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Fuel film deposits on combustion chamber walls are understood to be the main source of particle emissions in GDI engines under homogenous charge operation. More precisely, the liquid film that remains on the injector tip after the end of injection is a fuel rich zone that undergoes pyrolysis reactions leading to the formation of poly-aromatic hydrocarbons (PAH) known to be the precursors of soot. The physical phenomena accompanying the fuel film deposit, evaporation, and the chemical reactions associated to the injector film are not yet fully understood and require high fidelity CFD simulations and controlled experimental campaigns in optically accessible engines. To this end, a simplified model based on physical principles is developed in this work, which couples an analytical model for liquid film formation and evaporation on the injector tip with a stochastic particle dynamics model for particle formation.

During the past decades, the Nitrogen Oxides (NOx) emission limitations have become stricter, promoting the development of after-treatment systems like Selective Catalytic Reduction (SCR) for emission reduction purposes. The Urea-Water Solution (UWS) spray characteristics can directly have an effect on the SCR efficiency. To understand the droplet breakup and mixing of the UWS with the surrounding air under different operating conditions, a computational campaign has been set up. The main objective of the present study is to recreate the spray injection process, as well as the chemical processes that the UWS spray undergoes, and to analyze the optimal injection angle to maximize the amount of ammonia generated during the injection process by means of Computational Fluid Dynamics (CFD). A Eulerian-Lagrangian framework has been employed to track the evolution of the injected droplets within a Reynolds-Averaged Navier-Stokes (RANS) turbulence formulation.

Selective Catalytic Reduction stands for an effective methodology for the reduction of NOx emissions from Diesel engines and meeting current and future EURO standards. For it, the injection of Urea Water Solution (UWS) plays a major role in the process of reducing the NOx emissions. A LES approach for turbulence modelling allows to have a description of the physics which is a very useful tool in situations where experiments cannot be performed. The main objective of this study is to predict characteristics of the flow of interest inside the injector as well as spray morphology in the near field of the spray. For it, the nozzle geometry has been reconstructed from X-Ray tomography data, and an Eulerian-Eulerian approach commonly known as Mixture Model has been applied to study the liquid phase of the UWS with a LES approach for turbulence modeling. The injector unit is subjected to typical low-pressure working conditions.

The Selective Catalytic Reduction (SCR) system has great potential in reducing NOx emissions. The urea-water solution (UWS) is the preferred method on vehicles for obtaining the ammonia, the required reductant for SCR. The UWS spray is necessary to transform exhaust gas into nitrogen and water and plays an important role in the performance of this system. The UWS needs to be properly mixed with the exhaust gas coming from the engine before entering the SCR, therefore the solution must be injected in the exhaust pipe in a way that it completely vaporizes in order to reduce deposit formation and guaranteeing a proper functioning and durability of the NOx reduction system. Achieving complete vaporization of the UWS spray is not an easy task, mainly due to reduced package space. Another challenge for converting UWS to ammonia is the latent energy in the exhaust.

A prototype multi-hole diesel injector operating with n-heptane fuel from a high-pressure common rail system is used in a high-pressure and high-temperature test rig capable of reaching 1100 Kelvin and 150 bar under different oxygen concentrations. A novel optical set-up capable of visualizing the soot cloud evolution in the fuel jet from 30 to 85 millimeters from the nozzle exit with the high-speed color diffused back illumination technique is used as a result of the insertion of a high-pressure window in the injector holder opposite to the frontal window of the vessel. The experiments performed in this work used one wavelength provide information about physical of the soot properties, experimental results variating the operational conditions show the reduction of soot formation with an increase in injection pressure, a reduction in ambient temperature, a reduction in oxygen concentration or a reduction in ambient density.

Regulations on emissions from diesel engines are becoming more stringent worldwide. Hence there is a great deal of interest in developing engine combustion systems that offer the fuel efficiency of a diesel engine, but with low smoke and NOx emissions. Thus, premixed compression ignition combustion is an interesting way to achieve a clean and efficient engine. However, using a high reactivity fuel such as diesel fuel leads to a complex and expensive engine design. A proven way to overcome this drawback is to actively control the reactivity of the fuel using low cetane fuels such as gasoline. This strategy has been explored with single and multiple cylinder engines. However no detailed and well conducted studies of the injection process were found related to the effects of gasoline use in a standard commercial compression ignition diesel engine injection system.