diesel particulate filters (DPF) have become a standard aftertreatment component for a majority of current on-road/non-road diesel engines used in the US and Europe. The upcoming Stage V emissions regulations in Europe will make DPFs a standard component for emissions reductions for non-road engines. The tightening in NOx emissions standard has resulted in the use of selective catalytic reduction (SCR) technology for NOx reduction and as a result the general trend in engine technology as of today is towards a higher engine-out NOx/PM ratio enabling passive regeneration of the DPF. The novel filter concept discussed in this paper is optimized for low pressure drop, high filtration efficiency, and low thermal mass for optimized regeneration and fast heat-up, therefore reducing CO2 implications for the DPF operation.
Journal Article

Modeling of the Soot Oxidation in Gasoline Particulate Filters

2015-04-14
2015-01-1048
The share of gasoline engines based on direct injection (DI) technology is rapidly growing, to a large extend driven by their improved efficiency and potential to lower CO2 emissions. One downside of these advanced engines are their significantly higher particulate emissions compared to engines based on port fuel injection technologies [1]. Gasoline particulate filters (GPF) are one potential technology path to address the EU6 particulate number regulation for vehicles powered by gasoline DI engines. For the robust design and operation of GPFs it is essential to understand the mechanisms of soot accumulation and oxidation under typical operating conditions. In this paper we will first discuss the use of detailed numerical simulation to describe the soot oxidation in particulate filters under typical gasoline engine operating conditions. Laboratory experiments are used to establish a robust set of soot oxidation kinetics.
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