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In the perspective of a reduction of emissions and a rapid decarbonisation, especially for compression ignition engines, hydrogen plays a decisive role. The dual fuel technology is perfectly suited to the use of hydrogen, a fuel characterized by great energy potential. In fact, replacing, at the same energy content, the fossil fuel with a totally carbon free one, a significant reduction of the greenhouse gases, like carbon dioxide and total hydrocarbon, as well as of the particulate matter can be obtained. The dual fuel with indirect injection of gaseous fuel in the intake manifold, involves the problem of hydrogen autoignition. In order to avoid this difficulty, the optimal conditions for the injection of the incoming mixture into the cylinder were experimentally investigated. All combustion processes are carried out on a research engine with optical access. The engine speed has is set at 1500 rpm, while the EGR valve is deactivated.

Water removal from Proton Exchange Membrane (PEM) Fuel Cell (FC) mainly involves two phenomena: some of the emerging droplets will roll on the Gas Diffusion Layer (GDL), others may impact channel walls and start sliding along the airflow direction. This different behaviour is linked to the hydrophobic/hydrophilic nature of the surface the water is moving on. In this paper, the walls of the channel of a FC were characterized by applying optical techniques. The deposition of droplets on the channel wall led to an evaluation of the proper range for Contact Angle Hysteresis (CAH = 55° - 45°), and due to the high wettability of the surface, droplets dimension was defined with a dimensionless parameter B/H. Under high crossflow condition (15 m/s) a sliding behaviour was observed. The channel features determined through image processing were used as boundary conditions for a 2D CFD two phase simulation employing the Volume of Fluid (VOF) model to keep track of the fluids interface.

In this work, a dynamic 0-D electro-thermal model of a lithium-polymer battery for automotive applications is presented. The model predicts the battery temperature during its charging/discharging phases under different environmental and operating conditions, by considering the requested power or current, the coolant flow rate and its temperature as model inputs. The model was first validated with experimental data carried out at the test bench where only the convective heat transfer between the battery and the ambient air was considered. The accuracy of the internal heat generation model was experimentally assessed for different current discharge rates. Then, a liquid cooling system was designed on purpose, assembled, and installed on the battery at the test bench for the improvement of the model predictions in liquid convection conditions.

The growing concern about Greenhouse Gas (GHG) emissions led institutions to further reduce the limits on vehicle-related CO2 emissions. Therefore, car manufacturers are developing vehicles with low environmental impact, like Hybrid-Electric Vehicles (HEVs), which in the series architecture employ an Internal Combustion Engine (ICE) coupled with an electric generator for battery recharging, thus extending the range of a Battery Electric Vehicle (BEV). For this kind of application, small four-stroke Spark Ignition (SI) engines are preferred, as they are a proven and reliable solution to increase the driving range with very low environmental impact. In series hybrid-electric powertrains, the ICE is decoupled from the drive wheels, then it can operate in a steady-state high-efficiency working point, regardless of the power required by the mission profile. The benefits of lean combustion can be exploited to increase efficiency and reduce CO2 and NOx emissions.

The urban mobility electrification has been proposed as the main solution to the vehicle emission issues in the next years. However, internal combustion engines have still great potential to decarbonize the transport sector through the use of low/zero-carbon fuels. Alcohols such us methanol, have long been considered attractive alternative fuels for spark ignition engines. They have properties similar to those of gasoline, are easy to transport and store. Recently, great attention has been devoted to gaseous fuels that can be used in existing engine after minor modification allowing to drastically reduce the pollutant emissions. In this regard, this study tries to provide an overview on the use of alternative fuels, both liquid and gaseous in spark ignition engines, highlighting the benefits as well as the criticalities. The investigation was carried out on a small displacement spark ignition engine capable to operate both in port fuel and direct injection mode.

In order to reduce fuel consumption and polluting emissions from engines, alternative fuels such as hydrogen could play an important role towards carbon neutrality. Moreover, dual-fuel (DF) technology has the potential to offer significant improvements in carbon dioxide emissions for transportation and energy sectors. The dual fuel concept (natural gas/diesel or hydrogen/diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

Hybrid electric vehicles are a suitable solution for the transition from fossil fuels-based transportation to electric mobility. They have the benefits of zero-emissions operation when only the electric engine is used preventing the typical range anxiety of full-electric vehicles. Also, they can have a low battery pack capacity and weight thanks to the continuous recharge from the internal combustion engine that becomes the only responsible for exhaust emissions. A practical solution to limit the combustion engine emissions is represented by the range extender configuration, where the engine works at a fixed operating point with the highest efficiency serving uniquely as a battery charger. In the face of the current world situation and future changes, research for alternative energy sources is crucial. Hydrogen can be used as an alternative fuel for common internal combustion engines; moreover, it has the great advantage of high efficiency (about 44%).

