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The purpose of this paper is to investigate the mixture formation and optimize the operating conditions under cold start in a stoichiometric (λ=1) GDI engine with wall-guided piston using a 3D commercial code, STAR-CD [8]. For GDI engine under cold start, it can be difficult to carry out the optimization of operating conditions by engine test alone without the understanding of mixture formation inside the combustion chamber. In this study, three cold start conditions of the catalyst heating mode with split injection, the cranking under freezing temperature and acceleration before engine warm-up which causes oil dilution were calculated. In particular, injection strategy for each cold start condition were optimized and compared to the engine test data. The previously validated spray models [6] were applied to the analysis of the spray formation and mixing process inside the combustion chamber.