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Lithium-Ion batteries are being considered as a high-energy density replacement for Nickel Metal Hydride (NiMH) batteries in Hybrid Electric Vehicles (HEVs) and in the new Plug-In Hybrids (PHEVs). Although these cells can result in significant reduction in weight and volume, they have several safety related issues that still need to be addressed. We report here on the thermal response of Li-ion cells specifically assembled in our laboratory to test new materials, electrolytes and additives. Improvements in the thermal abuse tolerance of cells will be presented and discussed in terms of the need for overall battery system safety.

The spatial distribution of the mixture equivalence ratio within the squish volume is quantified under non-combusting conditions by planar laser-induced fluorescence (PLIF) of a fuel tracer (toluene). The measurements were made in a single-cylinder, direct-injection, light-duty diesel engine at conditions matched to an early-injection low temperature combustion mode. A fuel amount corresponding to a low load (3.0 bar indicated mean effective pressure) operating condition was introduced with a single injection. Data were acquired during the mixture preparation period from near the start of injection (-22.5° aTDC) until the crank angle where the start of high-temperature heat release normally occurs (-5° aTDC). Despite the opposing squish flow, the fuel jets penetrate through the squish region to the cylinder bore. Although rapid mixing is observed in the head of each jet, rich regions remain at the head at the start of high-temperature heat release.

In a recent experimental study the in-cylinder spatial distribution of mixture equivalence ratio was quantified under non-combusting conditions by planar laser-induced fluorescence (PLIF) of a fuel tracer (toluene). The measurements were made in a single-cylinder, direct-injection, light-duty diesel engine at conditions matched to an early-injection low-temperature combustion mode. A fuel amount corresponding to a low load (3.0 bar indicated mean effective pressure) operating condition was introduced with a single injection at -23.6° ATDC. The data were acquired during the mixture preparation period from near the start of injection (-22.5° ATDC) until the crank angle where the start of high-temperature heat release normally occurs (-5° ATDC). In the present study the measured in-cylinder images are compared with a fully resolved three-dimensional CFD model, namely KIVA3V-RANS simulations.

We present a parametric analysis of electric vehicle (EV) adoption rates and the corresponding contribution to greenhouse gas (GHG) reduction in the US light-duty vehicle (LDV) fleet through 2050. The analysis is performed with a system dynamics based model of the supply-demand interactions among the fleet, its fuels, and the corresponding primary energy sources. The differentiating feature of the model is the ability to conduct global sensitivity and parametric trade-space analyses. We find that many factors impact the adoption rates of EVs. These include, in particular, policy initiatives that encourage consumers to consider lifetime ownership costs, the price of oil, battery performance, as well as the pace of technological development for all powertrains (conventional internal combustion engines included). Widespread EV adoption can have noticeable impact on petroleum consumption and GHG emissions by the LDV fleet.

With the introduction of more fuel cell electric vehicles (FCEVs) on U.S. roadways, especially in California, the need for available hydrogen refueling stations is growing. While funding from the California Energy Commission is helping to solve this problem, solutions need to be developed and implemented to help reduce the time to commission a hydrogen station. The current practice of hydrogen station acceptance can take months because each vehicle manufacturer conducts their own testing and evaluation. This process is not practical or sufficient to support the timely development of a hydrogen fueling station network. To address this issue, as part of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project Sandia National Laboratories and the National Renewable Energy Laboratory along with a team of stakeholders and contractor Powertech Labs has developed the Hydrogen Station Equipment Performance (HyStEP) Device.

Transients in the rate of injection (ROI) with respect to time are ever-present in direct-injection engines, even with common-rail fueling. The shape of the injection ramp-up and ramp-down affects spray penetration and mixing, particularly with multiple-injection schedules currently in practice. Ultimately, the accuracy of CFD model predictions used to optimize the combustion process depends upon the accuracy of the ROI utilized as fuel input boundary conditions. But experimental difficulties in the measurement of ROI, as well as real-world affects that change the ROI from the bench to the engine, add uncertainty that may be mistaken for weaknesses in spray modeling instead of errors in boundary conditions. In this work we use detailed, time-resolved measurements of penetration at the Spray A conditions of the Engine Combustion Network to rigorously guide the necessary ROI shape required to match penetration in jet models that allow variable rate of injection.

The accurate quantification and control of mixture stoichiometry is critical in many applications using new combustion strategies and fuels (e.g., homogeneous charge compression ignition, gasoline direct injection, and oxygenated fuels). The parameter typically used to quantify mixture stoichiometry (i.e., the proximity of a reactant mixture to its stoichiometric condition) is the equivalence ratio, ϕ. The traditional definition of ϕ is based on the relative amounts of fuel and oxidizer molecules in a mixture. This definition provides an accurate measure of mixture stoichiometry when the fuel molecule does not contain oxidizer elements and when the oxidizer molecule does not contain fuel elements. However, the traditional definition of ϕ leads to problems when the fuel molecule contains an oxidizer element, as is the case when an oxygenated fuel is used, or once reactions have started and the fuel has begun to oxidize.

