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Abstract Due to the limitations of current battery manufacturing processes, integration technology, and operating conditions, the large-scale application of lithium-ion batteries in the fields of energy storage and electric vehicles has led to an increasing number of fire accidents. When a lithium-ion battery undergoes thermal runaway, it undergoes complex and violent reactions, which can lead to combustion and explosion, accompanied by the production of a large amount of flammable and toxic gases. These flammable gases continue to undergo chemical reactions at high temperatures, producing complex secondary combustion products. This article systematically summarizes the gas generation characteristics of different types and states of batteries under different thermal runaway triggering conditions. And based on this, proposes the key research directions for the gas generation characteristics of lithium-ion batteries.

Abstract Emissions development work for gasoline aftertreatment systems is often conducted in a laboratory on a chassis dynamometer. In this situation, extractive sample lines are frequently connected to the aftertreatment system before and after various components, such as a three-way catalyst, selective catalytic reduction substrate, and the like. This is done to measure the conversion efficiency of the aftertreatment system components as a function of time. The time series exhaust component concentration data, also referred to as continuous data, are combined with a measure of exhaust volumetric flowrate and used to calculate mass-based emissions. As gasoline powertrains become cleaner and produce lower levels of criteria emissions, the proximity (i.e., colocated or not colocated) of the volumetric flowrate and concentration measurements may affect the accuracy of the overall mass emission calculation.

Abstract An integrated electrically heated catalyst (EHC) in the three-way catalyst (TWC) of a gasoline internal combustion engine (ICE) is a promising technology to reduce engine cold-start pollutant emissions. Pre-heating the TWC ensures earlier catalyst light-off of a significant portion of the TWC. In such a case, the engine could readily be operated in a fuel-optimal manner since the engine cold-start emission is efficiently treated by the warmed-up EHC-equipped TWC. Pre-heating the EHC is an effective way to reduce cold-start emissions, among other possible EHC strategies. However, it might not always be possible to use pre-heating if the engine-start time is uncertain. In such a case, pre-heating can be started when the engine start is known with greater confidence and post-heating the catalyst could be followed. It would then be natural to turn off the EHC when the payoff for the electrical energy spent is no longer effective in engine cold-start emission reduction.

Abstract An aeroengine exhaust plume is one of the important sources of infrared (IR) signature in the 3-5 μm and the 2-3 μm bands. Analysis, characterization, and modeling of the exhaust plume IR emission are needed for insight into its role in aircraft survivability against IR-guided missiles. The IR signature estimation of aeroengine exhaust needs estimation of radiative properties of absorbing-emitting exhaust gases, e.g., carbon dioxide (CO2) and water vapor (H2O). The radiative properties of the gases can be estimated by a mathematical model with a spectroscopic database of these gases. Low-Resolution Transmission (LOWTRAN), Moderate-Resolution Transmission (MODTRAN), High-Resolution Transmission (HITRAN), and High-Temperature Transmission (HITEMP) are some commonly used spectroscopic databases. This study compares Statistical Narrowband (SNB) models with the various other mathematical models used for the estimation of radiative properties of exhaust gases.

Abstract Catalytic converters have been effectively controlling the harmful exhaust gases to meet stringent emission norms. This article presents a new three-way catalyst developed using natural zeolite for effective emission reduction. The step-by-step preparation of the material for the developed catalyst is followed by its characterization using an energy dispersive X-ray (EDX), X-ray diffraction (XRD), and scanning electron microscope (SEM). The testing performed on a synthetic gas test bench (SGTB) shows substantial carbon monoxide (CO), hydrocarbon (HC), and nitric oxide (NO) reduction. Results show a 100% conversion for NO above 280°C, 54.8% for CO at 315°C, and 52% for HC at 500°C. The developed natural zeolite-based catalyst stands out from among current catalysts and can be endorsed for three-way conversions than the synthetic zeolite catalyst.

