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Material and design engineers are constantly faced with the task of selecting the best thermoplastic material for interior trim applications. The purpose of this paper is to relate the results of physical property testing and part evaluation to their plastics selection process to allow a more optimized material choice for automotive interior applications. The thermoplastics that were evaluated in this study are the two largest volume plastics used today in interior trim, ABS (acrylonitrile, butadiene, styrene terpolymer) and polypropylene.

Joining dissimilar parts in automotive interior trim applications has been accomplished by utilizing mechanical fasteners, organic and water based adhesives, and more recently, thermoplastic polymers. Recent trends towards reducing solvent emissions and waste management problems, improving the consistency of adhesive application, integrating parts, lowering parts fabrication costs, and designing a specified bond level has increased the use of thermoplastic adhesive films as bonding agents in several applications. Initial efforts began over fifteen years ago with Dow Adhesive Films (DAF) being designed for bonding interior trim fabrics to various substrates. Films have subsequently been designed to improve performance of many interior trim parts in many ways such as: improving water resistance, allowing the part to be molded before installation, imparting a slip surface to a part, and supporting a non-woven fabric.

The construction of most automotive interior headliners requires an adhesive material to bond polyurethane foam-backed fabric to a molded headliner shell. More than ten years ago, The Dow Chemical Company qualified and began supplying a thermoplastic adhesive polymer film for headliner applications which replaced wet adhesive systems at several fabricators. DAF 899 adhesive film has gained acceptance in the industry due to excellent performance, convenience, and cost effectiveness without additional waste handling or volatile organic emission concerns. Recent advancements in headliner design such as additional recessed areas with more demanding contours, new substrate materials and the desire for more efficient operations created an opportunity to design improved adhesive films to meet the emerging industry demands.

Thermoplastic polyurethane/ABS blends are being developed by The Dow Chemical Company to meet the high performance requirements for flexible bumper fascia. Features of these blends include paintability without priming, excellent low temperature impact after painting, good heat resistance, and lower specific gravity than other high performance thermoplastic materials. Thermoplastic polyurethane/ABS blends also have excellent flow properties, which will allow large, complex parts with thin walls to be molded easily.

Polyurethane chemists have been challenged for many years to develop a laboratory scale test to measure the reactivity of polyurethane foam systems. The task is complicated by the need for the test to satisfy the requirements of both the researcher and polyurethane foamer. Numerous tests have been developed to address this task. However, the cup foam test continues to be the industry standard for quick and easy measurement of the overall reactivity of polyurethane foam systems. The characteristics of a small scale laboratory test which measures the rise profile and adiabatic temperature profile of flexible, semi-flexible (semi-rigid) and rigid polyurethane foam systems will be presented.

Novel acoustical materials have been developed. The materials are thermoplastic foams extruded from blends of a polypropylene (PP) resin with an ethylenic polymer resin. One material is an open-cell sheet product made from a blend of a PP resin and a polyolefin elastomer (POE). Another is a large-celled plank foam of substantially closed-cell structure made from a blend of a polypropylene resin and a low density polyethylene (PE) resin. The foam materials are of lightweight, hydrophobic, dust free, recyclable and withstand the temperatures prevailing in automotive uses.

A family of thermoplastic Polyurethane (TPU) blends is being developed to compete in the flexible automotive bumper fascia market. Features of these blends include paintability without adhesion promoter or primer, ease of processing, outstanding low temperature impact strength, good mar resistance, and excellent property retention upon recycling. Laboratory and application performance data indicate that painted TPU/ABS Blend XT2100 regrind can be incorporated up to a 25% level into flexible thermoplastic fascia without sacrificing impact resistance.

Adhesive materials are required to bond cover fabrics to most molded interior headliner substrates. Several thermoplastic adhesive films are qualified and used at U.S. and Japanese OEM's. These adhesive films offer benefits such as convenience, cost effectiveness, excellent adhesive performance and process efficiency while reducing concerns of emissions and hazardous waste handling compared to prior bonding methods. The automotive headliner part is a multifunctional component of the vehicle's interior trim. One of the main headliner functions is to reduce the interior cabin noise. Various adhesive materials are used in a lamination process to form a composite headliner. The purpose of this study was to compare the effects of this lamination process and various alternative adhesive materials on the overall acoustical performance of the headliner composite. Various headliner samples were fabricated under controlled process conditions and tested by an independent acoustics testing lab.

