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For internal combustion engines and industrial machinery, it is well recognized that the most cost-effective way of reducing energy consumption and extending service life is through lubricant development. This presentation summarizes our recent R&D achievements on developing a new class of candidate lubricants or oil additives ionic liquids (ILs). Features of ILs making them attractive for lubrication include high thermal stability, low vapor pressure, non-flammability, and intrinsic high polarity. When used as neat lubricants, selected ILs demonstrated lower friction under elastohydrodynamic lubrication and less wear at boundary lubrication benchmarked against fully-formulated engine oils in our bench tests. More encouragingly, a group of non-corrosive, oil-miscible ILs has recently been developed and demonstrated multiple additive functionalities including anti-wear and friction modifier when blended into hydrocarbon base oils.

A computational study using multi-dimensional CFD modeling was performed to investigate the effects of physical properties on diesel engine combustion characteristics with bio-diesel fuels. Properties of typical bio-diesel fuels that were either calculated or measured are used in the study and the simulation results are compared with those of conventional diesel fuels. The sensitivity of the computational results to individual physical properties is also investigated, and the results provide information about the desirable characteristics of the blended fuels. The properties considered in the study include liquid density, vapor pressure, surface tension, liquid viscosity, liquid thermal conductivity, liquid specific heat, latent heat, vapor specific heat, vapor diffusion coefficient, vapor viscosity and vapor thermal conductivity. The results show significant effects of the fuel physical properties on ignition delay and burning rates at various engine operating conditions.

Fatigue behavior of dissimilar ultrasonic spot welds in lap-shear specimens of magnesium AZ31B-H24 and hot-dipped-galvanized mild steel sheets is investigated based on experimental observations, closed-form stress intensity factor solutions, and a fatigue life estimation model. Fatigue tests were conducted under different load ranges with two load ratios of 0.1 and 0.2. Optical micrographs of the welds after the tests were examined to understand the failure modes of the welds. The micrographs show that the welds mainly fail from kinked fatigue cracks growing through the magnesium sheets. The optical micrographs also indicate that failure mode changes from the partial nugget pullout mode under low-cycle loading conditions to the transverse crack growth mode under high-cycle loading conditions. The closed-form stress intensity factor solutions at the critical locations of the welds are used to explain the locations of fatigue crack initiation and growth.

Failure modes of friction stir spot welds in lap-shear specimens of dissimilar high strength dual phase steel (DP780GA) and hot stamped boron steel (HSBS) sheets are investigated under quasi-static and cyclic loading conditions based on experimental observations. Optical micrographs of dissimilar DP780GA/HSBS friction stir spot welds made by a concave tool before and after failure are examined. The micrographs indicate that the failure modes of the welds under quasi-static and cyclic loading conditions are quite similar. The micrographs show that the DP780GA/HSBS welds mainly fail from cracks growing through the upper DP780GA sheets where the concave tool was plunged into during the welding process. Based on the observed failure modes, a kinked fatigue crack growth model is adopted to estimate fatigue lives.

Failure mode and fatigue behavior of friction stir spot welds made with convex and concave tools in lap-shear specimens of dissimilar high strength dual phase steel (DP780GA) and hot stamped boron steel (HSBS) sheets are investigated based on experiments and a kinked fatigue crack growth model. Lap-shear specimens with the welds were tested under both quasistatic and cyclic loading conditions. Optical micrographs indicate that under both quasi-static and cyclic loading conditions, the welds mainly fail from cracks growing through the upper DP780GA sheets where the tools were plunged in during the welding processes. Based on the observed failure mode, a kinked fatigue crack growth model is adopted to estimate fatigue lives of the welds. In the kinked crack fatigue crack growth model, the stress intensity factor solutions for fatigue life estimations are based on the closed-form solutions for idealized spot welds in lap-shear specimens.

Failure modes and fatigue behaviors of ultrasonic spot welds in lap-shear specimens of magnesium AZ31B-H24 and hot-dipped-galvanized mild steel sheets with and without adhesive are investigated. Ultrasonic spot welded, adhesive-bonded, and weld-bonded lap-shear specimens were made. These lap-shear specimens were tested under quasi-static and cyclic loading conditions. The ultrasonic spot weld appears not to provide extra strength to the weld-bonded lap-shear specimen under quasi-static and cyclic loading conditions. The quasi-static and fatigue strengths of adhesive-bonded and weld-bonded lap-shear specimens appear to be the same. For the ultrasonic spot welded lap-shear specimens, the optical micrographs indicate that failure mode changes from the partial nugget pullout mode under quasi-static and low-cycle loading conditions to the kinked crack growth mode under high-cycle loading conditions.