Direct injection spark ignition engines represent an effective technology to achieve the goal of carbon dioxide emission reduction. Further reduction of the carbon footprint can be achieved by using carbon-neutral fuels. Oxygenated alcohols are well consolidated fuels for spark ignition engines providing also the advantages of knock resistance and low soot tendency production. Methanol and ethanol are possible candidates as alternative fuels to gasoline due to their similar properties. In this study a blend at 25 % v/v of ethanol in gasoline (E25) and a blend with 80% gasoline, 5 % v/v ethanol and 15% v/v of methanol (GEM) were tested. These blends were considered since E25 is already available at fuel pump in some countries. The GEM blend, instead, could represent a valid alternative in the next future. Experiments were carried out on a high performance, turbocharged 1.8 L direct injection spark ignition engine over the Worldwide Harmonized Light Vehicles Test Cycle.

The application of an alternative fuel such as hydrogen to internal combustion engines is proving to be an effective and flexible solution for reducing fuel consumption and polluting emissions from engines. An easy to use and immediate application solution is the dual fuel (DF) technology. It has the potential to offer significant improvements in carbon dioxide emissions from light compression ignition engines. The dual fuel concept (natural gas / diesel or hydrogen / diesel) represents a possible solution to reduce emissions from diesel engines by using low-carbon or carbon-free gaseous fuels as an alternative fuel. Moreover, DF combustion is a possible retrofit solution to current diesel engines by installing a PFI injector in the intake manifold while diesel is injected directly into the cylinder to ignite the premixed mixture. In the present study, dual fuel operation has been investigated in a single cylinder research engine.

Nowadays, the stricter regulations in terms of emissions have limited the use of diesel engines on urban roads. On the contrary, for marine and off-road applications the diesel engine still represents the most feasible solution for work production. In the last decades, dual fuel operation with methane supply has been widely investigated. Starting from previous studies on a research engine, where diesel-methane dual fuel combustion has been deepened both experimentally and numerically with the aid of a CFD code, the authors implemented and tested a kinetic mechanism. It is obtained from the combination of the well-established GRIMECH 3.0 and a detailed scheme for a diesel surrogate oxidation. Moreover, the Autoignition-Induced Flame Propagation model, included in the ANSYS Forte® software, is applied because it can be considered the most appropriate model to describe dual fuel combustion.

The battery efficiency is strongly affected by the operating temperature, granting the best performance in a limited range. Great attention is given to the design and the testing of materials for the battery heat dissipation. In the present study, the thermal behavior of a Li-polymer cell, which is part of a battery pack for electric vehicles, is investigated. The cell is provided with different coatings of carbon, graphene, and silicone, used in turn, to dissipate the heat generated during the operation in natural convection. The coating is placed only on one side of the battery while the other one is inspected via thermal imaging. Optical diagnostics in the infrared band are used to evaluate the bi-dimensional distribution of the battery surface temperature and the effect of the coatings. Different operating conditions are tested by varying the current demand.

In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

Methane supply in diesel engines operating in dual fuel mode has demonstrated to be effective for the reduction of particulate matter and nitric oxides emissions from this type of engine. In particular, methane is injected into the intake manifold to form a premixed charge with air, while a reduced amount of diesel oil is still directly injected to ignite the mixture inside the cylinder. As a matter of fact, the liquid fuel burns following the usual diffusive combustion, so activating the gaseous fuel oxidation in a premixed flame. Clearly, the whole combustion process appears to be more complex to be described in a CFD simulation, mainly because it is not always possible to select in the 3-dimensional codes a different combustion model for each fuel and, also, because other issues arise from the interaction of the two fuels.

A growing number of electric vehicles (EV) and hybrid electric vehicles (HEV) in the present market depicts the rapid growing demand for energy storage systems. The battery’s main peculiarities must be the power density and reliability over time. The temperature strongly affects battery performance for low and high intensity. In particular, the management of the heat generated by the battery itself is one of the main aspects to handle to preserve the performance over time. The objective of this paper is to compare the surface temperature of the lithium-ion polymer battery at different discharging rates by infrared thermography. Thermal imaging is performed to detect the battery surface temperature distribution, focusing on its variation over time and the local inhomogeneity. Temperature measurements are then used to estimate the contributions of the different heat transfer mechanisms for the dissipation of the heat generated by the battery.

