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In the present work, five surrogate components (n-Hexadecane, n-Tetradecane, Heptamethylnonane, Decalin, 1-Methylnaphthalene) are proposed to represent liquid phase of diesel fuel, and another different five surrogate components (n-Decane, n-Heptane, iso-Octane, MCH (methylcyclohexane), Toluene) are proposed to represent vapor phase of diesel fuel. For the vapor phase, a 5-component surrogate chemical kinetic mechanism has been developed and validated. In the mechanism, a recently updated H2/O2/CO/C1 detailed sub-mechanism is adopted for accurately predicting the laminar flame speeds over a wide range of operating conditions, also a recently updated C2-C3 detailed sub-mechanism is used due to its potential benefit on accurate flame propagation simulation. For each of the five diesel vapor surrogate components, a skeletal sub-mechanism, which determines the simulation of ignition delay times, is constructed for species C4-Cn.

Electric vehicles (EVs) are a promising and proven technology for achieving sustainable mobility with zero carbon emissions, very low noise pollution, and reducing the dependency on fossil fuels. Global EV sales have been increasing by ~110 % since 2015, with a significant rise in 2021 (~6.75 mils EV registered) mainly led by China, the US, and Europe, amplifying the EV market share to 8.3% compared to 4.2% in 2020. Future developments aimed at designing better batteries and charging technologies that reduce charging time, reduce initial battery cost, and increased flexibility. In India, EVs are emerging significantly due to stringent Carbon di Oxide (CO2) reduction drives, increasing crude oil prices, and the availability of cheaper renewable energy. Leveraging government promotional policies, evolving the entire ecosystem, globally advantageous manufacturing costs, and competitive engineering skills form the perfect blend for India.

This study investigated the potential of generating reactive chemical species (including radicals) through pilot fuel injection in negative valve overlap for improving the combustion and emissions performances of spark ignition gasoline engines under low load and low speed operating conditions. Several Ford sub-models were used for simulating the physics and chemistry processes of injecting a small amount of fuel in NVO (negative valve overlap). Effects of different NVO degrees and different pilot injection timings, factors for fuel conversion were simulated and investigated. CO and H2 conversions during NVO, CO and H2 amounts before spark timing were used for comparing different schemes.

In order to decarbonize and lower the overall emissions of the transport sector, immediate and cost-effective powertrain solutions are needed. Natural gas offers the advantage of a direct reduction of carbon dioxide (CO2) emissions due to its better Carbon to Hydrogen ratio (C/H) compared to common fossil fuels, e.g. gasoline or diesel. Moreover, an optimized engine design suiting the advantages of natural gas in knock resistance and lean mixtures keeping in mind the challenges of power density, efficiency and cold start manoeuvres. In the public funded project MethMag (Methane lean combustion engine) a gasoline fired three-cylinder-engine is redesigned based on this change of requirements and benchmarked against the previous gasoline engine.

This paper analyzes the use of an ammonia sensor for feedback control in diesel exhaust systems. We build our case around the specific example of the heavy duty transient cycle, and an exhaust system with an SCR catalyst, a single urea injector and an upstream and downstream NOx sensor. A key component in our analysis is the inclusion of the tolerance of the ammonia sensor. We show that with the current understanding of the sensor tolerance, the ammonia sensor has limited benefit for controls.

A novel laser-absorption gas sensing apparaOn-vehicle Testing at VERtus capable of measuring NO directly within vehicle exhaust was developed and tested. The sensor design was enabled by key advances in the construction of optical probes that are sufficiently compact for deployment in real-world exhaust systems and can survive the harsh, high-temperature, and strongly vibrating environment typical of exhaust streams. Prototype test campaigns were conducted at high-temperature flow facilities intended to simulate exhaust gas conditions and within the exhaust of vehicles mounted on a chassis dynamometer. Results from these tests demonstrated that the sensor prototype is fundamentally free of cross-interference with competing species in the exhaust stream, can achieve a 1 ppmv NO detection limit, and can be operated across the full range of thermodynamic conditions expected for typical vehicle exhausts.

A series of cold start experiments using a 2.0 liter gasoline turbocharged direct injection (GTDI) engine with custom controls and calibration were carried out using gasoline and iso-pentane fuels, to obtain the cold start emissions profiles for the first 5 firing cycles at an ambient temperature of 22°C. The exhaust gases, both emitted during the cold start firing and emitted during the cranking process right after the firing, were captured, and unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start were analyzed and quantified. The HCs emitted during gasoline-fueled cold starts was found to reduce significantly as the engine cycle increased, while CO and CO2 emissions were found to stay consistent for each cycle. Crankcase ventilation into the intake manifold through the positive-crankcase ventilation (PCV) valve system was found to have little effect on the emissions results.

