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This paper describes the results of permeation and sorption tests conducted to assess the properties of several plastic materials as barriers to fuel. The materials examined include ethylene-vinyl alcohol copolymers (EVOH), nylon, high density polyethylene, polyketone, poly-vinyledene fluoride (PVDF) as well as tetra-fluoro-ethylene, hexa-fluoro-propylene and vinyledene fluoride terpolymers (THV). The permeation from thin films of these materials exposed to methanol or CM15 was analyzed (speciated) by gas chromatography. These results are compared to those of parallel sorption experiments conducted on the same materials. The goal of this work is to determine the materials best suited for fuel barrier applications.

This paper presents an extensive set of permeation data on automotive fuel system materials. It adds significantly to the information provided by the same authors in SAE paper 983160 [1]. The permeation measurements refer to three different test fuels: fuel C, CE10 and CM15 at 40, 50 and 60°C. The materials examined include poly-ethylenes, nylons, polyketons, ethylene-vinyl alcohol copolymers, acetals, fluoropolymers and fluoroelastomers. These data are important in the design of automotive fuel system components capable of meeting LEVII or PZEV requirements. In particular, data of this kind are crucial in optimizing the permeation performance of multilayer structures for fuel system applications.