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A significant amount of harmful emissions pass unreacted through catalytic after-treatment devices for IC engines before the light-off temperature is reached, despite the high conversion efficiency of these systems in fully warm conditions. Further tightening of fleet targets and worldwide emission regulations will make a faster catalyst light-off to meet legislated standards hence reduce the impact of road transport on air quality even more critical. This work investigates the effect of adding hydrogen (H2) at levels up to 2500 ppm into the exhaust gases produced by combustion of various oxygenated C2-, C4- and renewable fuel molecules blended at 20 % wt/wt with gasoline on the light-off performance of a commercially available three-way catalyst (TWC) (0.61 L, Pd/Rh/Pt - 19/5/1, 15g). The study was conducted on a modified naturally aspirated, 1.4 L, four-cylinder, direct-injected, spark-ignition engine.

The conversion of lignocellulosic biomass to liquid fuels presents an alternative to the current production of renewable fuels for IC engines from food crops. However, realising the potential for reductions in net CO2 emissions through the utilisation of, for example, waste biomass for sustainable fuel production requires that energy and resource inputs into such processes be minimised. This work therefore investigates the combustion and emission characteristics of five intermediate platform molecules potentially derived from lignocellulosic biomass: gamma-valerolactone (GVL), methyl valerate, furfuryl alcohol, furfural and 2-methyltetrahydrofuran (MTHF). The study was conducted on a naturally aspirated, water cooled, single cylinder spark-ignition engine. Each of the platform molecules were blended with reference fossil gasoline at 20 % wt/wt.

Development of new fuels and engine combustion strategies for future ultra-low emission engines requires a greater level of insight into the process of emissions formation than is afforded by the approach of engine exhaust measurement. The paper describes the development of an in-cylinder gas sampling system consisting of a fast-acting, percussion-based, poppet-type sampling valve, and a heated dilution tunnel; and the deployment of the system in a single cylinder engine. A control system was also developed for the sampling valve to allow gas samples to be extracted from the engine cylinder during combustion, at any desired crank angle in the engine cycle, while the valve motion was continuously monitored using a proximity sensor. The gas sampling system was utilised on a direct injection diesel engine co-combusting a range of hydrogen-diesel fuel and methane-diesel fuel mixtures.

Current developments in fuels and emissions regulations are resulting in an increasingly severe operating environment for diesel fuel injection systems. The formation of deposits within the holes or on the outside of the injector nozzle can affect the overall system performance. The rate of deposit formation is affected by a number of parameters, including operating conditions and fuel composition. For the work reported here an accelerated test procedure was developed to evaluate the relative importance of some of these parameters in a high pressure common rail fuel injection system. The resulting methodology produced measurable deposits in a custom-made injector nozzle on a single-cylinder engine. The results indicate that fuels containing 30%v/v and 100% Fatty Acid Methyl Ester (FAME) that does not meet EN 14214 produced more deposit than an EN590 petroleum diesel fuel.

The fuel economy and emissions performance of a Diesel engine is strongly influenced by the fuel injection process. This paper presents early results of an experimental investigation into diesel spray development carried out in a novel in-house developed optical pressure chamber capable of operating at pressure up to 50 bar and temperatures up to 900 K. The spatial evolution of a diesel spray tends to experience many transitory macroscopic phenomena that directly influence the mixing process. These phenomena are not considered highly reproducible and are extremely short lived, hence recording and understanding these transient effects is difficult. In this study, high-speed backlight-illuminated imaging has been employed in order to capture the transient dynamics of a short signal duration diesel spray injected into incremental back pressures and temperatures reaching a maximum of 10 bar and 473 K respectively.

Biodiesel is a renewable fuel which can be used as a direct replacement for fossil Diesel fuel as a calorific source in Diesel Engines. It consists of fatty acid mono-alkyl esters, which are produced by the trans-esterification reaction of plant oils with monohydric alcohols. The Plant oils and alcohols can both be derived from biomass, giving this fuel the potential for a sustainable carbon dioxide neutral life-cycle, which is an important quality with regard to avoiding the net emission of anthropogenic greenhouse gases. Depending on its fatty ester composition, Biodiesel can have varying physical and chemical properties which influence its combustion behaviour in a Diesel engine. It has been observed by many researchers that Biodiesel can sometimes lead to an increase in emissions of oxides of nitrogen (NOx) compared to fossil Diesel fuel, while emitting a lower amount of particulate mass.