“Real world emissions” is an emerging area of focus in motor vehicle related air quality. These emissions are commonly recorded using portable emissions measurement systems (PEMS) designed for regulatory application, which are large, complex and costly. Miniature PEMS (mPEMS) is a developing technology that can significantly simplify on-board emissions measurement and potentially promote widespread use. Whereas full PEMS use analyzers to record NOx, CO, and HCs similar to those in emissions laboratories, mPEMS tend to use electrochemical sensors and compact optical detectors for their small size and low cost. The present work provides a comprehensive evaluation of this approach. It compares measurements of NOx, CO, CO2 and HC emissions from five commercial mPEMS to both laboratory and full regulatory PEMS analyzers. It further examines the use of vehicle on-board diagnostics data to calculate exhaust flow, as an alternative to on-vehicle exhaust flow measurement.

Real world emissions are increasingly the standard of comparison for motor vehicle exhaust impact on the environment. The ability to collect such data has thus far relied primarily on full portable emissions measurement systems (PEMS) that are bulky, expensive, and time consuming to set up. The present work examines four compact, low cost, miniature PEMS (mPEMS) that offer the potential to expand our ability to record real world exhaust emissions over a larger number of operating conditions and combustion engine applications than currently possible within laboratory testing. It specifically addresses the particulate matter (PM) capabilities of these mPEMS, which employ three different methodologies for particle measurement: diffusion charger, optical scattering, and a multi-sensor approach that combines scattering, opacity, and ionization. Their performance is evaluated against solid particle number and PM mass with both vehicle tests and flame generated soot.

There is keen interest in understanding the origins of engine-out unburned hydrocarbons emitted during SI engine cold start. This is especially true for the first few firing cycles, which can contribute disproportionately to the total emissions measured over standard drive cycles such as the US Federal Test Procedure (FTP). This study reports on the development of a novel methodology for capturing and quantifying unburned hydrocarbon emissions (HC), CO, and CO2 on a cycle-by-cycle basis during an engine cold start. The method was demonstrated by applying it to a 4 cylinder 2 liter GTDI (Gasoline Turbocharged Direct Injection) engine for cold start conditions at an ambient temperature of 22°C. For this technique, the entirety of the engine exhaust gas was captured for a predetermined number of firing cycles.

In this work we studied the effects of piston bowl design on combustion in a small-bore direct-injection diesel engine. Two bowl designs were compared: a conventional, omega-shaped bowl and a stepped-lip piston bowl. Experiments were carried out in the Sandia single-cylinder optical engine facility, with a medium-load, mild-boosted operating condition featuring a pilot+main injection strategy. CFD simulations were carried out with the FRESCO platform featuring full-geometric body-fitted mesh modeling of the engine and were validated against measured in-cylinder performance as well as soot natural luminosity images. Differences in combustion development were studied using the simulation results, and sensitivities to in-cylinder flow field (swirl ratio) and injection rate parameters were also analyzed.

The new European test procedure, called the worldwide harmonized light vehicle test procedure (WLTP), deviates in some details from the current NEDC-based test which will have an impact on the determination of the official EU fuel consumption values for the new vehicles. The adaptation to the WLTP faces automakers with new challenges for meeting the stringent EU fuel consumption and CO2 emissions standards. This paper investigates the main changes that the new test implies to a mid-size sedan electrified vehicle design and quantifies their impact on the vehicles fuel economy. Three common electrified powertrain architectures including series, parallel P2, and powersplit are studied. A Pontryagin’s Minimum Principle (PMP) optimization-based energy management control strategy is developed to evaluate the energy consumption of the electrified vehicles in both charge-depleting (CD) and charge-sustaining (CS) modes.

Gasoline particulate filters (GPFs) are extremely effective at reducing tailpipe emissions of particulate mass and particulate number. Especially in the European and Chinese markets, where a particulate number standard is legislated, we see gasoline particulate filters being deployed in production on gasoline direct injected engines. Due to the high temperature in gasoline exhaust, most applications are expected to be passively regenerating without the help of an active regeneration strategy. However, for the few cases where a customer drive cycle has consistently low speed over a long time frame, an active regeneration strategy may be required. This involves increasing the exhaust temperature at the GPF up to around 600 degC so that soot can be combusted. We compare two different ways of achieving these temperatures, namely spark retard and air fuel ratio modulation. The former generates heat in the engine, the latter generates heat in one or more catalysts in the exhaust system.