Abstract The urea-selective catalyst reduction system implemented in commercial vehicles facilitates ensuring compliance with the NOx regulation limit. A significant challenge in urea injection is to comprehend its decomposition chemistry that often leads to the formation of unfavorable deposits in the exhaust system unit. Due to the complex interaction of the multiphase fluid flow and transport processes, a significant degree of uncertainty is associated with the identification of the interacting factors that control the deposit initiation and its growth. A systematic investigation was conducted through numerous experiments to study the factors controlling the urea deposit that guides innovation for new product development. For the first time, the effect of pressure on urea deposits is investigated by heating an aqueous urea solution in a closed system maintained between 30 and 200 psi.

Abstract An investigation into the pre-ashing of new gasoline particulate filters (GPFs) has demonstrated that the filtration efficiency of such filters can be improved by up to 30% (absolute efficiency improvement) when preconditioned using ash derived from a fuel-borne catalyst (FBC) additive. The additive is typically used in diesel applications to enable diesel particulate filter (DPF) regeneration and can be added directly into the fuel tank of the vehicle. This novel result was compared with ash derived from lube oil componentry, which has previously been shown to improve filtration efficiency in GPFs. The lube oil-derived ash utilized in this work improved the filtration efficiency of the GPF by −30%, comparable to the ash derived from the FBC additive.

Abstract Oxides of nitrogen (NOx) represent unwanted by-products from combustion of fossil fuels. NOx can cause significant harm to living beings through decreased air quality. This review summarizes the sources of NOx emissions, regulations established to limit these emissions from on-road transportation, and the technologies developed by the automotive industry to meet these requirements. As regulations continue to establish lower limits for NOx emissions, engine and power technologies are evolving to meet these requirements. Exhaust aftertreatment systems have enabled near-zero tailpipe NOx emissions using NOx reduction catalysts. These catalysts are being further developed for improved low-temperature performance and higher durability. Such improvements are enabled through fundamental understanding of the underlying chemistry governing these catalytic processes.

Abstract An ongoing challenge with Gasoline engines is achieving rapid activation of the three-way catalyst during cold starts in order to minimize pollutant emissions. Retarded combustion is an effective way in achieving rapid light-up of the three-way catalyst and can be facilitated by stratified charge using late fuel injection. This, however, provides insufficient time for fuel entrainment with air, resulting in locally fuel-rich diffusion combustion. Employing a split injection strategy can help tackle these issues. The effects of a split injection strategy, using a high-pressure Solenoid injector, on the in-cylinder charge formation are investigated in the current study. The studies are performed inside an optical Gasoline engine using high-speed particle image velocimetry (PIV) in the central tumble and Omega tumble planes, by means of a high-speed laser and camera operating at a repetition rate of 10 kHz.

Abstract Uncertainty of fuel reserves, environmental crisis, and health concerns arise from transport demands and reliance on fossil fuels. Downsized gasoline turbocharged direct injection (GTDI) engines have been developed and applied to most modern gasoline vehicles, delivering superior efficiency in high-load operation, reduced friction, and weight. But fuel enrichment and late combustion phasing to mitigate knocking combustion have hindered the efficiency benefits at higher loads with high boost. Furthermore, the wide valve-overlap with a three-cylinder setup for the maximum scavenging efficiency produces bursts of short-circuit (SC) air to cause underestimation of the equivalence ratio by the oxygen sensor, resulting in higher tailpipe nitrogen oxides (NOx) emissions with three-way catalyst (TWC) exhaust aftertreatment. Reducing the valve overlap to limit short-circuiting and enrichment will recover the combustion efficiency and the engine ER, but at the cost of high knock onset.

