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With accelerating exhaust gas regulations in recent years, not only CO / HC / NOx but also PN regulation represented by Euro 6 d, China 6 are getting stricter. PN reduction by engine combustion technology development also progresses, but considering RDE, PN reduction by after treatment technology is also indispensable. To reduce PN exhausted from the gasoline engine, it is effective to equip GPF with a filter structure. Considering the installation of GPF in limited space, we developed a system that so far replaces the second TWC with GPF for the TWC 2 bed system. In order to replace the second TWC with GPF, we chose the coated GPF with filtering and TWC functions. Since the initial pressure drop and the catalyst amount (purification performance) of coated GPF have a conflicting relationship, we developed the coated GPF that can achieve both the low initial pressure drop and high purification performance.

In recent years along with stringent the regulations, vehicles equipped with gasoline particulate filter (GPF) have started to launch. Compared to bare GPF, coated GPF (cGPF) requires not only PN filtration efficiency, low pressure drop, but also purification performance. In the wall flow type cGPF having a complicated the pore shape, the pore structure further irregularly changes depending on the coated state of the catalyst, so it is difficult to understand the matter of in-wall. In order to advance of cGPF function, it was researched that revealing the relevance between pore structure change in the wall and GPF function. Therefore, to understand the catalyst coated state difference, cGPF of several coating methods were prepared, and their properties were evaluated by various analyses, and performance was tested.

To evaluate the relationship between the exhaust gas purification performance and the catalyst pore properties related to gas diffusion, an elementary reaction model was combined with gas diffusion into catalyst pores, referred to as the pseudo-2D gas diffusion/reaction model. It was constructed for Pt/Al2O3 + CeO2 catalyst as lean NOx catalyst. The gas diffusion was described as macro pore diffusion between the catalyst particles and meso pore diffusion within the particle. The kinetic model was composed of 26 reactions of NO/CO/O2 chemistry including 17 Pt/Al2O3 catalyst reactions and 9 CeO2 reactions. Arrhenius parameters were optimized using activity measurement results from various catalysts with various pore properties, meso pore volume and diameter, macro pore volume and diameter, particle size, and washcoat thickness. Good agreement was achieved between the measured and calculated values.

Turbine housings in car engine turbochargers, which use costly stainless steel castings, account for nearly 50% of the parts cost of a turbocharger. They are also the component which controls the competitiveness of the turbocharger, in terms of both function and cost. In this research, focusing on thermal fatigue resistance which is one of the main functions demanded of a turbine housing, achieving reduction in wall thickness while securing sufficient thermal fatigue resistance, it is possible to reduce the amount of material used in the turbine housing and aimed for cost reduction. Therefore, we built a method to quantitatively predict, using 3D FEM, the lifespan from the initiation of thermal fatigue cracking to the formation of a penetrating crack which leads to gas leakage.

In recent years, fuel efficiency has been improved by using many technologies such as downsizing engine, turbocharger and direct injection to reduce CO2 emissions from vehicle. However, the temperature of the exhaust gas from the engines using these technologies becomes lower than that form conventional one. That increases the difficulty for three-way catalyst (TWC) to purify CO, HC and NOx enough because TWC is not warmed up just after engine starting. In order to reduce cold emission mentioned above, we have been studying the warmup strategy of which the key property is thermal mass of TWC. To achieve early warmup, thermal mass of TWC is reduced by lightening the weight of (1) substrate and (2) catalytic materials, namely washcoat amount. Along with the strategy, we have developed TWC with lightweight substrate and applied it from the 2016 model year CIVIC.

Honda diesel engine vehicles that go on the market in 2018 will be equipped with a newly developed silver (Ag)-type catalyzed diesel particulate filter (cDPF). Ag has high particulate matter (PM) oxidation performance, but conventional catalyst-carrying methods cause weak contact property between PM and Ag; therefore, the newly Ag-type cDPF was developed on the concept of enhancing the property of contact between PM and the catalyst to realize contact property enhancement at the macro, meso, and nano scales. As a result, the newly developed catalyst showed an enhancement of T90 performance by a factor of approximately 2 relative to the conventional Ag-type catalyst in fresh condition. Durability in the environment of an automobile in use was examined through hydrothermal aging, lean-rich (L/R) aging, sulfur (S) poisoning, and ash deposition. The results have confirmed that hydrothermal aging is the greatest factor in deterioration.

