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The introduction of CO2-reduction technologies like Start-Stop or the Hybrid-Powertrain and the future emissions regulations require a detailed optimization of the engine start-up. The combustion concept development as well as the calibration of the ECU makes it necessary to carry out an explicit thermodynamic analysis of the combustion process during the start-up. As of today, the well-known thermodynamic analysis using in-cylinder pressure traces at stationary condition is transmitted to the highly dynamic engine start-up. Due to this approximation the current models for calculation of the transient wall heat fluxes by Woschni, Hohenberg and Bargende do not lead to desired results. But with a fraction of approximately 40 % of the burnt fuel energy, the wall heat is very important for the calculation of energy balance and for the combustion process analysis during start-up.