Growing concerns about the emissions of internal combustion engines have forced the adoption of aftertreatment devices to reduce the adverse impact of diesel engines on health and environment. Diesel particulate filters are considered as an effective means to reduce the particle emissions and comply with the regulations. Research activity in this field focuses on filter configuration, materials and aging, on understanding the variation of soot layer properties during time, on defining of the optimal strategy of DPF management for on-board control applications. A model was implemented in order to simulate the filtration and regeneration processes of a wall-flow particulate filter, taking into account the emission characteristic of the engine, whose architecture and operating conditions deeply affect the size distribution of soot particles.

Nowadays, the regulation regards only the particles larger than 23 nm. The attention is shifting towards the sub-23 nm particles because of their large presence at the exhaust of the modern engines and their negative impact on human health. The main challenge of the regulation of these particles is the definition of a proper procedure for their measure. The nature of the sub-23 nm particles is not well understood, and their measure is strongly affected by the sampling conditions leading to not reliable measure. The aim of this paper is to provide information on the emissions of sub-23 nm particles from GDI vehicles/engines. At the same time, the presence of volatiles, which mainly contribute to the formation of sub-23 nm particles, was evaluated and the effect of sampling conditions was investigated. The analysis was performed on a 1.8L GDI powered vehicle, widely used both in North America and Europe, and a 4-cylinder GDI engine, whose features are similar to those of the vehicle.

Improvement of performance and emission of future internal combustion engine for passenger cars is mandatory during the transition period toward their substitution with electric propulsion systems. In middle time, direct injection spark ignition (DISI) engines could offer a good compromise between fuel economy and exhaust emissions. However, abnormal combustion and particularly knock and super-knock are some of the most important obstacles to the improvement of SI engines efficiency. Although knock has been studied for many years and its basic characteristics are clear, phenomena involved in its occurrence are very complex and are still worth of investigation. In particular, the definition of an absolute knock intensity and the precise determination of the knock onset are arduous and many indexes and methodologies has been proposed. In this work, most used methods for knock onset detection from in- cylinder pressure signal have been considered.

The permanent aim of the automotive industry is the further improvement of the engine efficiency and the simultaneous pollutant emissions reduction. The aim of the study was the optimization of the gasoline combustion by means of a passive prechamber. This analysis allowed the improvement of the engine efficiency in lean-burn operation condition too. The investigation was carried out in a commercial small Spark Ignition (SI) engine fueled with gasoline and equipped with a proper designed passive prechamber. It was analyzed the effects of the prechamber on engine performance, Indicated Mean Effective Pressure, Heat Release Rate and Fuel Consumption were used. Gaseous emissions were measured as well. Particulate Mass, Number and Size Distributions were analyzed. Emissions samples were taken from the exhaust flow, just downstream of the valves. Four different engine speeds were investigated, namely 2000, 3000, 4000 and 5000 rpm.

The current legislation does not take into account the limitation of sub 23 nm particles from engine. Nevertheless, the Common Rail Diesel engine emits a large number of nanoparticle, solid and volatiles, that are very dangerous for human health. In this contest, the challenge of the “dieper EU project” is to apply advanced technologies for exhaust after-treatment to existing diesel engines and to optimize the characteristics of a new generation of engines with regards to emissions, fuel consumption and drivability. Aim of the present paper is to provide useful information for the development of the after-treatment system that will have to fulfill Euro6 further steps. In order to characterize the chemical and physical nature of Particulate Matter emitted from Euro 6b Medium Duty diesel engine, the pollutants were collected and analyzed: from engine-out, downstream of the particulate filter (DPF), and at the exit of a selective catalytic reactor (SCR).

The growing concerns on the emission of particles smaller than 23 nm, which are harmful to human health, lead to the necessity of introducing a regulation for these particles not yet included in the current emission standards. Considering that measurements of concentration of sub-23 nm particles are particularly sensitive to the sampling conditions, it is important to identify an effective assessment procedure. Aim of this paper is the characterization of the effect of the sampling conditions on sub-23 nm particles, emitted by PFI (port fuel injection) and DI (direct injection) spark ignition engines fueled with gasoline, ethanol and a mixture of ethanol and gasoline (E30). The experimental activity was carried out on a 250 cm3 displacement four stroke GDI and PFI single cylinder engines. The tests were conducted at 2000 rpm and 4000 rpm full load, representative of the homologation urban driving cycle.