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The ever-tightening regulation norms across the world emphasize the magnitude of the air pollution problem. The decision to leapfrog from BS4 to BS6 – with further reduction in emission limits -showed India’s commitment to clean up its atmosphere. The overall cycle emissions were reduced significantly to meet BS6 targets [1]. However, the introduction of RDE norms in BS6.2 [1] demanded further reduction in emissions under real time operating conditions – start-stop, hard acceleration, idling, cold start – which was possible only through strategies that demanded a cost effective yet robust solutions. The first few seconds of the engine operation after start contribute significantly to the cycle gaseous emissions. This is because the thermal inertia of the catalytic converter restricts the rate at which temperature of the catalyst increases and achieves the desired “light-off” temperature.

India BS6 Stage2 (2023) regulations demand all gasoline direct injection (GDI) vehicles to meet particulate number emissions (PN) below 6x10+11# per km. Gasoline particulate filters (GPF) are a proven technology and enable high PN filtration efficiencies throughout the entire vehicle lifetime. One challenge for GPF applications could be the changing emission performance characteristics as a function of mileage due to collected ash and/or soot deposits with implications on back pressure losses. The main objective of this technical contribution is to study the above-mentioned challenges while applying Indian driving conditions and typical Indian climate and other ambient conditions. The substrate technology selected for this study is a high porosity GPF designed to enable the integration of a three-way functionality into the GPF, commonly described as catalyzed GPF (cGPF).

This review paper covers major regulatory and technology developments in 2018 pertinent to tailpipe emissions of greenhouse gases and criteria pollutants. Europe has proposed ambitious reductions in CO2 limits for both light- and heavy-duty sectors. The challenge is compounded with changing measurement norms and a significant shift away from fuel efficient diesels in the light-duty (LD) space. Both incremental and step changes are being made to advance internal combustion. New studies show that in-use NOx emissions from diesels can be much lower than required by the Euro 6 regulation. Discussions have already started on Euro 7 regulations, and the leading regulatory concepts and proposed technical solutions are provided. In the heavy-duty (HD) sector, the progress is outlined in improving engine and vehicle fuel efficiency through the US Department of Energy’s (DOE’s) SuperTruck II program and other representative studies.

For years, diesel engines have been the focus of particulate matter emission reductions. Now, however, modern diesel engines emit less particles than a comparable gasoline engine. This transformation necessitates an introduction of particulate reduction strategies for the gasoline-powered vehicle. Many strategies can be leveraged from diesel engines, but new combustion and engine control technologies will be needed to meet the latest gasoline regulations across the globe. Particulate reduction is a critical health concern in addition to the regulatory requirements. This is a vital issue with real-world implications. Reducing Particulate Emissions in Gasoline Engines encompasses the current strategies and technologies used to reduce particulates to meet regulatory requirements and curtail health hazards - reviewing principles and applications of these techniques.

This review article summarizes major and representative developments in vehicle emissions regulations, engine efficiency, and emission control from 2017. The article starts with the key regulatory developments in the field, including newly proposed European light-duty (LD) CO2 regulations (15 and 30% cuts in 2025 and 2030, respectively, from 2020 levels) and technical improvements of the Euro 6 real driving emissions (RDE) regulations. China finalized their new energy vehicle (NEV) mandates for 2019 and 2020. LD and heavy-duty (HD) engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging criteria and greenhouse gas (GHG) regulations. Several LD gasoline concepts are achieving 10-15% and some up to 35% reductions relative to gasoline direct injection (GDI) engines of today.

This review paper summarizes major and representative developments in vehicle engine efficiency and emissions regulations and technologies from 2016. The paper starts with the key regulatory developments in the field, including newly proposed European RDE (real driving emissions) particle number regulations, and Euro 6 type regulations for China and India in the 2020 timeframe. China will be tightening 30-40% relative to Euro 6 in 2023. The California heavy duty (HD) low-NOx regulation is advancing and the US EPA is anticipating developing a harmonized proposal for implementation in 2023+. The US also finalized the next round of HD GHG (greenhouse gas) regulations for 2021-27, requiring 5% engine CO2 reductions. LD (light duty) and HD engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging criteria and greenhouse gas regulations.

This review paper summarizes major and representative developments in vehicular emissions regulations and technologies from 2015. The paper starts with the key regulatory advancements in the field, including newly proposed Euro 6 type regulations for Beijing, China, and India in the 2017-20 timeframe. Europe is continuing developments towards real driving emissions (RDE) standards with the conformity factors for light-duty diesel NOx ramping down to 1.5X by 2021. The California heavy duty (HD) low-NOx regulation is advancing and may be proposed in 2017/18 for implementation in 2023+. LD (light duty) and HD engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging criteria and greenhouse gas regulations. LD gasoline concepts are achieving 45% BTE (brake thermal efficiency or net amount of fuel energy gong to the crankshaft) and closing the gap with diesel.