For a spark-ignition engine, the parasitic loss suffered as a result of conventional throttling has long been recognised as a major reason for poor part-load fuel efficiency. While lean, stratified charge, operation addresses this issue, exhaust gas aftertreatment is more challenging compared with homogeneous operation and three-way catalyst after-treatment. This paper adopts a different approach: homogeneous charge direct injection (DI) operation with variable valve actuations which reduce throttling losses. In particular, low-lift and early inlet valve closing (EIVC) strategies are investigated. Results from a thermodynamic single cylinder engine are presented that quantify the effect of two low-lift camshafts and one standard high-lift camshaft operating EIVC strategies at four engine running conditions; both, two- and single-inlet valve operation were investigated. Tests were conducted for both port and DI fuelling, under stoichiometric conditions.

Synthetic bio-fuels, which can be obtained through the gasification of biomass into synthesis gas and the subsequent catalytic reaction of the synthesis gas into liquid fuel molecules, could play a key-role in providing a sustainable source of automotive fuels during the coming decades. This paper presents an attempt to understand the effect of molecular structure of potential oxygenated synthetic bio-fuel molecules of different structure on the diesel combustion process in both stratified and homogeneous combustion modes. Specifically, the effects of molecular structure on the energy release rates, gaseous exhaust emissions and the sub-micron particulate matter distribution were examined. The experiments were carried out on a single-cylinder direct-injection diesel engine using a specially adapted common-rail fuel-system which allowed the injection of small single-molecule fuel samples at high pressure.

The effect on the intake flow field, air fuel mixing processes, thermodynamic performance and emissions output has been investigated for a range of valve operating profiles. A standard speed load point of 2000 rpm and 2.7 bar IMEP720° has been reached by throttling the intake whilst running standard cam profiles, by early closing of both inlet valves (EIVC) and by early closing of each inlet individually to generate bulk swirl motions within the cylinder. Data has been recorded at stoichiometric air fuel ratios for both direct injection and port fuelled operation. The valve profiles have been applied to two single cylinder homogeneous gasoline direct injection (GDI) spark ignition engines, developed to investigate the potential of controlling engine load by limiting the inducted air mass using fully variable valve timing (FVVT) to reduce pumping losses at part load.

Controlled Auto-Ignition (CAI) combustion was realised in a production type 4-stroke 4-cylinder gasoline engine without intake charge heating or increasing compression ratio. The CAI engine operation was achieved using substantially standard components modified only in camshafts to restrict the gas exchange process The engine could be operated with CAI combustion within a range of load (0.5 to 4 bar BMEP) and speed (1000 to 3500 rpm). Significant reductions in both specific fuel consumption and CO emissions were found. The reduction in NOx emission was more than 93% across the whole CAI range. Though unburned hydrocarbons were higher under the CAI engine operation. In order to evaluate the potential of the CAI combustion technology, the European NEDC driving cycle vehicle simulation was carried out for two identical vehicles powered by a SI engine and a CAI/SI hybrid engine, respectively.

Controlled Auto-Ignition (CAI) combustion has been achieved in a production type 4-stroke multi-cylinder gasoline engine. The engine was based on a Ford 1.7L Zetec-SE 16V engine with a compression ratio of 10.3, using substantially standard components modified only in design dimensions to control the gas exchange process in order to significantly increase the trapped residuals. The engine was also equipped with Variable Cam Timing (VCT) on both the intake and exhaust camshafts. It was found that the largely increased trapped residuals alone were sufficient to achieve CAI in this engine and with VCT, a range of loads between 0.5 and 4 bar BMEP and engine speeds between 1000 and 3500 rpm were mapped for CAI fuel consumption and exhaust emissions. The measured CAI results were compared with those of Spark Ignition (SI) combustion in the same engine but with standard camshafts at the same speeds and loads.

This paper presents results from an experimental programme researching the in-cylinder conditions necessary to obtain homogenous CAI (or HCCI) combustion in a 4-stroke engine. The fuels under investigation include three blends of Unleaded Gasoline, a 95 RON Primary Reference Fuel, Methanol, and Ethanol. This work concentrates on establishing the CAI operating range with regard to Air/Fuel ratio and Exhaust Gas Re-circulation and their effect on the ignition timing, combustion rate and variability, Indicated thermal efficiency, and engine-out emissions such as NOx. Detailed maps are presented, defining how each of the measured variables changes over the entire CAI region. Results indicate that the alcohols have significantly higher tolerance to dilution than the hydrocarbon fuels tested. Also, variations in Gasoline blend have little effect on any of the combustion parameters measured.

