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Fossil fuels and biofuels usage in internal combustion engines are the main source for vehicular propulsion. This justifies the intense worldwide research and development to comply with the challenges of increasing efficiency and emissions reduction. The modeling of commercial fuels and engine combustion processes presents great challenges. There is also the need to better understand how different fuel components interact and influence engine combustion and performance parameters. In previous works, components selection and engine dynamometer tests were done to identify representative surrogate fuels for commercial Brazilian gasoline. It was concluded that formulations with n-heptane, iso-octane, toluene and ethanol can be used to model oxygenated gasolines. Methodologies were implemented to evaluate the influence of the fuel components on fuel properties and several engine combustion and performance parameters.

Gasoline is a complex mixture, composed of hundreds of different hydrocarbons. Surrogate fuels decrease the complexity of gasoline and are being used to improve the understanding of internal combustion engines (ICEs) fundamental processes. Computational tools are largely used in ICE development and performance optimization using simple fuels, because it is still not possible to completely model a commercial gasoline. The kinetics and interactions among all the chemical constituents are not yet fully understood, and the computational cost is also prohibitive. There is a need to find suitable surrogate fuels, which can reproduce commercial fuels performance and emissions behavior, in order to develop improved models for fuel combustion in practical devices, such as homogeneous charge compression ignition (HCCI) and spark ignition (SI) engines. Representative surrogate fuels can also be used in fuel development processes.

Accurate simulation of fuel properties influence in internal combustion engines performance is a very complex approach and combines many physical and chemical concepts such as combustion phenomena, chemical kinetics, fluid dynamics, turbulence and thermodynamics. The right modelling of that is still a challenge and currently available software packages for engines simulation usually consider standard or surrogate fuels. The objective of this paper is the prediction of gasolines performance in internal combustion engines as an auxiliary tool in researches and developments of new fuels, reducing experimental timing and costs. It is proposed the use of kriging metamodels based on bench test results of a flexible fuel engine running with distinct blends of iso-octane, n-heptane, toluene and ethanol, to predict performance, energetic efficiency and pollutant emissions in function of fuel properties and operating conditions.

The automotive industry usually adopts the crankshaft angle between 8° and 10° after piston top dead center for the CA50 (crank angle of 50% of mass fraction burned) in order to set the maximum break torque spark timing calibration in Otto cycle engines. There are few studies of the influence of fuel composition, such as the ethanol content, on the CA50 at the maximum torque operating condition. The subject is relevant to the extent that the fuels used in the Brazilian domestic market are different from those usually adopted abroad. The Brazilian gasoline must contain, by law, a volumetric percentage between 18% and 27% of anhydrous ethanol in its composition and, currently, this level is set at 27%. The introduction of flex fuel vehicles in the domestic market in 2003, which now represent most of the new vehicles production in the Country, allowed the use of any blend of national gasoline and hydrous ethanol. This significantly expanded the range of fuel properties variation.

Commercial gasoline is composed of hundreds of hydrocarbon components. Surrogate fuels that decrease the chemical and physical complexity of gasoline are being used to allow a better understanding of the processes involved in the interaction between fuels and internal combustion engines (ICEs). Based on previous published works about methodologies for fuel development using surrogate fuels, the aim of this paper is to present further results on the effect of individual components and fuel fractions on the combustion and performance parameters of spark ignition engines. SI engine dynamometer tests were conducted using ten mixtures of iso-octane, toluene, n-heptane and ethanol. Response surface models were statistically developed to analyze the interactions between fuel components, fuel properties and engine performance.

Gasoline is a complex mixture that possesses a quasi-continuous spectrum of hydrocarbon constituents. Surrogate fuels that decrease the chemical and/or physical complexity of gasoline can be used to enhance the understanding of fundamental processes involved in the interaction between fuels and internal combustion engines (ICEs). The aim of this paper is to present methodologies for fuel development and show how surrogate fuels can be used to investigate the effect of individual components and fuel fractions on fuel properties and the performance of commercial engines. For this purpose, experiments were designed and SI engine dynamometer tests were conducted using ten mixtures of iso-octane, toluene, n-heptane and ethanol. Response surface models were statistically developed to analyze the interactions between fuel components, fuel properties and engine performance.

