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The Argon Power Cycle (APC) is a novel zero-emission closed-loop argon recirculating engine cycle which has been developed by Noble Thermodynamics Systems, Inc. It provides a significant gain in indicated thermal efficiency of the reciprocating engine by breathing oxygen and argon rather than air. The use of argon, a monatomic gas, greatly increases the specific heat ratio of the working fluid, resulting in a significantly higher ideal Otto cycle efficiency. This technology delivers a substantial improvement in reciprocating engine performance, maximizing the energy conversion of fuel into useful work. Combined Heat and Power (CHP) operating under the APC represents a promising solution to realize a net-zero-carbon future, providing the thermal energy that hard-to-electrify manufacturing processes need while at the same time delivering clean, dispatchable, and efficient power.

The internal combustion engine (ICE) has long dominated the heavy-duty sector by using liquid fossil fuels such as diesel but global commitments by countries and OEMs to reduce lifecycle carbon dioxide (CO2) emissions has garnered interest in alternative fuels like hydrogen. Hydrogen is a unique gaseous fuel that contains zero carbon atoms and has desired thermodynamic properties of high energy density per unit mass and high flame speeds. However, there are challenges related to its adoption to the heavy-duty sector as a drop-in fuel replacement for compression ignition (CI) diesel combustion given its high autoignition resistance. To overcome this fundamental barrier, engine manufacturers are exploring dual fuel combustion engines by substituting a fraction of the diesel fuel with hydrogen which enables fuel flexibility when there is no infrastructure and retrofittability to existing platforms.

The autoignition chemistry of fuels depends on the pressure, temperature, and time history that the fuel-air mixture experiences during the compression stroke. While piezoelectric pressure transducers offer excellent means of pressure measurement, temperature measurements are not commonly available and must be estimated. Even if the pressure and temperature at the intake and exhaust ports are measured, the residual gas fraction (RGF) within the combustion chamber requires estimation and greatly impacts the temperature of the fresh charge at intake valve closing. This work replaced the standard D1 Detonation Pickup of a CFR engine with a rapid sampling valve to allow for in-cylinder gas sampling at defined crank-angle times during the compression stroke. The extracted cylinder contents were captured in an emissions sample bag and its composition was subsequently analyzed in an AVL i60 emissions bench.

This study presents experimental and numerical examination of directly injected (DI) propane and iso-octane, surrogates for liquified petroleum gas (LPG) and gasoline, respectively, at various engine like conditions with the overall objective to establish the baseline with regards to fuel delivery required for future high efficiency DI-LPG fueled heavy-duty engines. Sprays for both iso-octane and propane were characterized and the results from the optical diagnostic techniques including high-speed Schlieren and planar Mie scattering imaging were applied to differentiate the liquid-phase regions and the bulk spray phenomenon from single plume behaviors. The experimental results, coupled with high-fidelity internal nozzle-flow simulations were then used to define best practices in CFD Lagrangian spray models.

Gasoline compression ignition is a promising strategy to achieve high thermal efficiency and low emissions with limited modifications to the conventional diesel engine hardware. It is a partially premixed concept which derives its superiority from higher volatility and longer ignition delay of gasoline-like fuels combined with higher compression ratio typical of diesel engines. The present study investigates the combustion process in a gasoline compression ignition engine using computational fluid dynamics. Simulations are carried out on a single cylinder of a multi cylinder heavy-duty compression ignition engine which operates at a compression ratio of 17:1 and an engine speed of 1038 rev/min. In this study, a late fuel injection strategy is used because it is less sensitive to combustion kinetics compared to early injection strategies, which in turn is a better choice to assess the performance of the spray model.

The current research octane number (RON) and motor octane number (MON) gasoline tests are inadequate for describing the auto-ignition reactivity of fuels in homogeneous charge compression ignition (HCCI) combustion. Intake temperature and engine speed are two important parameters when trying to understand the fuel auto-ignition reactivity in HCCI combustion. The objective of this study was to understand the effect of high intake temperature (between 100 and 200 °C) and engine speed (600 and 900 rpm) on the auto-ignition HCCI reactivity ratings of fuels using an instrumented Cooperative Fuel Research (CFR) engine. The fuels used for this study included blends of iso-octane/n-heptane, toluene/n-heptane, ethanol/n-heptane, and gasolines with varying chemical compositions and octane levels. The CFR engine was operated at 600 and 900 rpm with an intake pressure of 1.0 bar and an excess air ratio (lambda) of 3.