A production calibrated GTDI 1.6L Ford Fusion was used to demonstrate low HC, CO, NOx, PM (particulate mass), and PN (particulate number) emissions using advanced catalyst technologies with newly developed high porosity substrates and coated GPFs (gasoline particulate filters). The exhaust system consisted of 1.2 liters of TWC (three way catalyst) in the close-coupled position, and 1.6L of coated GPF in the underfloor position. The catalysts were engine-aged on a dynamometer to simulate 150K miles of road aging. Results indicate that ULEV70 emissions can be achieved at ∼$40 of PGM, while also demonstrating PM tailpipe performance far below the proposed California Air Resources Board (CARB) LEV III limit of 1 mg/mi. Along with PM and PN analysis, exhaust system backpressure is also presented with various GPF designs.

With the increasing number of automobiles, the worldwide problem of air pollution is becoming more serious. The necessity of reducing tail-pipe emissions is as high as ever, and in countries all over the world the regulations are becoming stricter. The emissions at times such as after engine cold start, when the three-way catalyst (TWC) has not warmed up, accounts for the majority of the emissions of these pollutants from vehicles. This is caused by the characteristic of the TWC that if a specific temperature is not exceeded, TWC cannot purify the emissions. In other words, if the catalyst could be warmed up at an early stage after engine start, this would provide a major contribution to reducing the emissions. Therefore, this research is focused on the substrate weight and investigated carrying out major weight reduction by making the porosity of the substrate larger than that of conventional products.

The review paper summarizes major developments in vehicular emissions regulations and technologies in 2013. First, the paper covers the key regulatory developments in the field, including proposed light-duty (LD) criteria pollutant tightening in the US; and in Europe, the continuing developments towards real-world driving emissions (RDE) standards. Significant shifts are occurring in China and India in addressing their severe air quality problems. The paper then gives a brief, high-level overview of key developments in fuels. Projections are that we are in the early stages of oil supply stability, which could stabilize fuel prices. LD and HD (heavy-duty) engine technology continues showing marked improvements in engine efficiency. Key developments are summarized for gasoline and diesel engines to meet both the emerging NOx and GHG regulations. HD engines are or will soon be demonstrating 50% brake thermal efficiency using common approaches.

This review paper summarizes major developments in vehicular emissions regulations and technologies (light-duty, heavy-duty, gasoline, diesel) in 2011. First, the paper covers the key regulatory developments in the field, including proposed criteria pollutant tightening in California; and in Europe, the newly proposed PN (particle number) regulation for direct injection gasoline engines, test cycle development, and in-use testing discussions. The proposed US LD (light-duty) greenhouse gas (GHG) regulation for 2017-25 is reviewed, as well as the finalized, first-ever, US HD (heavy-duty) GHG rule for 2014-17. The paper then gives a brief, high-level overview of key emissions developments in LD and HD engine technology, covering both gasoline and diesel. Emissions challenges include lean NOx remediation for diesel and lean-burn gasoline to meet both the emerging NOx and GHG regulations.

Multi-scale computational chemistry methods based on the ultra-accelerated quantum chemical molecular dynamics (UA-QCMD) are applied to investigate electronic and atomistic roles of cordierite substrate in sintering of washcoated automotive catalysts. It is demonstrated that the UA-QCMD method is effective in performing quantum chemical molecular dynamics calculations of crystals of cordierite, Al₂O₃ and CeZrO₄ (hereafter denoted as CZ). It is around 10,000,000 times faster than a conventional first-principles molecular dynamics method based on density-functional theory (DFT). Also, the accuracy of the UA-QCMD method is demonstrated to be as high as that of DFT. On the basis of these confirmations and comparison, we performed extensive quantum chemical molecular dynamics calculations of surfaces of cordierite, Al₂O₃ and CZ, and interfaces of Al₂O₃ and CZ with cordierite at various temperatures.

To meet the future emission targets for Diesel engines, one trend is the use of Catalyzed Diesel Particulate Filters (CDPF). Catalyzing the filter, however, alters filter behavior. In particular, alteration in filter permeability imparts a significant change in the filter's performance. To understand the impact of the catalyst coating on a DPF, engine tests have been conducted to measure the pressure drop across DPFs with different catalyst coatings, cell densities, and soot loadings. The tests were performed over a range of engine speeds and loads, with a corresponding range in exhaust flow rates and temperatures. A pressure drop model based on previous work for uncatalyzed filters has been modified and validated for CDPFs. To achieve optimum design for DPF's, a parametric study comparing the influence of catalyst, cell density, wall thickness, filter length and diameter was done.

