Technical Paper
NO2 Formation in a Diesel Engine
1991-02-01
910231
The formation of NO2 in the cylinder of a diesel engine has been investigated using a total cylinder sampling technique and a simple kinetic model. Exhaust measurements of NO2 as a function of equivalence ratio and as function of time after engine start were made. Samples obtained by total cylinder sampling from an operating direct injection diesel engine showed NO2/NO ratios of 25 to 50%. This is much higher than the 1 to 3% which was measured in the exhaust. Simulations of the sampling process indicate that conversion of NO to NO2 is at least partially responsible for the high NO2/NO measurements. However, the processes which produce the NO to NO2 conversion during the sampling also occur during normal combustion. This may lead to high NO2 concentrations during the combustion cycle which are then lowered during the expansion to the measured exhaust concentrations.