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Selective Catalytic Reduction (SCR) catalysts used in Lean NOx Trap (LNT) - SCR exhaust aftertreatment systems typically encounter alternating oxidizing and reducing environments. Reducing conditions occur when diesel fuel is injected upstream of a reformer catalyst, generating high concentrations of hydrogen (H₂), carbon monoxide (CO), and hydrocarbons to deNOx the LNT. In this study, the functionality of an iron (Fe) zeolite SCR catalyst is explored with a bench top reactor during steady-state and cyclic transient SCR operation. Experiments to characterize the effect of an LNT deNOx event on SCR operation show that adding H₂ or CO only slightly changes SCR behavior with the primary contribution being an enhancement of nitrogen dioxide (NO₂) decomposition into nitric oxide (NO). Exposure of the catalyst to C₃H₆ (a surrogate for an actual exhaust HC mixture) leads to a significant decrease in NOx reduction capabilities of the catalyst.

Premixed low temperature combustion (LTC) in diesel engines simultaneously reduces soot and NOx at the expense of increased hydrocarbon (HC) and CO emissions. The use of biodiesel in the LTC regime has been shown to produce lower HC emissions than petroleum diesel; however, unburned methyl esters from biodiesel are more susceptible to particulate matter (PM) formation following atmospheric dilution due to their low volatility. In this study, the efficacy of a production-type diesel oxidation catalyst (DOC) for the conversion of light hydrocarbons species and heavier, semi-volatile species like those in unburned fuel is examined. Experimental data were taken from a high speed direct-injection diesel engine operating in a mid-load, late injection partially premixed LTC mode on ultra-low sulfur diesel (ULSD) and neat soy-based biodiesel (B100). Gaseous emissions were recorded using a conventional suite of analyzers and individual light HCs were measured using an FT-IR analyzer.

Homogeneous charge compression ignition (HCCI) has received much attention in recent years due to its ability to reduce both fuel consumption and NO emissions compared to normal spark-ignited (SI) combustion. However, due to the limited operating range of HCCI, production feasible engines will need to employ a combination of combustion strategies, such as stoichiometric SI combustion at high loads and leaner burn spark-assisted compression ignition (SACI) and HCCI at intermediate and low loads. The goal of this study was to extend the high load limit of HCCI into the SACI region while maintaining a stoichiometric equivalence ratio. Experiments were conducted on a single-cylinder research engine with fully flexible valve actuation. In-cylinder pressure rise rates and combustion stability were controlled using cooled external EGR, spark assist, and negative valve overlap. Several engine loads within the SACI regime were investigated.

Naturally aspirated HCCI operation is typically limited to medium load operation (∼ 5 bar net IMEP) by excessive pressure rise rate. Boosting can provide the means to extend the HCCI range to higher loads. Recently, it has been shown that HCCI can achieve loads of up to 16.3 bar of gross IMEP by boosting the intake pressure to more than 3 bar, using externally driven compressors. However, investigating HCCI performance over the entire speed-load range with real turbocharger systems still remains an open topic for research. A 1 - D simulation of a 4 - cylinder 2.0 liter engine model operated in HCCI mode was used to match it with off-the-shelf turbocharger systems. The engine and turbocharger system was simulated to identify maximum load limits over a range of engine speeds. Low exhaust enthalpy due to the low temperatures that are characteristic of HCCI combustion caused increased back-pressure and high pumping losses and demanded the use of a small and more efficient turbocharger.

The number of control actuators available on spark-ignition engines is rapidly increasing to meet demand for improved fuel economy and reduced exhaust emissions. The added complexity greatly complicates control strategy development because there can be a wide range of potential actuator settings at each engine operating condition, and map-based actuator calibration becomes challenging as the number of control degrees of freedom expand significantly. Many engine actuators, such as variable valve actuation and flow control valves, directly influence in-cylinder combustion through changes in gas exchange, mixture preparation, and charge motion. The addition of these types of actuators makes it difficult to predict the influences of individual actuator positioning on in-cylinder combustion without substantial experimental complexity.

Premixed diesel combustion is intended to supplant conventional combustion in the light to mid load range. This paper demonstrates the operating load limits, limiting criteria, and load-based emissions behavior of a direct-injection, diesel-fueled, premixed combustion mode across a range of test fuels. Testing was conducted on a modern single-cylinder engine fueled with a range of ultra-low sulfur fuels with cetane number ranging from 42 to 53. Operating limits were defined on the basis of emissions, noise, and combustion stability. The emissions behavior and operating limits of the tested premixed combustion mode are independent of fuel cetane number. Combustion stability, along with CO and HC emissions levels, dictate the light load limit. The high load limit is solely dictated by equivalence ratio: high PM, CO, and HC emissions result as overall equivalence ratio approaches stoichiometric.

Diesel engines have been used in large vehicles, locomotives and ships as more efficient alternatives to the gasoline engines. They have also been used in small passenger vehicle applications, but have not been as popular as in other applications until recently. The two main factors that kept them from becoming the major contender in the small passenger vehicle applications were the low power outputs and the noise levels. A combination of improved mechanical technologies such as multiple injection, higher injection pressure, and advanced electronic control has mostly mitigated the problems associated with the noise level and changed the public notion of the Diesel engine technology in the latest generation of common-rail designs. The power output of the Diesel engines has also been improved substantially through the use of variable geometry turbines combined with the advanced fuel injection technology.

