Technical Paper
Modelling of a Solid-Electrolyte Oxygen Sensor
2002-03-04
2002-01-1293
The limiting values for NOx and HC concentrations in the exhaust gas of SI engines will be further lowered by legislation in many countries during the next years. This necessitates an improvement of the pollution control systems, which is achieved by including the dynamics of the three way catalyst into the control system. Before a control system can be designed, the dynamic behaviour of the exhaust after treatment system including the sensors has to be properly analyzed. As a first step a dynamic model of a solid-electrolyte oxygen sensor has been derived. It was the goal to obtain a better understanding of the cross sensitivities towards both reducing and oxidizing exhaust gas components such as H2, CO, O2 and NO. The model consists of three parts. Firstly, the porous protection layer, where only diffusion is assumed to occur, secondly the porous catalytic electrodes where the redox reactions take place and thirdly the solid electrolyte, where the electric potential is generated.