This work focuses on reducing the computational effort of a 0-dimensional combustion model developed for compression ignition engines operating on gasoline-like fuels. As in-cylinder stratification significantly contributes to the ignition delay, which in turn substantially influences the entire gasoline compression ignition combustion process, previous modeling efforts relied on the results of a 1-dimensional spray model to estimate the in-cylinder fuel stratification. Insights obtained from the detailed spray model are leveraged within this approach and applied to a reduced order model describing the spray propagation. Using this computationally efficient combustion model showed a reduction in simulation time by three orders of magnitude for an entire engine cycle over the combustion model with the 1-dimensional spray model.

An increase in spark-ignition engine efficiency can be gained by increasing the engine compression ratio, which requires fuels with higher knock resistance. Oxygenated fuel components, such as methanol, ethanol, isopropanol, or iso-butanol, all have a Research Octane Number (RON) higher than 100. The octane numbers (ON) of fuels are rated on the CFR F1/F2 engine by comparing the knock intensity of a sample fuel relative to that of bracketing primary reference fuels (PRF). The PRFs are a binary blend of iso-octane, which is defined to an ON of 100, and n-heptane, which represents an ON of 0. Above 100 ON, the PRF scale continues by adding diluted tetraethyl lead (TEL) to iso-octane. However, TEL is banned from use in commercial gasoline because of its toxicity. The ASTM octane number test methods have a “Fit for Use” test that validate the CFR engine’s compliance with the octane testing method by verifying the defined ON of toluene standardization fuels (TSF).

Multi-mode combustion strategies may provide a promising pathway to improve thermal efficiency in light-duty spark ignition (SI) engines by enabling switchable combustion modes, wherein an engine may operate under advanced compression ignition (ACI) at low load and spark-assisted ignition at high load. The extension from the SI mode to the ACI mode requires accurate control of intake charge conditions, e.g., pressure, temperature and equivalence ratio, in order to achieve stable combustion phasing and rapid mode-switches. This study presents results from computational fluid dynamics (CFD) analysis to gain insights into mixture charge formation and combustion dynamics pertaining to auto-ignition processes. The computational study begins with a discussion of thermal wall boundary condition that significantly impacts the combustion phasing.

The modeling of fuel jet atomization is key in the characterization of Internal Combustion (IC) engines, and 3D Computational Fluid Dynamics (CFD) is a recognized tool to provide insights for design and control purposes. Multi-hole injectors with counter-bored nozzle are the standard for Gasoline Direct Injection (GDI) applications and the Spray-G injector from the Engine Combustion Network (ECN) is considered the reference for numerical studies, thanks to the availability of extensive experimental data. In this work, the behavior of the Spray-G injector is simulated in a constant volume chamber, ranging from sub-cooled (nominal G) to flashing conditions (G2), validating the models on Diffused Back Illumination and Phase Doppler Anemometry data collected in vaporizing inert conditions.

This paper presents a computational fluid dynamics (CFD) study of the Engine Combustion Network (ECN) Spray G under non-vaporizing condition, focusing on the impacts of fuel properties as well as realistic geometry on the atomization process. The large-eddy-simulation method, coupled with the volume-of-fluid method, is used to model the high-speed turbulent two-phase flow. A moving-needle boundary condition is applied to capture the internal flow boundary condition accurately. The injector geometry was measured with micron-level resolution using x-ray tomographic imaging at the Advanced Photon Source at Argonne National Laboratory, providing detailed machining tolerance and defects from manufacturing and a realistic rough surface. A 2.5-μm fine mesh is used to sufficiently resolve the details of liquid-gas interface and the breakup process.

Additive manufacturing was used to fabricate a head for an automotive-scale single-cylinder engine operating on natural gas. The head was consisted of a bimetallic composition of stainless steel and bronze. The engine performance using the bimetallic head was compared against the stock cast iron head. The heads were tested at two speeds (1200 and 1800 rpm), two brake mean effective pressures (6 and 10 bar), and two equivalence ratios (0.7 and 1.0). The bimetallic head showed good durability over the test and produced equivalent efficiencies, exhaust temperatures, and heat rejection to the coolant to the stock head. Higher combustion temperatures and advanced combustion phasing resulted from use with the bimetallic head. The implication is that with optimization of the valve timing, an efficiency benefit may be realized with the bimetallic head.

Advanced compression ignition (ACI) operation in gasoline direct injection (GDI) engines is a promising concept to reduce fuel consumption and emissions at part load conditions. However, combustion phasing control and the limited operating range in ACI mode are a perennial challenge. In this study the combined impact of fuel properties and engine control strategies in ACI operation are investigated. A design of experiments method was implemented using a three level orthogonal array to determine the sensitivity of engine control parameters on the engine load, combustion noise and stability under low load ACI operation for three RON 98 gasoline fuels, each exhibiting disparate chemical composition. Furthermore, the thermodynamic state of the compression histories was studied with the aid of the pressure-temperature framework.

