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Engine and flow reactor experiments were conducted to determine the impact of biodiesel relative to ultra-low-sulfur diesel (ULSD) on inhibition of the selective catalytic reduction (SCR) reaction over an Fe-zeolite catalyst. Fe-zeolite SCR catalysts have the ability to adsorb and store unburned hydrocarbons (HC) at temperatures below 300°C. These stored HCs inhibit or block NOx-ammonia reaction sites at low temperatures. Although biodiesel is not a hydrocarbon, similar effects are anticipated for unburned biodiesel and its organic combustion products. Flow reactor experiments indicate that in the absence of exposure to HC or B100, NOx conversion begins at between 100° and 200°C. When exposure to unburned fuel occurs at higher temperatures (250°-400°C), the catalyst is able to adsorb a greater mass of biodiesel than of ULSD. Experiments show that when the catalyst is masked with ULSD, NOx conversion is inhibited until it is heated to 400°C.

Battery electric vehicles possess great potential for decreasing lifecycle costs in medium-duty applications, a market segment currently dominated by internal combustion technology. Characterized by frequent repetition of similar routes and daily return to a central depot, medium-duty vocations are well positioned to leverage the low operating costs of battery electric vehicles. Unfortunately, the range limitation of commercially available battery electric vehicles acts as a barrier to widespread adoption. This paper describes the National Renewable Energy Laboratory's collaboration with the U.S. Department of Energy and industry partners to analyze the use of small hydrogen fuel-cell stacks to extend the range of battery electric vehicles as a means of improving utility, and presumably, increasing market adoption.

It is widely understood that cold ambient temperatures increase vehicle fuel consumption due to heat transfer losses, increased friction (increased viscosity lubricants), and enrichment strategies (accelerated catalyst heating). However, relatively little effort has been dedicated to thoroughly quantifying these impacts across a large set of real world drive cycle data and ambient conditions. This work leverages experimental dynamometer vehicle data collected under various drive cycles and ambient conditions to develop a simplified modeling framework for quantifying thermal effects on vehicle energy consumption. These models are applied over a wide array of real-world usage profiles and typical meteorological data to develop estimates of in-use fuel economy. The paper concludes with a discussion of how this integrated testing/modeling approach may be applied to quantify real-world, off-cycle fuel economy benefits of various technologies.

Electric drive vehicles (EDVs) have complex thermal management requirements not present in conventional vehicles. In addition to cabin conditioning, the energy storage system (ESS) and power electronics and electric motor (PEEM) subsystems also require thermal management. Many current-generation EDVs utilize separate cooling systems, adding both weight and volume, and lack abundant waste heat from an engine for cabin heating. Some use battery energy to heat the cabin via electrical resistance heating, which can result in vehicle range reductions of 50% under cold ambient conditions. These thermal challenges present an opportunity for integrated vehicle thermal management technologies that reduce weight and volume and increase cabin heating efficiency. Bench testing was conducted to evaluate a combined fluid loop technology that unifies the cabin air-conditioning and heating, ESS thermal management, and PEEM cooling into a single liquid coolant-based system.

Battery second use-putting used plug-in electric vehicle (PEV) batteries into secondary service following their automotive tenure-has been proposed as a means to decrease the cost of PEVs while providing low cost energy storage to other fields (e.g., electric utility markets). To understand the value of used automotive batteries, however, we must first answer several key questions related to battery degradation, including: How long will PEV batteries last in automotive service? How healthy will PEV batteries be when they leave automotive service? How long will retired PEV batteries last in second-use service? How well can we best predict the second-use lifetime of a used automotive battery? Under the support of the U.S. Department of Energy's Vehicle Technologies Office, the National Renewable Energy Laboratory has developed a methodology and the requisite tools to answer these questions, including the Battery Lifetime Simulation Tool (BLAST).

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.

Accurate evaluation of vehicles' transient total power requirement helps achieving further improvements in vehicle fuel efficiency. When operated, the air-conditioning (A/C) system is the largest auxiliary load on a vehicle, therefore accurate evaluation of the load it places on the vehicle's engine and/or energy storage system is especially important. Vehicle simulation models, such as "Autonomie," have been used by OEMs to evaluate vehicles' energy performance. However, the load from the A/C system on the engine or on the energy storage system has not always been modeled in sufficient detail. A transient A/C simulation tool incorporated into vehicle simulation models would also provide a tool for developing more efficient A/C systems through a thorough consideration of the transient A/C system performance. The dynamic system simulation software MATLAB/Simulink® is frequently used by vehicle controls engineers to develop new and more efficient vehicle energy system controls.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

Small impurities in the fuel can have a significant impact on the emissions control system performance over the lifetime of the vehicle. Of particular interest in recent studies has been the impact of sodium, potassium, and calcium that can be introduced either through fuel constituents, such as biodiesel, or as lubricant additives. In a collaboration between the National Renewable Energy Laboratory and the Oak Ridge National Laboratory, a series of accelerated aging studies have been performed to understand the potential impact of these metals on the emissions control system. This paper explores the effect of the rate of accelerated aging on the capture of fuel-borne metal impurities in the emission control devices and the subsequent impact on performance. Aging was accelerated by doping the fuel with high levels of the metals of interest. Three separate evaluations were performed, each with a different rate of accelerated aging.