The effects of combining premixed, low temperature combustion (LTC) with biodiesel are relatively unknown to this point. This mode allows simultaneously low soot and NOx emissions by using high rates of EGR and increasing ignition delay. This paper compares engine performance and emissions of neat, soy-based methyl ester biodiesel (B100), B20, B50, pure ultra low sulfur diesel (ULSD) and a Swedish, low aromatic diesel in a multi-cylinder diesel engine operating in a late-injection premixed LTC mode. Using heat release analysis, the progression of LTC combustion was explored by comparing fuel mass fraction burned. B100 had a comparatively long ignition delay compared with Swedish diesel when measured by start of ignition (SOI) to 10% fuel mass fraction burned (CA10). Differences were not as apparent when measured by SOI to start of combustion (SOC) even though their cetane numbers are comparable.

Extending the operating range of the gasoline HCCI engine is essential for achieving desired fuel economy improvements at the vehicle level, and it requires deep understanding of the thermal conditions in the cylinder. Combustion chamber deposits (CCD) have been previously shown to have direct impact on near-wall phenomena and burn rates in the HCCI engine. Hence, the objectives of this work are to characterize thermal properties of deposits in a gasoline HCCI engine and provide foundation for understanding the nature of their impact on autoignition and combustion. The investigation was performed using a single-cylinder engine with re-induction of exhaust instrumented with fast-response thermocouples on the piston top and the cylinder head surface. The measured instantaneous temperature profiles changed as the deposits grew on top of the hot-junctions.

Stringent fuel economy and emissions regulations have driven development of new mixture preparation technologies and increased spark-ignition engine complexity. Additional degrees of freedom, brought about by devices such as cam phasers and charge motion control valves, enable greater range and flexibility in engine control. This permits significant gains in fuel efficiency and emission control, but creates challenges related to proper engine control and calibration techniques. Accurate experimental characterization of high degree of freedom engines is essential for addressing the controls challenge. In particular, this paper focuses on the evaluation of three experimental residual gas fraction measurement techniques for use in a spark ignition engine equipped with dual-independent variable camshaft phasing (VVT).

Low-sulfur “clean” diesel fuel has been mandated in the US and Europe. However, quality of diesel fuel, particularly the sulfur content, varies significantly in other parts of the world. Due to logistical issues in various theaters of operation, the Army is often forced to rely on local fuel supplies, which exposes vehicles to diesel fuel or jet fuel (JP-8) with elevated levels of sulfur. Modern engines typically use cooled Exhaust Gas Recirculation (EGR) to meet emissions regulations. Using high-sulfur fuels and cooled EGR elevates problems associated with cooler fouling and corrosion of engine components. Hence, an experimental study has been carried out in a heavy-duty diesel engine running on standard JP-8 fuel and fuel doped with 2870 ppm of sulfur. Gas was sampled from the EGR cooler and analyzed using a condensate collection device developed according to a modified ASTM 3226-73T standard. Engine-out emissions were analyzed in parallel.

Increasing functionality of electronic control units has enhanced our ability to control engine operation utilizing calibration static maps that provide the values of several controllable variables. State-of-the-art simulation-based calibration methods permit the development of these maps with respect to extensive steady-state and limited transient operation of particular driving cycles. However, each individual driving style is different and rarely meets those test conditions. An alternative approach was recently implemented that considers the derivation of these maps while the engine is running the vehicle. In this approach, a self-learning controller selects in real time the optimum values of the controllable variables for the sequences of engine operating point transitions, corresponding to the driver's driving style.

Meeting diesel engine emission standards for heavy-duty vehicles can be achieved by simultaneous injection of fuel and water. An injection system for instantaneous mixing of fuel and water in the combustion chamber has been developed by injecting water in a mixing passage located in the periphery of the fuel spray. The fuel spray is then entrained by water and hot air before it burns. The experimental work was carried out on a Rapid Compression Machine and on a Komatsu direct-injection heavy-duty diesel engine with a high pressure common rail fuel injection system. It was also supported by Computational Fluid Dynamics simulations of the injection and combustion processes in order to evaluate the effect of water vapor distribution on cylinder temperature and NOX formation. It has been concluded that when the water injection is appropriately timed, the combustion speed is slower and the cylinder temperature lower than in conventional diesel combustion.

The thermal conditions of an engine structure, in particular the wall temperatures, have been shown to have a great effect on the HCCI engine combustion timing and burn rates through wall heat transfer, especially during transient operations. This study addresses the effects of thermal inertia on combustion in an HCCI engine. In this study, the control of combustion timing in an HCCI engine is achieved by modulating the residual gas fraction (RGF) while considering the wall temperatures. A multi-cylinder engine simulation with detailed geometry is carried out using a 1-D system model (GT-Power®) that is linked with Simulink®. The model includes a finite element wall temperature solver and is enhanced with original HCCI combustion and heat transfer models. Initially, the required residual gas fraction for optimal BSFC is determined for steady-state operation. The model is then used to derive a map of the sensitivity of optimal residual gas fraction to wall temperature excursions.

