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While developing one of the first commercialized Super Ultra Low Emission Vehicles, one vehicle manufacturer also improved the method for measuring low level hydrocarbons [1]. This was accomplished by enhancing the Constant Volume Sample System, and correcting hydrocarbon measurements from the Flame Ionization Detector hydrocarbon analyzer for the effect of oxygen quench. Based on the manufacturer's results, it appears that the variation in oxygen content of the calibration gas, span gas, zero gas, and sample gas can affect the accuracy of low level hydrocarbon measurement. Within the last couple of years, the United States Environmental Protection Agency and the California Air Resources Board approved the Bag Mini Diluter method for emission sampling [2,3]. This method was developed by the American auto industry in cooperation with government agencies within the American Industry/Government Emissions Research Consortium.

As automakers begin to develop and certify vehicles that meet the California Air Resources Board LEV II and Environmental Protection Agency Tier II Regulations, the study/usage of the Bag Mini-Diluter (BMD, or Mini-Diluter) sampling system continues to increase. Previous papers have provided an overview of the BMD and compared the measurements from the BMD to the measurements from a traditional constant volume sampler (CVS). These papers have suggested that the BMD approach offers new opportunities to improve the quality of vehicle exhaust measurement at very low levels, which will be crucial for accurate measurements on vehicles meeting LEV II SULEV standards (NMOG = 10 mg/mile, NOx = 20 mg/mile). This paper continues the effort to study and implement the BMD sampling system as the optimal sampling system for SULEV measurements. Based on the results from previous testing, a number of investigations have been initiated to improve the quality and understanding of BMD measurements.

For the past several years, manufacturers have been developing emission measurement systems for Super Ultra Low Emission (SULEV) measurements. The Bag Mini-Diluter (BMD) with an advanced exhaust flow measurement device is designed as an alternative to the traditional method for sampling vehicle exhaust, the constant volume sampler (CVS). Exhaust sampling instruments require system verification tests. The system verification test described and mandated for the CVS in the Code of Federal Regulations (CFR) §86.119-90(c) is a simulated test with propane. The very low concentration measurements required for SULEV regulations demand a more enhanced and accurate verification technique and procedure than the method described in the CFR. This investigation focuses on the technique and necessary equipment for verifying system integrity of the entire emission sampling system, including the Bag Mini-Diluter and the exhaust flow measurement device in the test cell.

The Vehicle Exhaust Emissions Simulator was developed to evaluate the performance of vehicle emissions sampling and analytical systems. The simulator produces a representative tailpipe volume flow rate containing up to five emission constituents, injected via mass flow controllers (MFCs). Eliminating the variability of test results associated with the vehicle, driver, and dynamometer makes the simulator an ideal quality control tool for use in commissioning new test cells, checking data correlation between test cells, and evaluating overall system performance. Earlier vehicle emissions simulators being used in the industry were primarily for checking Constant Volume Samplers (CVSs) and Bag Benches but they did not have the ability to properly simulate tailpipe volume.

With the need for emission measurements of super ultra low emission vehicles (SULEV), analyzer manufacturers have been required to produce more precise and accurate analyzers. In order to compare analyzers, the customer must understand the different specifications used by the analyzer manufacturers. One specification that some manufacturers have used is the limit of detection (LOD) to indicate the reliability of the analyzer output at low concentrations. There are various methods for determining the LOD for a given analyzer. The authors will demonstrate how variations in methodology can produce different LOD values for a specific analyzer and what it means for the automotive emission analyzers. It is also demonstrated that the standard deviations of a zero signal, which is related to LOD, can be heavily influenced by data processing, such as data length in use and/or data smoothing. The LOD values obtained will be compared to the limit of quantification (LOQ) for that analyzer.

The Bag Mini-diluter (BMD) is a proportional exhaust sampling system that is being studied as an improved measurement system for ultra-low level vehicle exhaust emissions. The traditional method for sampling vehicle exhaust has been the constant volume sampler (CVS) technique. This method dilutes the entire exhaust output from the vehicle, meters the mixture, and then takes a proportional sample for measurement. In contrast, the Mini-diluter sampling method meters a small sample of raw exhaust, and then dilutes this sample to a fixed dilution ratio. This approach offers new opportunities to improve the quality of the sample measurement at very low levels, which will be crucial for accurate vehicle exhaust emission measurements on vehicles that meet the ULEV and SULEV standards. A number of test programs have compared the performance of the Mini-diluter to the CVS on vehicles certified to Tier 1 and LEV standards, and the results demonstrated favorable correlation.

As automakers begin to develop and certify vehicles that meet the California Air Resources Board LEV II and Environmental Protection Agency Tier II Regulations, emissions test cells must be designed and implemented that are capable of accurate low-level measurements. A new test cell has been installed at Ford Motor Company for use in testing vehicles that meet the stringent Partial Zero Emission Vehicle tailpipe requirements (NMOG = 10 mg/mile, NOx = 20 mg/mile). This test cell includes a redesigned Bag Mini-Diluter (BMD), improved analytical benches, an ultrasonic exhaust flow meter with an integrated tailpipe pressure control system, a conventional constant volume sampler (CVS), and a moveable electric dynamometer. The Bag Mini-Diluter will be used as the primary sampling system for the tailpipe measurements. The moveable electric dynamometer enables the test cell to be configured so that the vehicle is moved to the test equipment rather than moving the test equipment to the vehicle.