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Toyota and BP have performed a collaborative study to understand the impact of fuel composition on the combustion and emissions of a prototype 1.8L lean boosted engine. The fuel matrix was designed to understand better the impact of a range of fuel properties on fundamental combustion characteristics including thermal efficiency, combustion duration, exhaust emissions and extension of lean limit. Most of the fuels in the test matrix were in the RON range of 96 - 102, although ethanol and other high octane components were used in some fuels to increase RON to the range 104 - 108. The oxygen content ranged from 2 - 28%, and constituents included biocomponents, combustion improving additives and novel blend components. Performance and emissions tests were conducted over a range of engine operating conditions. Thermal efficiency was mapped at stoichiometric and lean conditions, and the limit of lean combustion was established for different fuels.