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The scope of this work is to propose a methodology to define multicomponent surrogate mixtures which describe the main evaporation characteristics of real gasoline fuels. Since real fuels are commonly complex mixtures with hundreds or thousands of hydrocarbons, their exact composition is generally not known. Only global characteristics are standardized. An accurate modeling of such complex mixtures in 3D-CFD requires the definition of a suitable surrogate. So far, surrogate mixtures have mostly been defined based on their combustion properties, such as ignition delay or burning velocity, irrespective of their evaporation characteristics. For this reason, in this work, a systematic study is carried out to develop a methodology to define mixtures of representative components that mimic the evaporation behavior of real fuels.