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Thermal barrier coatings (TBC) are perceived as enabling technology to increase low heat rejection (LHR) diesel engine performance and improve its longevity. The state of the art of thermal barrier coating is the plasma spray zirconia. In addition, other material systems have been investigated for the next generation of thermal barrier coatings. The purpose of this TBC program is to focus on developing binder systems with low thermal conductivity materials to improve the coating durability under high load and temperature cyclical conditions encountered in the real engine. Research and development (R&D) and analysis were conducted on aluminum alloy piston for high output turbocharged diesel engine coated with TBC.

An advanced low heat rejection engine concept has successfully completed a 100 hour endurance test. The combustion chamber components were insulated with thermal barrier coatings. The engine components included a titanium piston, titanium headface plate, titanium cylinder liner insert, M2 steel valve guides and monolithic zirconia valve seat inserts. The tribological system was composed of a ceramic chrome oxide coated cylinder liner, chrome carbide coated piston rings and an advanced polyolester class lubricant. The top piston compression ring Included a novel design feature to provide self-cleaning of ring groove lubricant deposits to prevent ring face scuffing. The prototype test engine demonstrated 52 percent reduction in radiator heat rejection with reduced intake air aftercooling and strategic forced oil cooling.

An experimental investigation of the effects of ceramic coatings on diesel engine performance and exhaust emissions was conducted. Tests were carried out over a range of engine speeds at full load for a standard metal piston and two pistons insulated with 0.5 mm and 1.0 mm thick ceramic coatings. The thinner (0.5 mm) ceramic coating resulted in improved performance over the baseline engine, with the gains being especially pronounced with decreasing engine speed. At 1000 rpm, the 0.5 mm ceramic coated piston produced 10% higher thermal efficiency than the metal piston. In contrast, the relatively thicker coating (1 mm), resulted in as much as 6% lower thermal efficiency compared to baseline. On the other hand, the insulated engines consistently presented an attractive picture in terms of their emissions characteristics. Due to the more complete combustion in the insulated configurations, exhaust CO levels were between 30% and 60% lower than baseline levels.

An advanced low heat rejection engine concept has been selected based on a trade-off between thermal insulating performance and available technology. The engine concept heat rejection performance is limited by available ring-liner tribology and requires cylinder liner cooling to control the piston top ring reversal temperature. This engine concept is composed of a titanium piston, headface plate and cylinder liner insert with thermal barrier coatings. Monolithic zirconia valve seat inserts, and thermal barrier coated valves and intake-exhaust ports complete the insulation package. The tribological system is composed of chrome oxide coated cylinder, M2 steel top piston ring, M2 steel valve guides, and an advanced polyol ester class lubricant.

An experimental study of the effects of thin ceramic thermal barrier coatings on the performance of a spark-ignited gasoline engine was conducted. A modified 2.5 liter GM engine with ceramic-coated pistons, liners, head, valves and ports was used. Experimental results obtained from the ceramic engine were compared with baseline metal engine data. It was shown that at low-speed part-load conditions encountered in typical driving cycles the ceramic engine could achieve up to 18% higher brake power and up to 10% lower specific fuel consumption. At wide open throttle conditions, the two engines exhibited similar characteristics, except at high speeds where the metal engine showed better performance at the expense of inferior fuel economy. The ceramic coating did not produce any observable knock in the engine and showed no significant wear at the conclusion of the testing phase.

A highly effective thermal insulating piston concept with high projected durability characteristics has been developed by means of computer aided modelling, thermal rig bench screening, and small-bore engine testing. The piston concept is composed of a relatively low thermal conductivity titanium alloy type 6242 structural material and a 1.25 mm thick slurry densified thermal barrier coating. The piston material, structural configuration, and detail design features were selected through computer aided modelling and qualified through small-bore engine testing. Screening of plasma sprayed thermal barrier coatings was performed on a simple thermal test rig and final selection of a system was made through small-bore engine testing.

Significant progress has been achieved in the development of advanced high-temperature, insulated, in-cylinder components for high-power-output miliraty diesel engines. Computer aided modeling and small-bore engine component testing have both been utilized extensively during the exploratory development process. Specific insulated optimal designs for the piston, cylinder headface, and cylinder liner have been identified. The designs all utilize thermal barrier coatings, titanium alloy, and interfacial air-gaps to provide thermal resistance. Finite element modeling including diesel cycle simulation has been utilized to screen and optimize material and design concepts relative to program objectives, while small-bore engine testing has been utilized to demonstrate component integrity. An improved slurry densified thermal barrier coating has been demonstrated by testing on a high temperature small-bore engine.

Finite element models of various fast-response thermocouple designs have been developed. Due to the small differences in thermal properties between thermoelements and metal engine components, standard co-axial thermocouples can measure transient temperatures of metal components within an accuracy of 98%. However, these relatively small errors in total temperature measurement translate into as high as 30% errors in indicated peak-to-peak-temperature swings for iron surfaces. The transient swing errors result in up to 30% errors in peak heat flux rates to iron surfaces. These peak heat flux errors can be substantially larger if coaxial thermocouples are used for heat flux measurements in aluminum or ceramic surfaces. Increasing the thin film thickness is a compromise solution to reduce the discrepancy in peak heat flux measured with coaxial designs in metal engines. An alternative overlapping thin film thermocouple design has also been evaluated.

Significant headway has recently been achieved in advanced high-temperature component design. Progress has been made in selecting a highly effective thermal insulating design composed of a titanium alloy piston with 1.0 mm thermal barrier coating which provides the same level of insulating effectiveness as a ductile iron piston with 2.5 mm coating. The low thermal conductivity of Titanium Alloy 6242 inherently provides a significant level of thermal resistance which effectively reduces the required coating thickness, reduces thermal stresses, and nearly eliminates coating thermal expansion mismatch. Other benefits of the titanium alloy piston include low weight and increased high temperature strength. Thermal rig testing has been completed on several plasma-sprayed zirconia coatings and a critical durability threshold thickness of 1.25 mm has been identified. In addition, zirconia coatings and chrome-oxide-densified Eirconia coatings have been screened in a small bore diesel engine.