Metal additive manufacturing has high potential to produce automobile parts, due to its shape flexibility and unique material properties. On the other hand, residual stress which is generated by rapid solidification causes deformation, cracks and failure under building process. To avoid these problems, understanding of internal residual stress distribution is necessary. However, from the view point of measureable area, conventional residual stress measurement methods such as strain gages and X-ray diffractometers, is limited to only the surface layer of the parts. Therefore, neutron which has a high penetration capability was chosen as a probe to measure internal residual stress in this research. By using time of flight neutron diffraction facility VULCAN at Oak Ridge National Laboratory, residual stress for mono-cylinder head, which were made of aluminum alloy, was measured non-distractively. From the result of precise measurement, interior stress distribution was visualized.

In-cylinder surface temperature is of heightened importance for Homogeneous Charge Compression Ignition (HCCI) combustion since the combustion mechanism is thermo-kinetically driven. Thermal Barrier Coatings (TBCs) selectively manipulate the in-cylinder surface temperature, providing an avenue for improving thermal and combustion efficiency. A surface temperature swing during combustion/expansion reduces heat transfer losses, leading to more complete combustion and reduced emissions. At the same time, achieving a highly dynamic response sidesteps preheating of charge during intake and eliminates the volumetric efficiency penalty. The magnitude and temporal profile of the dynamic surface temperature swing is affected by the TBC material properties, thickness, morphology, engine speed, and heat flux from the combustion process. This study follows prior work of authors with Yttria Stabilized Zirconia, which systematically engineered coatings for HCCI combustion.

In order to meet common fuel specifications such as cetane number and volatility, a refinery must blend a number of refinery stocks derived from various process units in the refinery. Fuel chemistry can be significantly altered in meeting fuel specifications. Additionally, fuel specifications are seldom changed in isolation, and the drive to meet one specification may alter other specifications. Homogeneous charge compression ignition (HCCI) engines depend on the kinetic behavior of a fuel to achieve reliable ignition and are expected to be more dependent on fuel specifications and chemistry than today's conventional engines. Regression analysis can help in determining the underlying relationships between fuel specifications, chemistry, and engine performance. Principal Component Analysis (PCA) is used as an adjunct to regression analysis in this work, because of its ability to deal with co-linear variables and potential to uncover ‘hidden’ relationships between the variables.

The effect of B and Si additions on fracture and fatigue performance of vacuum carburized 4320 steel and modifications of 4320 steel containing additions of Si (1.0 and 2.0 wt pct) and B (0 and 17 ppm) was evaluated by bending fatigue testing. Three rates of gas quenching, in 10 bar nitrogen and 15 and 20 bar helium, were used to cool specimens after carburizing. The B, protected by Ti additions, together with the Si additions, increased core hardenability. The B/Si modified steels showed no improvement in fatigue resistance, as measured by endurance limits established by 10 million cycle runouts without fracture. However, scanning electron microscopy showed that Si reduced sensitivity to intergranular fracture or quench embrittlement, a major cause of bending fatigue crack initiation, and contributed to variable fatigue performance, with both low-cycle failures and runout performance at applied stresses significantly above measured endurance limits.

Exhaust gas recirculation (EGR) cooler fouling has become a significant issue for compliance with NOx emissions standards. This paper reports results of a study of fundamental aspects of EGR cooler fouling. An apparatus and procedure were developed to allow surrogate EGR cooler tubes to be exposed to diesel engine exhaust under controlled conditions. The resulting fouled tubes were removed and analyzed. Volatile and non-volatile deposit mass was measured for each tube. Thermal diffusivity of the deposited soot cake was measured by milling a window into the tube and using the Xenon flash lamp method. The heat capacity of the deposit was measured at temperatures up to 430°C and was slightly higher than graphite, presumably due to the presence of hydrocarbons. These measurements were combined to allow calculation of the deposit thermal conductivity, which was determined to be 0.041 W/mK, only ∼1.5 times that of air and much lower than the 304 stainless steel tube (14.7 W/mK).

The friction and wear characteristics of three commercially-available, electrolytic coatings for aluminum engine cylinder bores were compared to those of cast iron liners. A Ni/SiC electrocomposite, a hard anodized treatment, and a Plasma Electrolytic Oxidation (PEO) coating were investigated. ASTM standard test method G133-95, non-firing test method, for linearly reciprocating sliding wear was modified to use segments of piston rings and cylinder liners. Tests were conducted using Mr. Goodwrench™ 5W30 as a lubricant at room temperature. The normal force was 150N, the reciprocating frequency was 15Hz, the stroke length was 8mm, and the test duration was 60 minutes. Kinetic friction coefficients ranged from 0.1 to 0.22, typical of boundary lubrication. The Ni/SiC and cast iron samples exhibited the lowest friction. The wear resistance of the Ni/SiC coating was superior to that of cast iron.