Lean-burn is an effective means of reducing CO2 emissions. To date, Homogenous Lean Charge Spark Ignition (HLSI) combustion, which lowers emissions of both CO2 and NOx, has been studied. Although HLSI realizes lower emission, it is a major challenge for lean-burn engines to meet SULEV regulations, so we have developed a new aftertreatment system for HLSI engines. It consists of three types of catalysts that have different functions, as well as special engine control methods. As the first stage in achieving SULEV emissions, this study focused on enhancing performance under lean conditions. HLSI engine exhaust gases contain high concentrations of hydrocarbons, including a large amount of paraffin, which are difficult to purify, rather than low concentrations of NOx. Therefore, the key point in low emissions is to purify not only NOx, but also high concentrations of paraffin at the same time.

In recent years, studies have been conducted on the relationship between the J factor, which indicates flow of molten aluminum at the time of injection, and the quality of HPDC products. The flow of molten metal at a high J factor is referred to as “Atomized Flow.” The authors and others conducted studies on the relationship between the J factor and the strength of HPDC products. An area exceeding 300MPa was found in the product produced at a high J factor corresponding to the “Atomized Flow.” The defect was less in the above-mentioned position because the gas porosity was finely dispersed. Considering that the fine dispersion of gas porosity is related to the “Atomized Flow”, pictures were taken to analyze “Atomized Flow.” The molten aluminum was ejected into an open space at a high speed and the splashed conditions were photographed. From the images taken by the pulse laser permeation, the conditions of microscopic atomized flow were observed precisely.

Piston ring wear in gasoline engine induces deterioration of emissions performance due to leakage of blow-by gas, instability of idling caused by reduced compression in combustion chamber, and to generate early degeneration of engine oil. We examined anti-wear performance of DLC coating on piston ring, which had been recently reported as an effective method for improving the abrasion resistance. As a result, wear rate remained low under the condition of DLC existence on sliding surface, but once DLC was worn out completely, wear of the piston ring was accelerated and its life became shorter than piston ring without DLC. In this research, we designed reciprocating test apparatus that operates at much higher velocity range, and characterized the frictional materials of the piston ring and sleeve and the DLC as a protective film, a vapor phase epitaxy (VPE) was actively used as a means to form certain level of convex and concave shape on its surface.

We developed a copper catalyst using zero Platinum group metals (hereafter PGMs) to fit motorcycle specific emission gas environment. Though many research reports to develop catalyst without using PGMs that are precious and costly resources are available, no reports had proven Base Metal Catalyst development to meet actual emission regulation equivalent to PGM catalysts. Compared to conventional PGM catalysts, higher temperature is required to keep high catalytic conversion efficiency by utilizing properties of this Base Metal Catalyst. Thus, this Base Metal Catalyst is located in cross coupling position, though it is rare case in motorcycle. This catalyst location could cause negative impacts on engine knocking, engine performance and drivability. This time, to overcome such negative impacts we optimized whole exhaust system, including parts around catalyst.

For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.

1. On page 111, the authors have described a method to assess driver distraction. In this method, participants maintained a white square size on a forward display by using a game gas pedal of like in car-following situation. The size of the white square is determined by calculating the distance to a virtual lead vehicle. The formulas to correct are used to explain variation of acceleration of the virtual lead vehicle. The authors inadvertently incorporated old formulas they had used previously. In the experiments discussed in the article, the corrected formulas were used. Therefore, there is no change in the results. The following from the article:

A new nitriding technology and material technology have been developed to increase the strength of microalloyed gears. The developed nitriding technology makes it possible to freely select the phase composition of the nitride compound layer by controlling the treatment atmosphere. The treatment environment is controlled to exclude sources of supply of [C], and H2 is applied as the carrier gas. This has made it possible to control the forward reaction that decomposes NH3, helping to enable the stable precipitation of γ′-phase, which offers excellent peeling resistance. A material optimized for the new nitriding technology was also developed. The new material is a low-carbon alloy steel that makes it possible to minimize the difference in hardness between the compound layer and the substrate directly below it, and is resistant to decline in internal hardness due to aging precipitation in the temperature range used in the nitriding treatment.