Abstract The energy management of hybrid electric vehicles (HEVs) is a complex subject that can be addressed with the tools provided by optimal control theory. Optimization algorithms explored so far in the literature, like dynamic programming (DP) or equivalent consumption minimization strategy (ECMS), have systematically analyzed the potential CO2 reduction for different topologies and degree of hybridization. However, the management of engine and electric machine (EM) neglects that the catalyst material in the aftertreatment system needs to reach a certain temperature to properly convert pollutant emissions. In this study, the thermal management of the catalyst in a gasoline HEV has been investigated, and two algorithms have been proposed. Two strategies based on the ECMS are presented: the first one explicitly considers the catalyst temperature; the second one keeps the underlying structure of ECMS, but it adds a high-level rule to indirectly encompass catalyst management.

Abstract The aim of this article is to analyze the energy recovery of synthesis gases in an internal combustion engine, in terms of both their general behavior and recommendations for their future composition in production. This article presents an experimental analysis of power and economical parameters of internal combustion engine as a source of propulsion for a cogeneration unit. The power parameters were measured using 13 various low-energy synthesis gases as fuels. Most of them are methane-free synthesis gases. The main components of these synthesis gases were hydrogen, carbon monoxide, methane, carbon dioxide, and nitrogen. The composition of the synthesis gases responded to various waste gasification technologies. The mass lower heating value of the selected synthesis gases ranged from 4 to 8 MJ/kg.

Abstract Nitrous oxide (N2O) is both an ozone depleting gas and a potent greenhouse gas (GHG), having a global warming potential (GWP) value nearly 300 times that of carbon dioxide (CO2). While long known to be a trace by-product of combustion, N2O was not considered a pollutant of concern until the introduction of the three-way catalyst (TWC) on light-duty gasoline vehicles in the 1980s. These precious metal-containing catalysts were found to increase N2O emissions substantially. Through extensive research efforts, the effects of catalyst type, temperature, air/fuel ratio, space velocity, and other factors upon N2O emissions became better understood. Although not well documented, N2O emissions from non-catalyst vehicles probably averaged 5-10 mg/mi (on the standard FTP test), while early generation TWC-equipped vehicles exceeded 100 mg/mi. As emissions control systems evolved to meet increasingly stringent criteria pollutant standards, N2O emissions also decreased.

Abstract Continuously tightening Particulate Matter (PM) and Particulate Number (PN) regulations make Gasoline Particulate Filters (GPFs) with high filtration efficiency and low pressure drop highly desirable as Gasoline Direct Injection (GDI) engines increase in market share. Due to packaging constraints, GPFs are often coated with three-way catalyst (TWC) materials to achieve four-way functionality. Therefore, it is critical to investigate the effects of various washcoating strategies on GPF performance. A three-dimensional (3D) Computational Fluid Dynamics (CFD) model, along with an analytical filtration model was created. A User Defined Function (UDF) was implemented to define the heterogeneous properties of the GPF wall due to washcoating or ash membrane application. The model demonstrated the ability to predict transient filtration efficiency and pressure drop of uncoated and washcoated GPFs.

Abstract Different aftertreatment systems consisting of a combination of selective catalytic reduction (SCR) and SCR catalyst on a diesel particulate filter (DPF) (SCR-F) are being developed to meet future oxides of nitrogen (NOx) emissions standards being set by the Environmental Protection Agency (EPA) and the California Air Resources Board (CARB). One such system consisting of a SCRF® with a downstream SCR was used in this research to determine the system NOx reduction performance using experimental data from a 2013 Cummins 6.7L ISB diesel engine and model data. The contribution of the three SCR reactions on NOx reduction performance in the SCR-F and the SCR was determined based on the modeling work. The performance of a SCR was simulated with a one-dimensional (1D) SCR model. A NO2/NOx ratio of 0.5 was found to be optimum for maximizing the NOx reduction and minimizing NH3 slip for the SCR for a given value of ammonia-to-NOx ratio (ANR).