The Advanced Battery Readiness Ad Hoc Working Group, a government- industry forum sponsored by the United States Department of Energy, is charged with assessing environmental and safety issues associated with advanced batteries for electric and hybrid electric vehicles. Electric and hybrid electric vehicles require sophisticated advanced battery storage systems. Frequently, toxic, reactive, and flammable substances are used in the energy storage systems. Often, the substances have safety, recycling, and shipping implications with respect to U.S. Environmental Protection Agency and Department of Transportation regulations. To facilitate commercialization, reg-ulations must either be modified or newly developed. Government-industry coordination has expedited needed regulatory changes, and promoted other partnerships to achieve environmental and safety solutions.

A variety of diagnostic techniques useful for the study of cold start phenomena are presented. Although the tools are demonstrated in a port fuel-injected engine, they are also suitable for direct-injection gasoline engines. A very useful technique, seemingly forgotten in the literature (and applicable to diesel engines as well), is the use of a short focal-length lens inside a Bowditch piston to expand the field-of-view. Rather than being limited by the clear aperture of the window in the piston, this technique permits the entire combustion chamber and the top section of the cylinder liner to be seen. Results using this technique are presented for the imaging of pool fires and laser-induced fluorescence of fuel films.

Advanced rechargeable lithium-ion batteries are presently being developed and commercialized worldwide for use in consumer electronics, military and space applications. The motivation behind these efforts involves, among other things, a favorable combination of energy and power density. For some of the applications the power sources may need to perform at a reasonable rate at subambient temperatures. Given the nature of the lithium-ion cell chemistry the low temperature performance of the cells may not be very good. At Sandia National Laboratories, we have used different electrochemical techniques such as impedance and charge/discharge at ambient and subambient temperatures to probe the various electrochemical processes that are occurring in Li-ion cells. The purpose of this study is to identify the component that reduces the cell performance at subambient temperatures.

Thermal batteries are normally constructed using pressed-powder anode, separator, and cathode pellets (discs). However, parts less than 0.010” thick are difficult to press from the starting powders. The use of plasma spraying to deposit thin pyrite films onto a stainless steel substrate was examined as an alternative to pressed-powder cathodes. The electrodes were tested under isothermal conditions and constant-current discharge over a temperature range of 400°C to 550°C using a standard LiSi anode and a separator based on the LiCIKCI eutectic. The plasma-sprayed cathodes were also evaluated in similar 5-cell thermal batteries. Cells and batteries using pressed-powder cathodes were tested under the same conditions for comparative purposes.

Silica aerogels have 1/3 the thermal conductivity of the best commercial composite insulations, or ~13 mW/m-K at 25 °C. However, aerogels are transparent in the near IR region of 4-7 μm, which is where the radiation peak from a thermal-battery stack occurs. Titania and carbon-black powders were examined as thermal opacifiers, to reduce radiation at temperatures between 300°C and 600°C, which spans the range of operating temperature for most thermal batteries. The effectiveness of the various opacifiers depended on the loading, with the best overall results being obtained using aerogels filled with carbon black. Fabrication and strength issues still remain, however.

The impact of 50 ppm intake seeding of ozone (O3) on performance and emissions characteristics was explored in a single-cylinder research engine operated under lean spark assisted compression ignition (SACI) conditions. Optical access into the engine enabled complementary crank angle resolved measurements of in-cylinder O3 concentration via ultraviolet (UV) light absorption. Experiments were performed at moderate loads (4 - 5 bar indicated mean effective pressure) and low-to-moderate engine speeds (800 - 1400 revolutions per minute). Each operating condition featured a single early main injection and maximum brake torque spark timing. Intake pressure was fixed at 1.0 bar, while intake temperatures were varied between 42 - 80 °C. Moderate amounts of internal residuals (12 - 20%) were retained through the use of positive valve overlap. Ozone addition was to found stabilize combustion relative to similar conditions without O3 addition by promoting end gas auto-ignition.

As a part of NASA’s efforts in space, options are being examined for an Artemis moon base project to be deployed. This project requires a system of interconnected, but separate, DC microgrids for habitation, mining, and fuel processing. This in-place use of power resources is called in-situ resource utilization (ISRU). These microgrids are to be separated by 9-12 km and each contains a photovoltaic (PV) source, energy storage systems (ESS), and a variety of loads, separated by level of criticality in operation. The separate microgrids need to be able to transfer power between themselves in cases where there are generation shortfall, faults, or other failures in order to keep more critical loads running and ensure safety of personnel and the success of mission goals. In this work, a 2 grid microgrid system is analyzed involving a habitation unit and a mining unit separated by a tie line.