To establish performance trends in ultra thin wall substrates and help support their selection criteria for designing catalytic converter systems, the light-off behavior of five Ultra Thin Wall ceramic substrates and two catalysts on an engine dynamometer are hereby examined. Modeling predictions are also compared to the engine results and the trends and implications are discussed. To quantify the performance of these different systems, light-off tests were performed on an engine dynamometer using a simulated FTP cycle. Five systems were evaluated (600/4, 600/3, 600/2, 900/2 and 1200/2) each with two different catalyst formulations. Engine bench aging was used to simulate typical aged conditions in the converter systems. Second by second emissions data for temperature, hydrocarbons and carbon monoxide, were used to evaluate the relative performances of the substrates.

An analytical model for estimating shear and bending stresses during canning of cordierite ceramic catalyst supports is presented. These stresses arise when the radial pressure distribution is nonuniform due, primarily, to variations in gap bulk density (GBD ) of intumescent mat around the perimeter of the substrate. Variations in GBD can occur during canning, regardless of the canning technique, due to anisotropic can stiffness or component tolerances or mat overlap. The model helps relate shear and bending stresses to substrate size and orientation, elastic modulii, cell size and wall porosity. If these stresses approach the corresponding strength of substrate, a shear crack may develop during or after the canning process depending on the magnitude of stress. A special test fixture was developed to measure the shear strength of ceramic catalyst supports, with different cell sizes, before and after the application of washcoat.

This paper gives a comprehensive overview of the current state-of-the-art in diesel emission control. The nature of diesel particulates is summarized. The variety of diesel particulate filter regeneration strategies that will become so important to filter application are reviewed. Filter retrofit and durability issues are addressed. DeNOx catalysts, SCR, NOx traps for diesel, and non-thermal plasma methods are summarized. Integrated NOx/PM systems are described. And reduction of exhaust toxics is discussed. The paper covers all major conferences in the year 2000 that occurred in the US and Europe. US and Europe.

The key diesel emission control papers of the last 12 months have been summarized. In addition, the emerging US and European light-duty and heavy-duty tailpipe regulations are compared. Results are reported on light-duty diesel filtration regeneration systems and experiences, including effects of ash build-up and some recent modeling work. On the heavy-duty side, optimization of SCR catalysts and systems are described, as well as experiences with the first integrated SCR/filter systems, which are already achieving “Euro V” 2008 standards. An update on NOx adsorbers is also provided. The results with new NOx formulations are described, as well as the system performance in a light-duty diesel application.

One approach to the remediation of NOx generated under lean automotive engine conditions is its controlled storage and then periodic release and reaction under enriched conditions. This process is being considered for automotive exhaust systems that will be operated pre–dominantly lean for reasons of fuel economy. Because of the special characteristics of alkali and alkaline earth elements in the presence of NOx, they are being considered for use, in conjunction with γ–alumina–based washcoats and precious metal catalysts, as NOx catalyst coatings on cellular supports. It is known that alumino–silicates will react with alkali and alkaline earth elements to form stable ceramic phases when mixtures of the components are held in direct contact at elevated temperatures.

With stricter emissions standards, low back pressure requirements, and 100,000 mile durability specifications, ceramic catalysts have undergone significant developments over the past few years. The thrust in the ceramics area has centered on thin-wall structures to minimize back pressure and on high cell density for rapid light-off in close-coupled applications. The thin-wall structures are extruded from low expansion cordierite ceramic with adequate strength and thermal shock resistance equivalent to those of standard cordierite substrate. Examples of thin-wall substrate include 350XT which is extruded from a very low expansion dense cordierite ceramic, and 400/4 and 600/4 cell structures extruded from a low expansion modified cordierite ceramic. This paper will focus on the high fatigue resistance, excellent conversion efficiency, and low back pressure of 350 XT substrates with advanced washcoat system.

The monolithic, large frontal area (LFA), extruded ceramic substrates for diesel flow-through catalysts offer unique advantages of design versatility, longterm durability, ease of packaging and low Cost [1, 2]*. This paper examines the effect of cell density and cell size on catalyst light-off performance, back pressure, mechanical and thermal durability, and the steady-state catalytic activity. The factors which affect these performance characteristics are discussed. Certain trade-offs in performance parameters, which are necessary for optimum systems design, are also discussed. Following a brief discussion of design methodology, substrate selection, substrate/washcoat interaction and packaging specifications, the durability data for ceramic flow-through catalysts are summarized. A total of over 18 million vehicle miles have been successfully demonstrated by ceramic LFA catalysts using the systems design approach.