An experimental investigation was performed on an engine dynamometer to study in cylinder pressure curve and combustion parameters variability with ethanol addition. It was used a Flex-Fuel engine, 1.4 L, 4 cylinders, with a programmable engine control unit to optimize the calibration for different blends of Brazilian gasoline and hydrous ethanol. Engine was calibrated for maximum break torque limited by knocking. In-cylinder pressure was measured by using a pressure sensor installed on the spark plug and analyzed by a combustion data system. Combustion duration, mass fraction burned, indicated mean effective pressure (IMEP) and others were calculated based on in-cylinder pressure curve data. The combustion variability was analyzed from 300 recorded engine cycle for each operating condition. Results for some operating conditions indicated that ethanol addition can reduce combustion variability on a non linear pattern.

In Brazilian market, Flex-Fuel vehicles represented over 85% of new light-duty vehicles sold in 2010. These vehicles can use gasoline blended with anhydrous ethanol (18 to 25% v/v), 100% of hydrous ethanol (contains from 6,2 to 7,4% w/w of water) or any blend of these fuels. Some studies regarding Flex-Fuel technology are being made in Brazil, but there are not many published information about fuel properties of different ethanol-gasoline blends. Also, it is important to better understand emissions of aldehydes, unburned ethanol and total hydrocarbons of different ethanol blends on gasoline. A Flex-Fuel engine, 1.4 l, 4 cylinders was tested on a dynamometer. A FTIR (Fourier Transform Infrared analyzer) bench measured aldehydes, unburned ethanol and total hydrocarbons. It was used Gasoline with 25% of anhydrous ethanol was used as a reference fuel (E25). E25 was blended with different hydrous ethanol contents such as 30% (H30), 50% (H50), 80% (H80) and 100% (H100).

In Brazilian market, Flex-Fuel vehicles represented over 90% of new light-duty vehicles sold in 2009. These vehicles can use gasoline blended with anhydrous ethanol (20 to 25% v/v), 100% of hydrous ethanol (contains from 6,2 to 7,4% w/w of water) or any blend of these fuels. An experimental investigation was done to study fuel consumption, emissions and in-cylinder pressure data of a Flex-Fuel Otto engine, 1.4 L, 4 cylinders. It used gasoline with 22% of anhydrous ethanol as a reference fuel (E22). E22 was blended with different hydrous ethanol contents such as 50% (H50) and 80% (H80), also a 100% hydrous ethanol H100) was used. The main fuel properties were analyzed as part of this work. To control the engine operation, a programmable ECU (Engine Control Unit) was used, allowing spark timing calibration either for maximum break torque (MBT) or to keep the engine below the knocking limit.

Brazil is known for its long experience on using alternative fuels, mainly ethanol for light duty vehicles. In 2002, it was released the Flexible fuel car that can run with gasohol (gasoline with 22% of ethanol), hydrated ethanol or any blend of these fuels. By the end of 2006, national production of these vehicles represented around 80% of the total. Brazil is also the second world fleet of Natural Gas Vehicles (NGV), with more than 1,4 million light duty converted vehicles. This paper describes the development of a computational thermodynamic model of compression, combustion and expansion processes of gasohol, ethanol and Natural Gas (NG) for the cylinder pressure curve prediction of a Flexible Fuel engine, working with a NG kit installed. The combustion process is modeled using a Wiebe function, which establishes the mass fraction of burned fuel. Convective heat transfer to cylinder walls is estimated with an empirical correlation for heat transfer coefficient determination.

This paper describes the development of a computational thermodynamic model of compression, combustion and expansion processes of gasohol, ethanol and Natural Gas (NG) for the cylinder pressure curve prediction of a Flexible Fuel engine, working with a NG kit installed. The combustion process is modeled using a Wiebe function. Equations for specific heat at constant pressure (Cp) were developed for each fuel for temperatures up to 4000 K. The model output generates the cylinder gas pressure and temperature, work output and heat release profiles as functions of crank angle, allowing studies of engine performance parameters in different working conditions for each fuel. The differences between the experimental and simulation results were lower than 4% for the maximum cylinder pressure value.