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Impedance is an important parameter of power lithium-ion batteries, which can represent battery characteristics and can also be used as an indicator for battery fault diagnosis. Since Electrochemical Impedance Spectroscopy (EIS) includes various electrode processes and information, it is more significant and worthwhile for lithium-ion batteries research. However, it is quite difficult to attain EIS online because of the nonlinear characteristics of batteries. Therefore, this paper focus on studying the nonlinear impedance characteristics of lithium-ion batteries and proposing a new method to calculate the EIS online based on Fast Fourier Transform (FFT). Data similarity analysis is used to study the influence of resting time, excitation current amplitude, bias current amplitude and the state of charge (SOC) on the impedance quantitatively.