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Catalytic oxidation is an effective means of controlling the build up of ammonia and other trace gas contaminants within closed spaces. However, it sometimes leads to the formation of noxious gases that need to be removed in post-treatment systems. In addition, ammonia removal is an issue when regeneration of water from wastewater is considered since ammonia is a byproduct of urea decomposition. For example, the VPCAR (Vapor Phase Catalytic Ammonia Reduction) advanced water processor system includes an oxidation reactor for the destruction of ammonia and of other volatile organics that are not separated out in the evaporator due to their volatility. The oxidation of ammonia may produce nitrogen, nitrogen oxides (NO and NO2), nitrous oxide (N2O) and water vapor. The Spacecraft Maximum Allowable Concentration (SMAC) for NO and NO2 are respectively 4.5 and 0.5 ppm whereas the Threshold Limit Value (TLV) for N2O is 25 ppm.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

The Conductivity Sensor designed for use in the Node 3 Water Processor Assembly (WPA) was based on the existing Space Shuttle application for the fuel cell water system. However, engineering analysis has determined that this sensor design is potentially sensitive to two- phase fluid flow (gas/liquid) in microgravity. The source for this sensitivity is the fact that free gas will become lodged between the sensor probe and the wall of the housing without the aid of buoyancy in 1-g. Once gas becomes lodged in the housing, the measured conductivity will be offset based on the volume of occluded gas. A development conductivity sensor was flown on the NASA Microgravity Plane (KC-135) to measure the offset, which was determined to range between 0 and 50%. This range approximates the offset experienced in 1-g gas sensitivity testing.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the international Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, hand wash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.

The TIMES system was evaluated to determine its ability to process reverse osmosis (RO) brine as one of the Advanced Water Processor steps. Since preliminary testing performed in 1998 showed that the membrane typically used in the process (Nafion 117) offered a very poor ammonia rejection, a search for an alternate membrane exhibiting high ammonia rejection capability was initiated under NASA-JSC funding. This investigation has resulted in the selection of a PolyVinylAlcohol (PVA) composite membrane as a replacement. When processing RO brine and untreated human urine as feeds, the Pervap 2201 membrane showed a 96% ammonia rejection over a large range of ammonia concentration. The water permeation rates in both laboratory-scale and pilot scale testings were also similar to the Nafion. The water permeance of the Pervap 2201 was approximately 7.5 kg/h/m2/atm (1.1 lb/h/m2/psi).

Carbon dioxide reduction in a closed loop life support system recovers water from otherwise waste carbon dioxide and hydrogen. Incorporation of a carbon dioxide reduction assembly (CRA) into the International Space Station life support system frees up thousands of pounds of payload capacity in the supporting Space Shuttle that would otherwise be required to transport water. Achievement of this water recovery goal requires coordination of the CRA design to work within the existing framework of the interface systems that are either already on orbit or well advanced in their development; namely, the Oxygen Generator Assembly (OGA), Carbon Dioxide Removal Assembly (CDRA) and Water Processor Assembly (WPA). The Oxygen Generation System (OGS) rack is in its final design phase and is scarred to accept later installation of the CRA.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene wastewaters. All planned development testing has been completed and this paper provides the status of the development activities and results for the WPA.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop, an Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization. Initially, the hydrogen will be vented overboard to space vacuum. The OGA has been under development at HSSSI for 3 years. This paper will update last year's ICES paper on the design/development of the OGA.

Hamilton Sundstrand Space Systems International, Inc. (HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recovery System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.

The Water Processor developed for the International Space Station includes a high temperature catalytic reactor that utilizes oxygen gas to oxidize dissolved chemicals. The effluent from the reactor is a mixture of gases (O2, CO2, N2) and hot water. Since the crew has requested that drinking water does not contain any free gas at body temperature (37.8 °C or 100 °F), a phase separator operating at elevated temperatures is required downstream of the catalytic reactor. For this application, Hamilton Sundstrand Space Systems International (HSSSI) has developed a passive Gas Liquid Separator (GLS) that relies on a positive barrier - a membrane - to extract the free gas from the inlet two-phase mixture. The membrane selected is a hollow fiber hydrophobic asymmetric membrane with pore size in the ultra-filtration range. This paper outlines the challenges in both design and operation that were overcome during the development of this device.

A Low Pressure Electrolyzer (LPE) is being developed to provide metabolic oxygen aboard US nuclear submarines. The system is derived from a more complex system already developed for the Virginia Class of attack submarines. The LPE generates up to 250 standard cubic feet per hour (SCFH) of oxygen at ambient pressure through electrolysis of water utilizing SPE® (Solid Polymer Electrolyte) technology. The hydrogen is generated at pressures suitable for disposal overboard. The system operates unattended which minimizes crew workload, and can safely shut down without crew intervention. Generating oxygen at ambient pressure significantly reduces risk to personnel and greatly simplifies the system. Reliability, maintainability, safety, and ease of operation are major system design drivers.

Hamilton Sundstrand Space Systems International, Inc. HSSSI) is under contract to NASA Marshall Space Flight Center (MSFC) to develop a Water Processor Assembly (WPA) and Oxygen Generation Assembly (OGA) for the International Space Station (ISS). The WPA produces potable quality water from humidity condensate, carbon dioxide reduction water, water obtained from fuel cells, reclaimed urine distillate, shower, handwash and oral hygiene waste waters. The Oxygen Generation Assembly (OGA) electrolyzes potable water from the Water Recover System (WRS) to provide gaseous oxygen to the Space Station module atmosphere. The OGA produces oxygen for metabolic consumption by crew and biological specimens. The OGA also replenishes oxygen lost by experiment ingestion, airlock depressurization, CO2 venting, and leakage. As a byproduct, gaseous hydrogen is generated. The hydrogen will be supplied at a specified pressure range to support future utilization.