Abstract Powertrain simulations and catalyst studies showed the efficiency credits and feasibility of onboard reforming as a way to recover waste heat from heavy duty vehicles (HDVs) fueled by natural gas (NG). Onboard reforming involves 1) injecting NG into the exhaust gas recycle (EGR) loop of the HDV, 2) reforming NG on a catalyst in the EGR loop to hydrogen and carbon monoxide, and 3) combusting the reformed fuel in the engine. The reformed fuel has increased heating value (4-10% higher LHV) and flame speed over NG, allowing stable flames in spark ignition (SI) engines at EGR levels up to 25-30%. A sulfur-tolerant reforming catalyst was shown to reform a significant amount of NG (15-30% conversion) using amounts of precious metal near the current practice for HDV emissions control (10 g rhodium). Engine simulations showed that the high EGR levels enabled by onboard reforming are used most effectively to control engine load instead of waste-gating or throttling.

Abstract Catalytic converters, a primary component in most automotive emissions control systems, do not function well until they are heated substantially above ambient temperature. As the primary energy for catalyst heating comes from engine exhaust gases, plug-in hybrid electric vehicles (PHEVs) that have the potential for short and infrequent use of their onboard engine may have limited energy available for catalytic converter heating. This article presents a comparison of multiple hybrid supervisory control strategies to determine the ability to avoid engine cold starts during a blended charge-depleting propulsion mode. Full vehicle and catalytic converter simulations are performed in parallel with engine dynamometer testing in order to examine catalyst temperature variations during the course of the US06 City drive cycle. Emissions and energy consumption (E&EC) calculations are also performed to determine the effective number of engine starts during the drive cycle.

Abstract In the development of hydrocarbon (HC) traps for E85 fuel vehicle emission control, the addition of palladium (Pd) to BEA zeolite was studied for trapping and decreasing cold-start ethanol emissions. BEA zeolite after a laboratory aging at 750°C for 25 hours released nearly all of the trapped ethanol as unconverted ethanol at low temperature, and some ethene was released at a higher temperature by a dehydration reaction. The addition of Pd to BEA zeolite showed a decrease in the release of unconverted ethanol emissions even after the lab aging. The release of methane (CH4), acetaldehyde (CH3CHO), carbon monoxide (CO), and CO2 from Pd-BEA zeolite during desorption (temperature programmed desorption (TPD)) demonstrated that multiple ethanol reaction mechanisms were involved including dehydrogenation and decomposition reactions.

Abstract Dynamic stresses exist in parts of a catalyst muffler caused by the vibration of a moving vehicle, and it is important to clarify and predict the vibration response properties for preventing fatigue failures. Assuming a vibration isolating installation in the vehicle frame, the vibration transmissibility and local dynamic stress of the catalyst muffler were examined through a vibration machine. Based on the measured data and by systematically taking vibration theories into consideration, a new prediction method of the vibration modes and parameters was proposed that takes account of vibration isolating and damping. A lumped vibration model with the six-element and one mass point was set up, and the vibration response parameters were analyzed accurately from equations of motion. In the vibration test, resonance peaks from the hanging bracket, rubber bush, and muffler parts were confirmed in three excitation drives, and local stress peaks were coordinate with them as well.

Abstract Directional drilling rigs and hydraulic stimulation equipment typically use diesel fueled compression ignition (CI) engines. The majority of these engines are compliant with US Environmental Protection Agency (EPA) Tier 2 standards. To reduce fuel costs, industry is investing in dual fuel (DF) and dedicated natural gas (DNG) engines. DF engines use diesel oxidation catalysts (DOCs) to reduce CO and NMHC emissions. DNG engines may be either lean-burn or rich-burn and the latter uses three-way catalysts (TWC) to reduce CO, NMHC, and NOx emissions. This research presents in-use catalyst efficiency data collected pre- and post-catalyst for three DF engines and two DNG engines. One DF engine was converted earlier and did not include a DOC. Data were collected from six Tier 2 engines, two CI drilling engines converted to operate as DF, two CI hydraulic fracturing engines converted to operate as DF, and two SI DNG drilling engines.