A new concept for trapping NOx and HC during cold start, the NOx Trap Three-Way Catalyst (N-TWC), is proposed. N-TWC adsorbs NOx at room temperature, and upon reaching activation temperature under suitable air-fuel ratio conditions, it reduces the adsorbed NOx. This allows a reduction in NOx emissions during cold start. N-TWC's reduction mechanism relies on NOx adsorption sites which are shown to be highly dispersed palladium on acid sites in the zeolite. Testing on an actual vehicle equipped with N-TWC confirmed that N-TWC is able to reduce emissions of NOx and HC during cold start, which is a challenge for conventional TWCs.

Catalyst simulation, which can analyze the complicated reaction pathway of exhaust gas purifications and identify the rate-determining step, is an essential tool in the development of catalyst materials. This requires an elementary reaction model which describes the detailed processes, i.e. adsorption, decomposition, and others. In our previous work, the elementary reaction model on Pt/CeO2 catalyst was constructed. In this study, we focused on extending the Zeolite catalyst and including the gas diffusivity through the catalyst layer. The reaction rate of a Zeolite catalyst was expressed by an Arrhenius equation, and the elementary reaction model was composed of 17 reactions. Each Arrhenius parameter was optimized by the catalytic activity measurements. The constructed model was validated with NOx conversion in cyclic experiments which were repeated with Lean phase (NOx adsorption) and Rich phase (NOx reduction).

With the increasing number of automobiles, the worldwide problem of air pollution is becoming more serious. The necessity of reducing tail-pipe emissions is as high as ever, and in countries all over the world the regulations are becoming stricter. The emissions at times such as after engine cold start, when the three-way catalyst (TWC) has not warmed up, accounts for the majority of the emissions of these pollutants from vehicles. This is caused by the characteristic of the TWC that if a specific temperature is not exceeded, TWC cannot purify the emissions. In other words, if the catalyst could be warmed up at an early stage after engine start, this would provide a major contribution to reducing the emissions. Therefore, this research is focused on the substrate weight and investigated carrying out major weight reduction by making the porosity of the substrate larger than that of conventional products.

This research is aimed at development of the catalyst for gasoline automobiles which uses only palladium (Pd) among platinum group metals (PGMs). And the conformity emission category aimed at LEV III-SULEV30. For evaluation, the improvement effect was verified for 2013 model year (MY) ACCORD (LEV II-SULEV) as the reference. As compared with Pd-rhodium (Rh) catalyst, a Pd-only catalyst had the low purification performance of nitrogen oxides (NOx), and there was a problem in the drop in dispersion of Pd by sintering, and phosphorus (P) poisoning.

By increasing the percentage of highly dissociative strong acid components included in the neutralizing acid of the electrodeposition coating, it was possible to improve electrical conductivity and coulomb efficiency and achieve excellent throwing power. The GA cratering caused by the increase in the strong acid ratio was resolved by setting the strong acid ratio to 90% while reducing MEQ. By increasing coulomb efficiency, the quantity of hydrogen gas produced during electrodeposition was minimized, and as a result, gas pinholes remaining in the coating were reduced, increasing the smoothness of the coating beyond than that of the current materials. As a result of this study, the usage of e-coating per vehicle body was reduced by approximately 11%.

The reduction of NOx in exhaust gas has been a major challenge in diesel engine development. For the NOx reduction issues, a new Lean NOx Catalyst (LNC) aftertreatment system has been developed by Honda. A feature of the LNC system is the method that is used to reduce NOx through an NH₃-Selective Catalytic Reduction (NH₃-SCR). In an LNC system NOx is adsorbed at lean conditions, then converted to NH₃ at rich conditions and subsequently reduced in the next lean phase. In recent years, as the efficiency of the diesel engine has improved, the exhaust gas temperatures have been reduced gradually. Therefore, the aftertreatment system needs to be able to purify NOx at lower temperatures. The development of a new LNC which has a high activity at low temperature has been carried out. For the improvement of the LNC three material improvements were developed. The first of these was the development of a NOx adsorbent which is matching the targeted exhaust gas temperatures.

Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).