Fast, accurate delivery of metal to the shot well is critical to the success of any cold chamber die casting operation. For some metals this is a simple problem to solve. Magnesium, however, requires more innovative thinking. Simplicity of design is essential for reliable operation in the environment of a magnesium die casting facility. Complex control is required to provide speed and accuracy of shot delivery. Blending these two ingredients to produce a viable system produces a truly innovative shot delivery system for magnesium. Construction details of a newly developed stand alone system for the auto ladling of magnesium will be presented. Data with regard to speed and accuracy will also be presented.

The magnesium alloy AE42 (nominally a 4 % aluminum, 2 % rare earth alloy of magnesium) is a developmental die cast alloy with good strength and creep resistance at elevated temperatures. Standard salt spray corrosion tests have been used with controlled purity AE42 die castings to define the critical iron, nickel and copper contaminant levels below which excellent corrosion performance can be obtained. As previously observed with the magnesium alloys AZ91, AM60, and AS41, the critical iron content is dependent upon the manganese content of the alloy. While the iron:manganese tolerance for AE42 is about the same as that of AM60, the tolerance for the nickel and copper contaminants is greater than that of AZ91. When each of these contaminants is less than the critical level, the salt spray performance was equal to or better than die cast 380 aluminum and cold rolled steel.

A method for refining magnesium scrap which produces consistent, high quality magnesium metal has been developed. High quality magnesium metal is defined in this paper as metal which has heavy metal contaminants controlled within high-purity ASTM chemical specification, and is relatively free of internal impurities such as non-metallic inclusions (oxides and flux) and dissolved gas. The refining process utilizes a protective gas atmosphere, inert gas sparging and filtration techniques, rather than salt based fluxes, to remove both non-metallic inclusions and dissolved gases. Experimentation results of this refining process indicate magnesium scrap can be remelted and refined to a quality equal to or better than virgin ingot, without the introduction of salt based fluxes or a large capital investment.

Continued development of Reinforced Reaction Injection Molding (RRIM) polyurea polymers for toughness, blister resistance and large-part processing as exterior vertical body panels has launched ELPO-compatible exterior outers into automotive assembly-line operations. This allows automotive OEM design to take advantage of the unique molding shapes for side outers and fenders while reducing weight, assembly (DFA) and time/operations costs (DFM). Polyurea RRIM body panels have been successful in meeting the demanding auto industry requirement for lightweight, damage-resistant exterior outer panels as an economical alternative to steel. Design freedom advantages, low prototype cost and tooling savings through predictive modelling have allowed the commercial use of RRIM body panels. This high-temperature-resistant polyurea RRIM composite allows on-line painting, including passing through the steel corrosion protection primer (E-coat) cure environments.

Syndiotactic potystyrene (SPS) is a new semi-crystalline polymer under development by Dow Plastics, a business group of The Dow Chemical Company. The material is differentiated from conventional styrenic polymers in terms of microstructure and physical properties and represents the basis for an entirely new family of materials derived from crystalline polystyrene. SPS exhibits excellent thermal performance with a melting point of 270° C (520° F) combined with resistance to moisture and automotive fluids. Products produced from SPS demonstrate exceptional electrical performance, low specific gravity, competitive toughness and high modulus relative to other semi-crystalline engineering polymers. A wide range of products have been formulated including impact modified and glass reinforced resins for use in specific markets.

The objective of this paper will be to review a novel recycle process involving Structural Reaction Injection Molding(SRIM) which enables a variety of coarsely ground plastic recycle materials to be incorporated into the molded part. What makes this approach novel, is that flexural modulus of the fabricated parts are actually increased when the recycled granulate is employed in the part. This paper will present data for the recycle of a variety of automotive parts, including painted fascia, door skins, covered interior door panels, armrests and instrument panels along with composite bumper beams into the SRIM recycle core process. Resulting part economics will be reviewed along with potential applications to utilize this technology.