Gasoline particulate filters (GPF) with high filtration efficiency (>80%) at zero mileage are in growing demand to meet increasingly tight vehicle emission standards for particulate matter being implemented in US, EU, China and elsewhere. Current efforts to achieve high filter performance mainly focus on fine-tuning the filter structure, such as the pore size distribution and porosity of the bare substrate, or the washcoat loading and location of catalyzed substrates. However, high filtration efficiency may have a cost in high backpressure that negatively affects engine power. On the other hand, it has been recognized in a few reports that very low amounts of ash deposits (from non-combustible residue in the exhaust) can significantly increase filtration efficiency with only a mild backpressure increase.

The availability of connectivity and autonomy enabled resources, within the automotive sector, has primarily been considered for driver assist technologies and for extending the levels of vehicle autonomy. It is not a stretch to imagine that the additional information, available from connectivity and autonomy, may also be useful in further improving powertrain functions. Critical powertrain subsystems that must operate with limited or uncertain knowledge of their environment stand to benefit from such new information sources. Unfortunately, the adoption of this new information resource has been slow within the powertrain community and has typically been limited to the obvious problem choices such as battery charge management for electric vehicles and efforts related to fuel economy benefits from adaptive/coordinated cruise control. In this paper we discuss the application of connectivity resources in the management of an aftertreatment sub-system, the Diesel Particulate Filter (DPF).

Medium duty vehicles come in many design variations, which makes testing them all for CO2 impractical. As a result there are multiple ways of reporting CO2 emissions. Actual tests may be performed, data substitution may be used, or CO2 values may be estimated using an analytical correction. The correction accounts for variations in road load force coefficients (f0, f1, f2), weight, and axle ratio. The EPA Analytically Derived CO2 equation (EPA ADC) was defined using a limited set of historical data. The prediction error is shown to be ±130 g/mile and the sensitivities to design variables are found to be incorrect. Since the absolute CO2 is between 500 and 1,000 g/mi, the equation has limited usefulness. Previous work on light duty vehicles has demonstrated a linear relationship between vehicle fuel consumption, powertrain properties and total vehicle work. This relationship improves the accuracy and avoids co-linearity and non-orthogonality of the input variables.

Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.

In the development of HC traps (HCT) for reducing vehicle cold start hydrocarbon (HC)/nitrogen oxide (NOx) emissions, zeolite-based adsorbent materials were studied as key components for the capture and release of the main gasoline-type HC/NOx species in the vehicle exhaust gas. Typical zeolite materials capture and release certain HC and NOx species at low temperatures (<200°C), which is lower than the light-off temperature of a typical three-way catalyst (TWC) (≥250°C). Therefore, a zeolite alone is not effective in enhancing cold start HC/NOx emission control. We have found that a small amount of Pd (<0.5 wt%) dispersed in the zeolite (i.e., BEA) can significantly increase the conversion efficiency of certain HC/NOx species by increasing their release temperature. Pd was also found to modify the adsorption process from pure physisorption to chemisorption and may have played a role in the transformation of the adsorbed HCs to higher molecular weight species.

Passive in-line catalyzed hydrocarbon (HC) traps have been used by some manufacturers in the automotive industry to reduce regulated tailpipe (TP) emissions of non-methane organic gas (NMOG) during engine cold-start conditions. However, most NMOG molecules produced during gasoline combustion are only weakly adsorbed via physisorption onto the zeolites typically used in a HC trap. As a consequence, NMOG desorption occurs at low temperatures resulting in the use of very high platinum group metal (PGM) loadings in an effort to combust NMOG before it escapes from a HC trap. In the current study, a 2.0 L direct-injection (DI) Ford Focus running on gasoline fuel was evaluated with full useful life aftertreatment where the underbody converter was either a three-way catalyst (TWC) or a HC trap. A new HC trap technology developed by Ford and Umicore demonstrated reduced TP NMOG emissions of 50% over the TWC-only system without any increase in oxides of oxygen (NOx) emissions.

Friction reduction in lubricated components through engine oil formulations has been investigated in the present work. Three different DI packages in combination with one friction modifier were blended in SAE 5 W-20 and SAE 0 W-16 viscosity grades. The friction performance of these oils was compared with GF-5 SAE 5 W-20 oil. A motored cranktrain assembly has been used to evaluate these, in which friction mean effective pressure (FMEP) as a function of engine speeds at different lubricant temperatures is measured. Results show that the choice of DI package plays a significant role in friction reduction. Results obtained from the mini-traction machine (MTM2) provide detailed information on traction coefficient in boundary, mixed and elastohydrodynamic (EHD) lubrication regimes. It has been shown that the results from the cranktrain rig are fairly consistent with those found in MTM2 tests for all the lubricants tested.