A fuel fractionating system is designed and commissioned to separate standard gasoline fuel into two components by evaporation. The system is installed on a Ricardo E6 single cylinder research engine for testing purposes. Laboratory tests are carried out to determine the Research Octane Number (RON) and Motoring Octane Number (MON) of both fuel fractions. Further tests are carried out to characterize Spark-Ignition (SI) and Controlled Auto-Ignition (CAI) combustion under borderline knock conditions, and these are related to results from some primary reference fuels. SI results indicate that an increase in compression ratio of up to 1.0 may be achieved, along with better charge ignitability if this system is used with a stratified charge combustion regime. CAI results show that the two fuels exhibit similar knock-resistances over a range of operating conditions.

This paper presents the development of an engine simulation program for SI engines and its application to a two-stage expansion cycle. The two-stage expansion analysis is performed using the engine simulation, where a sudden expansion much faster than the normal expansion takes place during the expansion stroke. The changes in NO emissions and knock tolerance of the resulting new engine cycle are investigated for the same compression ratio. The changes in NO emissions and specific fuel consumption through increasing the compression ratio in order to return to the same amount of work done within the cycle are also studied.

A mathematical model has been developed which describes the evaporation and trajectories of fuel droplets during their flight in the inlet manifold of port-injected gasoline engines. Based on the model, a computer simulation program was developed, and sample results of this program are given in this paper. Extensive results obtained using the simulation program are described in a companion paper. The simulation program can be used as a tool to improve understanding of mixture preparation in port injected engines. Such effects as: engine load and speed, air and fuel temperature, fuel type, fuel injection velocity, injection timing, and spray droplet size can be investigated.

A number of tests were conducted on a 2.5 litre, high-speed, direct-injection diesel engine running at various loads and speeds. The aim of the tests was to gain understanding which would lead to more effective use of exhaust gas recirculation (EGR) for controlling exhaust NOx whilst minimising the penalties of increased smoke emission and fuel consumption. In addition to exhaust emission measurements, in-cylinder sampling of combustion gases was carried out using a fast-acting, snatch-sampling valve. The results showed that the effectiveness of EGR was enhanced considerably by cooling the EGR. In addition to more effective NOx control, this measure also improved volumetric efficiency which assisted in the control of smoke emission and fuel consumption. This second of two papers on the use of EGR in diesel engines deals with the effects of EGR on soot emission and on the engine fuel economy.

This paper is concerned with the performance of the sensors and associated instrumentation used for the standard cetane tests for diesel fuels according to the ASTM D-613 procedure. The two primary sensors are replaced by modern units, and the analogue monitoring system is replaced by a digital one; the changes in the performance of the instrumentation system are then assessed. It is shown that the main source of inaccuracy in the measurement of ignition delay (on which the cetane test is based) is cyclic instability in the start of combustion, and that the current instrumentation and monitoring methods do not cope well with this instability. Although some of the cyclic variation can be ascribed to the instrumentation system, a large part is contributed by variability in the fuel ignition and injection processes. Improvements to the instrumentation and monitoring systems are presented and assessed.

The paper first describes three linked computational models which allow the estimation of: swirl generated during the induction process; the modification of swirl with bowl-in-piston combustion chambers during compression as the piston approaches top dead centre; the interaction of the fuel sprays with swirl including relative crosswind velocities between the air and the fuel sprays and spray impingement velocities. The paper then presents experimental results from a single-cylinder direct injection diesel engine, during which both the fuel spray and swirl parameters were changed systematically. Finally, the predicted spray impingement and crosswind velocities for this engine are correlated with the engine performance obtained experimentally, in particular, with fuel economy and smoke emission.

Comparisons have been made between the ignition delay and combustion performance of sunflower oil and diesel fuel. The experimental results have been obtained in a naturally aspirated direct injection diesel engine, and particular attention has been given to the heat release analysis, ignition delay, combustion noise and lubricant degradation. The anomalous behaviour of sunflower oil is explained by reference to its physical properties and ignition quality, as reported in the literature from bomb tests. It is concluded that the power output and brake efficiency are largely unaffected by the use of the sunflower oil, and that lubricant degradation is not likely to be significant. However, the build up of combustion deposits already widely reported in the literature was observed. Suggestions are made as to how this might be ameliorated through modifications to the injection system.

A Waukesha VR 220 naturally aspirated Diesel Engine has been modified to operate with a high compression ratio fast-burn spark-ignition combustion system. Since the application of greatest interest is for Combined Heat and Power (CHP), the majority of data have been obtained with the engine operating at full throttle and 1500 rpm. The philosophy of the open chamber combustion system design is described, and this includes a discussion on the selection of the compression ratio. Results are presented for the energy balance and the emissions, for a wide range of air fuel ratios. The experiments have been conducted with natural gas and natural gas/carbon dioxide mixtures (to simulate bio-gas). Comparisons are made with the baseline engine performance data, some of which has been published earlier(1)*.