Three dimensional fabrics have seen increasing use lately as composite reinforcements. Advantages over prepreg or chopped fiber processes can include cost, handling, consistent quality, impact behavior, and resistance to delamination [1]. To gain acceptance in the transportation industry it is imperative that properties including dynamic and fatigue behavior be designable. A Progressive Failure Analysis (PFA) was developed jointly by Alpha Star Corp and NASA to predict fatigue life of composites and determine their damage mechanisms so that the life could be extended. The title of this software package is GENOA™, and it was used to focus on the three dimensional fabric called 3WEAVE™ made by 3TEX, Inc. It was discovered through fatigue testing that void content greatly affected fatigue life for the 3D E-glass fabric reinforcing a polyurethane modified vinyl ester resin called Dion 9800 from Reichhold. This is a common characteristic for most structural materials.

Thermal conductivity detection has long been used in gas chromatography to detect hydrogen and other diatomic gases in a gas sample. Thermal conductivity instruments that are not coupled to gas chromatographs are useful for detecting hydrogen in binary gas mixtures, but suffer from significant cross-interference from other gas species that are separated when the detector is used with a gas chromatograph. This study reports a method for using a commercially-available thermal conductivity instrument to detect and quantify hydrogen in a diesel exhaust stream. The instrument time response of approximately 40 seconds is sufficient for steady-state applications. Cross-interference from relevant gas species are quantified and discussed. Measurement uncertainty associated with the corrections for the various species is estimated and practical implications for use of the instrument and method are discussed.

Surfaces of A356 castings were treated by friction stir processing to reduce porosity and to create more uniform distributions of second-phase particles. Dendritic microstructures were eliminated in stir zones. The ultimate tensile strength, ductility, and fatigue life of the cast A356 was increased by friction stir processing. Tensile specimens of cast and friction stir processed metal were also given a T7 heat treatment. Higher tensile strengths and ductilities were also measured for these friction stir processed specimens.

Phosphorous in diesel exhaust is derived via engine oil consumption from the zinc dialkyldithiophosphate (ZDDP) oil additive used for engine wear control. Phosphorous present in the engine exhaust can react with an exhaust catalyst and cause loss of performance through masking or chemical reaction. The primary effect is loss of light-off or low temperature performance. Although the amount of ZDDP used in lube oil is being reduced, it appears that there may is a minimum level of ZDDP needed for engine durability. One of the ways of reducing the effects of the resulting phosphorous on catalysts might be to alter the chemical state of the phosphorous to a less damaging form or to develop catalysts which are more resistant to phosphorous poisoning. In this study, lube oil containing ZDDP was added at an accelerated rate through a variety of engine pathways to simulate various types of engine wear or oil disposal practices.

The most significant obstacle to the widespread use of carbon-fiber-based composites by the automotive industry is the high cost of carbon fibers in comparison to other potential structural materials. Carbon fibers are currently produced by thermal pyrolysis of a polyacrylonitrile (PAN) precursor to obtain the desired properties. The most significant cost factors in the process are the high cost of precursors and the high capital equipment and energy costs in conversion to carbon fiber. The Department of Energy is supporting developmental efforts to reduce costs in both precursor production and conversion areas. This paper describes developments in the conversion process. Because of the unsuccessful results of manufacturing carbon fibers through their direct heating with microwave radiation (variable frequency microwave [VFM] and single frequency microwave [SFM] energy), new avenues were explored for this processing.

The Young's modulus, hardness, and fracture toughness of barium titanate dielectric ceramics in three commercially available multilayer capacitors (MLCs) were measured in-situ using indentation and a mechanical properties microprobe. The three MLCs were equivalent in size (0805), capacitance (0.1 μF) and dielectric type (X7R). The Young's modulus and hardness of the dielectric ceramics in the three MLCs were similar, while there were statistically significant differences in their fracture toughnesses. The results provide insight into the assessment of MLC mechanical reliability, and show that equivalent electrical MLC rating is not necessarily a guarantee that the dielectric ceramics in them will exhibit equivalent mechanical performance.

The goal of this program is to utilize the recently developed high conductivity carbon foam for thermal management in electronics (heat exchangers and heat sinks). The technique used to fabricate the foam produces mesophase pitch-based graphitic foam with extremely high thermal conductivity and an open-celled structure. The thermal properties of the foam have been increased by 79% from 106 to 187 W/m·K at a density of 0.56 g/cm3 through process optimization. It has been demonstrated that when the high-thermal-conductivity graphitic foam is utilized as the core material for the heat exchanger, the effective heat transfer can be increased by at least an order of magnitude compared to traditional designs. A once-through-foam core/aluminum-plated heat exchanger has been fabricated for testing in electronic modules for power inverters.

Several standard methods exist for testing composites, metals and plastics in Mode I fracture. However, these standard test methods have limitations that disqualify them as candidates for testing certain automotive materials. In order to conduct successful fracture toughness tests with these automotive materials, a modified double cantilever beam testing geometry and associated new procedure have been developed. Both the test procedure and the data analysis have been fully documented in a draft standard. Representative SRIM composite, e-coat steel and epoxy were selected to develop and validate the testing procedure.