This paper analyzes and compares reactor and engine behavior of a diesel oxidation catalyst (DOC) in the presence of conventional diesel exhaust and low temperature premixed compression ignition (PCI) diesel exhaust. Surrogate exhaust mixtures of n-undecane (C11H24), ethene (C2H4), CO, O2, H2O, NO and N2 are defined for conventional and PCI combustion and used in the gas flow reactor tests. Both engine and reactor tests use a DOC containing platinum, palladium and a hydrocarbon storage component (zeolite). On both the engine and reactor, the composition of PCI exhaust increases light-off temperature relative to conventional combustion. However, while nominal conditions are similar, the catalyst behaves differently on the two experimental setups. The engine DOC shows higher initial apparent HC conversion efficiencies because the engine exhaust contains a higher fraction of trappable (i.e., high boiling point) HC.

Homogenous Charge Compression Ignition (HCCI) engines offer a good potential for achieving high fuel efficiency while virtually eliminating NOx and soot emissions from the exhaust. However, realizing the full fuel economy potential at the vehicle level depends on the size of the HCCI operating range. The usable HCCI range is determined by the knock limit on the upper end and the misfire limit at the lower end. Previously proven high sensitivity of the HCCI process to thermal conditions leads to a hypothesis that combustion chamber deposits (CCD) could directly affect HCCI combustion, and that insight about this effect can be helpful in expanding the low-load limit. A combustion chamber conditioning process was carried out in a single-cylinder gasoline-fueled engine with exhaust re-breathing to study CCD formation rates and their effect on combustion. Burn rates accelerated significantly over the forty hours of running under typical HCCI operating conditions.

Degreening is crucial in obtaining a stable catalyst prior to assessing its performance characteristics. This paper characterizes the light-off behavior and conversion efficiency of a Diesel Oxidation Catalyst (DOC) during the degreening process. A platinum DOC is degreened for 16 hours in the presence of actual diesel engine exhaust at 650°C and 10% water (H2O) concentration. The DOC's activity for carbon monoxide (CO) and for total hydrocarbons (THC) conversion is checked at 0, 1, 2, 3, 4, 6, 8, 10, 12, and 16 hours of degreening. Pre-and post-catalyst hydrocarbon species are analyzed via gas chromatography at 0, 4, 8, and 16 hours of degreening. It is found that both light-off temperature and species-resolved conversion efficiencies change rapidly during the first 8 hours of degreening and then stabilize to a large degree. T50, the temperature where the catalyst is 50% active towards a particular species, increases by 14°C for CO and by 11°C for THC through the degreening process.

Premixed compression ignition low-temperature diesel combustion (PCI) can simultaneously reduce particulate matter (PM) and oxides of nitrogen (NOx). Carbon monoxide (CO) and total hydrocarbon (THC) emissions increase relative to conventional diesel combustion, however, which may necessitate the use of a diesel oxidation catalyst (DOC). For a better understanding of conventional and PCI combustion, and the operation of a platinum-based production DOC, engine-out and DOC-out exhaust hydrocarbons are speciated using gas chromatography. As combustion mode is changed from lean conventional to lean PCI to rich PCI, engine-out CO and THC emissions increase significantly. The relative contributions of individual species also change; increasing methane/THC, acetylene/THC and CO/THC ratios indicate a richer combustion zone and a reduction in engine-out hydrocarbon incremental reactivity.

Modern diesel engines operate under injection pressures varying from 30 to 200 MPa and employ combinations of very early and conventional injection timings to achieve partially homogeneous mixtures. The variety of injection and cylinder pressures results in droplet atomization under a wide range of Weber numbers. The high injection velocities lead to fast jet disintegration and secondary droplet atomization under shear and catastrophic breakup mechanisms. The primary atomization of the liquid jet is modeled considering the effects of both infinitesimal wave growth on the jet surface and jet turbulence. Modeling of the secondary atomization is based on a combination of a drop fragmentation analysis and a boundary layer stripping mechanism of the resulting fragments for high Weber numbers. The drop fragmentation process is predicted from instability considerations on the surface of the liquid drop.

This study investigates the impact of transient engine operation on the emissions formed during a tip-in procedure. A medium-duty production V-8 diesel engine is used to conduct experiments in which the rate of pedal position change is varied. Highly-dynamic emissions instrumentation is implemented to provide real-time measurement of NOx and particulate. Engine subsystems are analyzed to understand their role in emissions formation. As the rate of pedal position change increases, the emissions of NOx and particulates are affected dramatically. An instantaneous load increase was found to produce peak NOx values 1.8 times higher and peak particulate concentrations an order of magnitude above levels corresponding to a five-second ramp-up. The results provide insight into relationship between driver aggressiveness and diesel emissions applicable to development of drive-by-wire systems. In addition, they provide direct guidance for devising low-emission strategies for hybrid vehicles.