The relationship between hydrogen gas and microporosity in magnesium alloy AZ91 was quantified, refuting the belief that hydrogen levels less than the maximum solid solubility are of no detriment. Sand castings were made from melts containing measured levels of hydrogen gas, and the amount of porosity was determined by density measurements. At concentrations below the maximum solid solubility, it was established that the amount of microporosity is directly proportional to the gas content. This supports the premise that dissolved hydrogen gas provides nucleation sites for microporosity, and that it is useful to remove all gas to achieve porosity-free cast parts.

The American public's desire to recycle and the predictions of future recycle mandates are motivating automotive OEMs and plastic suppliers to address the recycling of plastic materials. As a result, the OEMs and plastic industry groups have asked resin suppliers, automotive dismantlers and reprocessors to assist them in studying and developing solutions for the recovery of post-consumer automotive plastics and recycling those materials back into automotive applications. The Dow Chemical Company has been a participant in plastic industry sponsored projects and has initiated numerous research and development activities involving the recycling of automotive thermoplastic and thermoset materials, as well.

The market for composite engine oil sealing components, such as valve covers and oil pans, continues to expand, replacing traditional metal stamping and die casting materials. As the market for these composite components grows, so must the understanding of the material performance characteristics and the relationship of these characteristics to the design of the part. Unlike metals, composites are viscoelastic in nature, exhibiting time-temperature dependant properties. Therefore, the traditional design approach utilizing static property data to predict long-term performance under load and over a wide temperature range will not sufficiently characterize the nonlinear property response of polymeric-based composites. A robust composite sealing design requires complete materials characterization, including long-term creep performance as a function of temperature, loading, and cycling.

The use of low density reinforced Reaction Injection Molded (RIM) substrates for covered interior automotive articles continues to increase globally. Reduced party mass, consolidation of manufacturing steps (labor), and the use of aluminum tooling, instead of steel, are cited advantages that LD-RIM offers when compared to traditional wood based and thermoplastic materials. Two RIM processes are successfully being used to produce covered interior door panels. Low density structural RIM (LD-SRIM), utilizing conventional RIM equipment, involves the placement of a pre-cut fiberglass mat in the tool cavity prior to open-pour injection of the 2-stream liquid urethane components. Low density reinforced RIM (LD-RRIM), utilizing lance cylinder RIM equipment, incorporates reinforcing fibers, such as milled fiberglass or wollastonite, in the liquid resin component. The liquid resin containing reinforcing filler is injected with the isocyanate component into a closed mold.

The persistent occurrence of microporosity defects in AZ91 castings has made it difficult to consistently produce sound parts. Earlier work established that dissolved hydrogen gas causes microporosity defects in AZ91; however, the exact role of hydrogen in the nucleation and growth of microporosity was not determined. In this paper, the behavoir of dissolved hydrogen gas in elemental magnesium, AZ91 alloy, and liquid binary Mg/Al alloys was studied. The results show that during the last stages of solidification, hydrogen gas is rejected from the Mg17Al12 intermetallic compound to assist in the nucleation and/or growth of microporosity.

The opportunity for composites in engine closure systems such as valve covers, oil pans, and timing belt covers is expanding rapidly. The primary driving forces are lighter weight finished components, integrated designs, improved isolation of engine noise, improved materials systems, and matured manufacturing processes for composite materials. Thermoset-based composite materials, particularly those based on high-temperature resistant epoxy vinyl ester matrices, offer improved performance with respect to thermoplastic and thermoset polyester-based composites and can be manufactured using different processing methods. This paper presents the current state-of-the-art design, engineering and optimization techniques for engine closure systems. The performance requirements of different systems such as valve covers and oil pans are explained in detail. Techniques for long-term structural stiffness evaluation, vibration performance assessment and noise transmission estimation are described.