The goal of this project was to demonstrate a low emissions, high efficiency heavy-duty on-highway natural gas engine. The emissions targets for this project are to demonstrate US 2010 emissions standards on the 13-mode steady state test. To meet this goal, a chemically correct combustion (stoichiometric) natural gas engine with exhaust gas recirculation (EGR) and a three way catalyst (TWC) was developed. In addition, a Sturman Industries, Inc. camless Hydraulic Valve Actuation (HVA) system was used to improve efficiency. A Volvo 11 liter diesel engine was converted to operate as a stoichiometric natural gas engine. Operating a natural gas engine with stoichiometric combustion allows for the effective use of a TWC, which can simultaneously oxidize hydrocarbons and carbon monoxide and reduce NOx. High conversion efficiencies are possible through proper control of air-fuel ratio.

Plug-in hybrid electric vehicle (PHEV) technology will provide substantial reduction in petroleum consumption as demonstrated in previous studies. Platform engineering steps including, reduced mass, improved engine efficiency, relaxed performance, improved aerodynamics and rolling resistance can impact both vehicle efficiency and design. Simulations have been completed to quantify the relative impacts of platform engineering on conventional, hybrid, and PHEV powertrain design, cost, and consumption. The application of platform engineering to PHEVs reduced energy storage system requirements by more than 12%, offering potential for more widespread use of PHEV technology in an energy battery supply-limited market. Results also suggest that platform engineering may be a more cost-effective way to reduce petroleum consumption than increasing the energy storage capacity of a PHEV.

Plug-in hybrid electric vehicles (PHEVs) differ from hybrid vehicles (HEVs) with their ability to use off-board electricity generation to recharge their energy storage systems. In addition to possessing charge-sustaining HEV operation capability, PHEVs use the stored electrical energy during a charge-depleting operating period to displace a significant amount of petroleum consumption. The particular operating strategy employed during the charge-depleting mode will significantly influence the component attributes and the value of the PHEV technology. This paper summarizes three potential energy management strategies, and compares the implications of selecting one strategy over another in the context of the aggressiveness and distance of the duty cycle over which the vehicle will likely operate.

The air-conditioning (A/C) compressor load significantly impacts the fuel economy of conventional vehicles and the fuel use/range of plug-in hybrid electric vehicles (PHEV). A National Renewable Energy Laboratory (NREL) vehicle performance analysis shows the operation of the air conditioner reduces the charge depletion range of a 40-mile range PHEV from 18% to 30% in a worst case hot environment. Designing for air conditioning electrical loads impacts PHEV and electric vehicle (EV) energy storage system size and cost. While automobile manufacturers have climate control procedures to assess A/C performance, and the U.S. EPA has the SCO3 drive cycle to measure indirect A/C emissions, there is no automotive industry consensus on a vehicle level A/C fuel use test procedure. With increasing attention on A/C fuel use due to increased regulatory activities and the development of PHEVs and EVs, a test procedure is needed to accurately assess the impact of climate control loads.

Electrifying transportation can reduce or eliminate dependence on foreign fuels, emission of green house gases, and emission of pollutants. One challenge is finding a pathway for vehicles that gains wide market acceptance to achieve a meaningful benefit. This paper evaluates several approaches aimed at making plug-in electric vehicles (EV) and plug-in hybrid electric vehicles (PHEVs) cost-effective including opportunity charging, replacing the battery over the vehicle life, improving battery life, reducing battery cost, and providing electric power directly to the vehicle during a portion of its travel. Many combinations of PHEV electric range and battery power are included. For each case, the model accounts for battery cycle life and the national distribution of driving distances to size the battery optimally. Using the current estimates of battery life and cost, only the dynamically plugged-in pathway was cost-effective to the consumer.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

The National Renewable Energy Laboratory (NREL) collaborated with Millennium Cell and DaimlerChrysler to study heat and water management in a sodium borohydride (NaBH4) storage/processor used to supply hydrogen to a fuel cell in an automotive application. Knowledge of heat and water flows in this system is necessary to maximize the storage concentration of NaBH4, which increases vehicle range. This work helps evaluate the NaBH4 system's potential to meet the FreedomCAR program technical target of 6 wt% hydrogen for hydrogen storage technologies. This paper also illustrates the advantages of integrating the NaBH4 hydrogen processor with the fuel cell.

Delphi and the National Renewable Energy Laboratory (NREL) collaborated to develop a simulation code to model the mechanical and electrical architectures of a series hybrid vehicle simultaneously. This co-simulation code is part of the larger ADVISOR® product created by NREL and diverse partners. Simulation of the macro power flow in a series hybrid vehicle requires both the mechanical drivetrain and the entire electrical architecture. It is desirable to solve the electrical network equations in an environment designed to comprehend such a network and solve the equations in terms of current and voltage. The electrical architecture for the series hybrid vehicle has been modeled in Saber™ to achieve these goals. This electrical architecture includes not only the high-voltage battery, generator, and traction motor, but also the normal low-voltage bus (14V) with loads common to all vehicles.

The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.

Fuel cell hybrid vehicles (FCHVs) use an energy management strategy to partition the power supplied by the fuel cell and energy storage system (ESS). This paper presents an adaptive energy management strategy, created in the ADVISOR™ software, for a series FCHV. The strategy uses a local or “real-time” optimization approach, which aims to reduce total energy consumption at each instantaneous time interval by dynamically adjusting the amount of power supplied by the fuel cell and ESS. Compared with a static control strategy, the adaptive strategy improved the simulated FCHV's fuel economy by 1.4%-8.5%, depending on the drive cycle.

An ADVISOR model of a large sport utility vehicle with a fuel cell / battery hybrid electric drivetrain is developed using validated component models. The vehicle mass, electric traction drive, and total net power available from fuel cells plus batteries are held fixed. Results are presented for a range of fuel cell size from zero (pure battery EV) up to a pure fuel cell vehicle (no battery storage). The fuel economy results show that some degree of hybridization is beneficial, and that there is a complex interaction between the drive cycle dynamics, component efficiencies, and the control strategy.