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Within the scope of this work, the convective mass transfer to the zirconia sensor element of an exhaust oxygen sensor was analyzed experimentally and numerically. For the experimental setup, a heightened model of an oxygen sensor was built from Lucite® considering the similarity theory. Mass transfer is measured based on the absorption of ammonia and subsequent immediate color reaction. For the numerical investigation, a three-dimensional model of the test rig was built. To predict the flow pattern and the species transport inside the protection tubes, the commercial CFD-Code FLUENT® is used. The model for the mass transfer to the surface is implemented through user-defined functions.