While experimental data measured directly on the engine are very valuable, there is a limitation of what measurements can be made without modifying the engine or the process that is being investigated, such as cylinder temperature. In order to supplement the experimental results, a Three Pressure Analysis (TPA) GT-Power model of the Cooperative Fuel Research (CFR) engine was previously developed and validated for estimating cylinder temperature and residual fraction. However, this model had only been validated for normal and knocking spark ignition (SI) combustion with RON-like intake conditions (naturally aspirated, <52 °C). This work presents improvements made to the GT-Power model and the expansion of its use for HCCI combustion. The burn rate estimation sub-model was modified to allow for low temperature heat release estimation and compression ignition operation.

A zero-dimensional heat release model was developed for compression ignition engines. This type of model can be utilized for parametric studies, off-line optimization to reduce experimental efforts as well as model-based control strategies. In this particular case, the combustion model, in a simpler form, will be used in future efforts to control the combustion in compression ignition engines operating on gasoline-like fuels. To allow for a realistic representation of the in-cylinder combustion process, a spray model has been employed to allow for the quantification of fuel distribution as well as turbulent kinetic energy within the injection spray. The combustion model framework is capable of reflecting premixed as well as mixing controlled combustion. Fuel is assigned to various combustion events based on the air-fuel mixture within the spray.

Currently there is a significant research effort being made in gasoline spark/ignition (SI) engines to understand and reduce cycle-to-cycle variations. One of the phenomena that presents this cycle-to-cycle variation is combustion knock, which also happens to have a very stochastic behavior in modern SI engines. Conversely, the CFR octane rating engine presents much more repeatable combustion knock activity. The aim of this study is to assess the impact of fuel composition on the cycle to cycle variation of the pressure and timing of end gas autoignition. The variation of cylinder conditions at the timing of end-gas autoignition (knock point) for a wide selection of cycle ensembles have been analyzed for several constant RON 98 fuels on the CFR engine, as well as in a modern single-cylinder gasoline direct injection (GDI) SI engine operated at RON-like intake conditions.

A multi-mode operation strategy, wherein an engine operates compression ignited at low load and spark ignited at high load, is an attractive way of achieving better part-load efficiency in a light duty spark ignition (SI) engine. Given the sensitivity of compression ignition operation to in-cylinder conditions, one of the critical requirements in realizing such strategy in practice, is accurate control of intake charge conditions - pressure (P), temperature (T) and equivalence ratio (φ), in order to achieve stable combustion and enable rapid mode-switches. This paper presents the first of a two part study, correlating ignition delay data for five RON98 gasoline blends measured under engine-relevant operating conditions in a rapid compression machine (RCM), to the cylinder conditions obtained from a modern SI engine operated in compression ignition mode.

A multi-mode operation strategy, wherein an engine operates compression ignited at low load and spark-ignited at high load, is an attractive way to achieve better part-load efficiency in light duty, spark-ignition (SI) engines, while maintaining robust operation and control across the operating map. Given the sensitivity of compression ignition operation to in-cylinder conditions, one of the critical requirements in realizing such a strategy in practice is accurate control of intake charge conditions - pressure, temperature, as well as fuel loading, to achieve stable combustion and enable rapid mode-switches. A reliable way of characterizing fuels under such operating schemes is key.

Fuel stratification effects on the combustion and emissions behaviors for partially premixed compression ignition (PPCI) combustion of a high reactivity gasoline (research octane number of 80) was investigated using the third generation Gasoline Direct-Injection Compression Ignition (Gen3 GDCI) multi-cylinder engine. The PPCI combustion mode was achieved through a double injection strategy. The extent of in-cylinder fuel stratification was tailored by varying the start of second fuel injection timing (SOIsecond) while the first fuel injection event was held constant and occurred during the intake stroke. Based on the experimental results, three combustion characteristic zones were identified in terms of the SOIsecond - CA50 (crank angle at 50% cumulative heat release) relationship: (I) no response zone (HCCI-like combustion); (II) negative CA50 slope zone: (early PPCI mode); and (III) positive CA50 slope zone (late PPCI mode).

Diesel-fueled, heavy-duty engines are critical to global economies, but unfortunately they are currently coupled to the rising price and challenging emissions of Diesel fuel. Public awareness and increasingly stringent emissions standards have made Diesel OEMs consider possible alternatives to Diesel, including electrification, fuel cells, and spark ignition. While these technologies will likely find success in certain market segments, there are still many applications that will continue to require the performance and liquid-fueled simplicity of Diesel-style engines. Three-way catalysis represents a possible low-cost and highly-effective pathway to reducing Diesel emissions, but that aftertreatment system has typically been incompatible with Diesel operation due to the prohibitively high levels of soot formation at the required stoichiometric fuel-air ratios. This paper explores a possible method of integrating three-way catalysis with Diesel-style engine operation.