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Cold start remains a major obstacle to the commercialization of proton exchange membrane fuel cell (PEMFC), however, there are few studies on the cold start characteristics, especially at a complicated stack level. In this study, a novel layer-lumped numerical model with higher computational efficiency is proposed to investigate the cold start behavior of PEMFC stack, in which phase transition, heat transfer and electrochemical reaction are comprehensively considered. Besides, phase transition mechanisms are reconstructed based on the assumption that super-cooled water exists within the cell. With this model, the inconsistency of the stack temperature distribution and output performance is presented, some constant loading voltage strategies are investigated, and a linear variable controlling voltage strategy is developed.

Gas purge is considered as an essential shutdown process for a PEMFC (Proton Exchange Membrane Fuel Cell), especially in subfreezing temperature. The water flooding phenomenon inside fuel cell flow channel have a marked impact on performance in normal operating condition. In addition, the residual water freezes in the subzero temperature, thus blocking the mass transfer from flow channel to porous media. Therefore, the gas purge course is of primary importance for improvement of performance and durability. The water droplet residing in the flow channel can be purged out due to shearing force of gas. In fact, the flow channel is not completely flat due to surface roughness of gas diffusion layer (GDL), meaning the water droplet may climb over obstacles. Moreover, the water droplet may block the flow channel and then be sheared into films on the surface of GDL.