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A passive thermal management system (TMS) using composite phase change material (PCM) for large-capacity, rectangular lithium-ion batteries is designed. A battery module consisting of six Li-ion cells connected in series was investigated as a basic unit. The passive TMS for the module has three configurations according to the contact area between cells and the composite PCM, i.e., surrounding, front-contacted and side-contacted schemes. Firstly, heat generation rate of the battery cell was calculated using the Bernardi equation based on experimentally measured heat source terms (i.e. the internal resistance and the entropy coefficient). Physical and thermal properties such as density, phase change temperature, latent heat and thermal conductivity of the composite PCM were also obtained by experimental methods. Thereafter, thermal response of the battery modules with the three TMS configurations was simulated using 3D finite element analysis (FEA) modeling in ANSYS Fluent.

The thermophysical parameters and amount of composite phase change materials (PCMs) have decisive influence on the thermal control effects of thermal management systems (TMSs). At the same time, the various thermophysical parameters of the composite PCM are interrelated. For example, increasing the thermal conductivity is bound to mean a decrease in the latent heat of phase change, so a balance needs to be achieved between these parameters. In this paper, a prismatic LiFePO4 battery cell cooled by composite PCM is comprehensively analyzed by changing the phase change temperature, thermal conductivity and amount of composite PCM. The influence of the composite PCM parameters on the cooling and temperature homogenization effect of the TMS is analyzed. which can give useful guide to the preparation of composite PCMs and design of the heat transfer enhancement methods for TMSs.

As one of the most crucial components in electric vehicles, power batteries generate abundant heat during charging and discharging processes. Thermal management system (TMS), which is designed to keep the battery cells within an optimum temperature range and to maintain an even temperature distribution from cell to cell, is vital for the high efficiency, long calendar life and reliable safety of these power batteries. With the desirable features of low system complexity, light weight, high energy efficiency and good battery thermal uniformity, thermal management using composite phase change materials (PCMs) has drawn great attention in the past fifteen years. In the hope of supplying helpful guidelines for the design of the PCM-based TMSs, this work begins with the summarization of the most commonly applied heat transfer enhancement methods (i.e., the use of thermally conductive particles, metal fin, expanded graphite matrix and metal foam) for PCMs by different researchers.

With the advantages of flexible size and high energy density etc., pouch-type lithium ion battery cells with large capacity have been found more and more applications in electric vehicles. For these large-scale battery cells, thermal uniformity is vital for their safety and cycle life. To be specific, temperature gradients are expected to cause different degradation rates of active materials in different areas, which is possible to cause early failure or even fire and explosion of the battery cell. Thus, it is necessary to illustrate the batterie’s thermal uniformity in detail under different operating conditions. This work investigated the thermal uniformity of two 36 Ah pouch-type NCM/C battery cells with different sizes using both the thermal imaging method and thermoelectric effect method with K-type thermocouples. Experimental results show that there is an obvious temperature gradient on the surface of the pouch-type battery cell.

Thermal propagation test of lithium-ion battery is an important method to verify the safety of battery system, and how to effectively trigger the thermal runaway of a cell and minimize the energy introduced into the system become the key of test method design. In this work, the influence of different heating area and different heating power on thermal runaway of prismatic cells and pouch cells is studied. The results show that when the heating area is fixed, the heating power increases, the heating time required to trigger the thermal runaway of the cells becomes shorter. The energy needed to be introduced becomes smaller, but there will be a minimum value of the introduced energy. On the other hand, the thermal runaway results of prismatic cells are more sensitive to the change of heating area, and the thermal runaway results of pouch cells are more sensitive to heating power.

With the increasing frequency of fire incidents of electric vehicles, the safety of power batteries has attracted more and more attention. At present, the research on the safety of power batteries is mainly focused on fresh batteries. As the state of health of batteries deepens, how the safety of the battery evolves is not clear enough so far. This paper analyzes the external short-circuit safety of a NCM/C rectangular battery under different state of charges. The results show that when the cycle number is less than 800, the maximum temperature of the battery during short-circuit is below 130 °C. The main failure mode of the battery is bulging in volume or opening of the explosion-proof valve and there is no obvious regularity between the failure mode with the cycle life. However, when the cycle number reaches 1000, the battery goes into thermal runaway during the safety test.