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The TIMES system was evaluated to determine its ability to process reverse osmosis (RO) brine as one of the Advanced Water Processor steps. Since preliminary testing performed in 1998 showed that the membrane typically used in the process (Nafion 117) offered a very poor ammonia rejection, a search for an alternate membrane exhibiting high ammonia rejection capability was initiated under NASA-JSC funding. This investigation has resulted in the selection of a PolyVinylAlcohol (PVA) composite membrane as a replacement. When processing RO brine and untreated human urine as feeds, the Pervap 2201 membrane showed a 96% ammonia rejection over a large range of ammonia concentration. The water permeation rates in both laboratory-scale and pilot scale testings were also similar to the Nafion. The water permeance of the Pervap 2201 was approximately 7.5 kg/h/m2/atm (1.1 lb/h/m2/psi).

The Thermoelectric Integrated Membrane Evaporative Subsystem (TIMES) was evaluated to determine its ability to process reverse osmosis brine as one of the Advanced Water Processor steps. As the baselined membrane (Nafion 117) was unable to retain ammonia, a NASA-sponsored project was conducted to find an alternate membrane capable of retaining ammonia while maintaining reasonable water production rates. A long term test was performed with up to 90% water recovery using a hydrophilic membrane and a hydrophobic membrane. The ammonia rejection for the hydrophilic membrane was 80%. The average water production rates for both membranes were greater than for the pretreated baselined Nafion membrane.

The Lunar Mars Life Support Test Project (LMLSTP) Phase III test was the final test in a series of tests conducted to evaluate regenerative life support systems performance over increasingly longer durations. The Phase III test broke new ground for the U.S. Space Program by being the first test to look at integration of biological and physical-chemical systems for air, water and solid waste recovery for a crew of four for 91 days. Microbial bioreactors were used as the first step in the water recovery system (WRS). This biologically based WRS continuously recovered 100% of the water used by the crew consistent with NASA's strict potable standards. The air revitalization system was a combination of physical-chemical hardware and wheat plants which worked together to remove and reduce the crew's metabolically produced carbon dioxide and provide oxygen.

An integrated water recovery system was operated for 91 days in support of the Lunar Mars Life Support Test Project (LMLSTP) Phase III test. The system combined both biological and physical-chemical processes to treat a combined wastewater stream consisting of waste hygiene water, urine, and humidity condensate. Biological processes were used for primary degradation of organic material as well as for nitrification of ammonium in the wastewater. Physical-chemical systems removed inorganic salts from the water and provided post-treatment. The integrated system provided potable water to the crew throughout the test. This paper describes the water recovery system and reviews the performance of the system during the test.

A Human Metabolic Simulator (HMS) was developed for use in testing life support air revitalization systems. The developed equipment simulates atmospheric effects of human respiration, perspiration, and metabolism, including consumption of oxygen and production of carbon dioxide, water vapor, and sensible heat. By analogy with human metabolism, oxygen is converted into carbon dioxide and water vapor through catalytic oxidation (combustion) of an organic fuel. Virtually complete combustion of methyl acetate and ethanol fuels was demonstrated using a monolithic precious-metal catalyst at reaction temperatures above 275°C. The HMS has been used successfully in support of NASA's Early Human Testing (EHT) program.

Computer models are currently being developed by NASA and major aerospace companies to characterize regenerative life support waste water reclamation bioreactors. Detailed models increase understanding of complex processes within the bioreactors and predict performance capabilities over a wide range of operating parameters. Bench-top scale bioreactors are contributing to the development and validation of these models. The purpose of the detailed bioreactor model is to simulate the complex water purification processes as accurately as possible by minimizing the use of simplifying assumptions and empirical relationships. Fundamental equations of mass transport and microbial kinetics were implemented in a finite-difference model structure to maximize accuracy and adaptability to various bioreactor configurations. The model development is based upon concepts and data from the available literature and data from the bench top bioreactor investigations.

The NASA Johnson Space Center has plans to integrate a Solid Amine Water Desorbed (SAWD II) carbon dioxide removal subsystem into the Variable Pressure Growth Chamber (VPGC). The SAWD II subsystem will be used to remove any excess carbon dioxide (CO2) input into the VPGC which is not assimilated by the plants growing in the chamber. An analysis of the integrated VPGC-SAWD II system was performed using a mathematical model of the system implemented in the Computer-Aided System Engineering and Analysis (CASE/A) package. The analysis consisted of an evaluation of the SAWD II subsystem configuration within the VPGC, the planned operations for the subsystem, and the overall performance of the subsystem and other VPGC subsystems. Based on the model runs, recommendations were made concerning the SAWD II subsystem configuration and operations, and the chambers' automatic CO2 injection control subsystem.

Reclamation of purified water from waste water will be a necessity for self-sufficiency on Lunar and Martian outposts. Biological waste water treatment is advantageous because it has low temperature, low pressure, and low power requirements. Four different media were tested for use as biological growth substrates in bench-top aerobic trickling filter bioreactors in the Hybrid Regenerative Water Recovery Lab at Johnson Space Center. The four media tested included a mixture of open skeleton polypropylene spheres and cylinders, ceramic berl saddles, solid glass beads, and small rocks. The media were tested to characterize the organism inoculation rate; the steady state performance; the response to system upsets; and the column characteristics like flooding and channeling. Results indicate that the ceramic berl saddles performed best with respect to inoculation rate, steady state performance, and response to system upsets.

An 84 day wheat crop was grown in the Variable Pressure Growth Chamber (VPGC) at Johnson Space Center (JSC). The VPGC is an atmospherically closed, controlled environment facility used to evaluate the use of higher plants as part of a regenerative life support system. The chamber has 10.6 m2 of growing area consisting of 480 pots of calcined clay support media. The chamber is lit by very high output, cool white fluorescent bulbs. Five wheat seeds were planted per pot giving a seeding density of 227 seeds·m-2. Pots were irrigated with a modified half strength Hoagland's nutrient solution three or six times per day depending on the crop age. At the plant canopy, the average temperature during the test was 22 ° C, relative humidity was maintained at 69%, CO2 concentration was 1000 ppm, photoperiod was continuous light, and the light intensity averaged 350 μmol·m-2·s-1.

Long duration manned space missions will require integrated biological and physicochemical processes for recovery of resources from wastes. This paper discusses a hybrid regenerative biological and physicochemical water recovery system designed and built at NASA's Crew and Thermal Systems Division (CTSD) at Johnson Space Center (JSC). The system is sized for a four-person crew and consists of a two-stage, aerobic, trickling filter bioreactor; a reverse osmosis system; and a photocatalytic oxidation system. The system was designed to accommodate high organic and inorganic loadings and a low hydraulic loading. The bioreactor was designed to oxidize organics to carbon dioxide and water; the reverse osmosis system reduces inorganic content to potable quality; and the photocatalytic oxidation unit removes residual organic impurities (part per million range) and provides in-situ disinfection. The design and performance of the hybrid system for producing potable/hygiene water is described.