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In the last years, there has been an increasing concern on the emission of ultrafine particles in the atmosphere. A detailed study of formation and oxidation of these particles in the environment of the diesel cylinder presents many experimental difficulties due to the high temperatures, pressures and extremely reactive intermediate species. In this paper, in order to follow the different phases of diesel combustion process, high temporal and spatial resolution optical techniques were applied in the optically accessible chamber of diesel engine, at 2000 rpm and A/F=80:1 and 60:1. Simultaneous extinction, scattering and flame chemiluminescence measurements from UV to visible were carried out, in order to study the diesel combustion process from the droplet ignition to the formation of soot, through the growth of its precursors.

Polychromatic extinction and chemiluminescence techniques, from ultraviolet to visible, were applied in an optical diesel engine, in order to analyze the temporal and spatial evolution of a high pressure fuel jet interacting with a swirling air motion. A fully flexible Common Rail fuel injection system equipped with a single hole nozzle was used. The experiments were performed at fixed engine speed and air/fuel ratio for three injection strategies. The first one consisted of a main injection to compare with those operating at low pressure injection. The other ones were based on a pilot and main injections, typical of current direct injection diesel engines, with different dwell time. A detailed investigation of the mixture formation process inside the combustion chamber during the ignition delay time was performed. The liquid and vapor fuel distribution in the combustion chamber was obtained analyzing the polychromatic extinction spectra.

Conventional methods to measure gas concentrations and, in particular, NO are typically based on sampling by valve, sample treatment and subsequent analysis. These methods suffer low spatial and temporal resolution. The introduction of high energy lasers in combination with fast detection systems allowed to detect the NO distribution inside optically accessible Diesel engines. In this paper, a high spatial and temporal resolution in-situ technique based on ultraviolet - visible absorption spectroscopy is proposed. The characterization of the combustion process by the detection of gaseous compounds from the start of combustion until the exhaust phase was performed. In particular, this technique allows the simultaneous detection of NO and OH absolute concentrations inside an optically accessible Diesel combustion chamber.

Non-intrusive diagnostic techniques based on broadband (190-550 nm) extinction and scattering spectroscopy were applied to undiluted exhaust Common Rail (CR) diesel engine. The influence of engine speed and load on soot mass concentration, size distribution of emitted particles and NOx concentration was analysed. NOx concentration was evaluated by “in situ” ultraviolet-visible absorption measurements and compared with those obtained by conventional analyser. The extinction and scattering spectra were compared with those evaluated by the Lorenz-Mie model for spherical particles in order to retrieve the size, the number concentration of the emitted particles and particulate mass.

Direct-injection spark-ignition (DISI) engines have been adopted increasingly by the automotive industry in recent years due to their performance, reduced impact on the environment, and customer demand for advanced technology. However, detailed combustion processes in such engines are still not thoroughly analysed and understood. This work reports on the effects of different control parameters on the combustion process, such as fuel type, ignition timing and exhaust gas recirculation. Pure n-butanol and gasoline were used. All experiments were performed at 2000 rpm and 100 bar injection pressure in a transparent single-cylinder DISI engine equipped with the head of a commercial turbocharged engine with similar geometrical specifications (bore, stroke, compression ratio). Crank angle resolved 2D chemiluminescence in the UV range for OH radical and CO2 detection was performed with an ICCD camera and a high-speed CMOS camera was used for cycle resolved imaging.