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A passive thermal management system (TMS) using composite phase change material (PCM) for large-capacity, rectangular lithium-ion batteries is designed. A battery module consisting of six Li-ion cells connected in series was investigated as a basic unit. The passive TMS for the module has three configurations according to the contact area between cells and the composite PCM, i.e., surrounding, front-contacted and side-contacted schemes. Firstly, heat generation rate of the battery cell was calculated using the Bernardi equation based on experimentally measured heat source terms (i.e. the internal resistance and the entropy coefficient). Physical and thermal properties such as density, phase change temperature, latent heat and thermal conductivity of the composite PCM were also obtained by experimental methods. Thereafter, thermal response of the battery modules with the three TMS configurations was simulated using 3D finite element analysis (FEA) modeling in ANSYS Fluent.

Fuel cell vehicles (FCV) have become a promising transportation tool because of their high efficiency, fast response and zero-emission. However, the cold start problem is one of the main obstacles to limit the further commercialization of FCV in cold weather countries. Many efforts have made to improve the cold start ability. This review presents comprehensive heating methods and influence factors of the research progress in solving the Proton Exchange Membrane Fuel Cells (PEMFC) system cold start problems with more than 100 patents, papers and reports, which may do some help for PEMFC system cold start from the point of practical utilization. Firstly, recent achievements and goals will be summarized in the introduction part. Then, regarding the heating strategies for the PEMFC system cold start, different heating solutions are classified into self-heating strategies and auxiliary-heating heating depending on their heating sources providing approach.

The thermophysical parameters and amount of composite phase change materials (PCMs) have decisive influence on the thermal control effects of thermal management systems (TMSs). At the same time, the various thermophysical parameters of the composite PCM are interrelated. For example, increasing the thermal conductivity is bound to mean a decrease in the latent heat of phase change, so a balance needs to be achieved between these parameters. In this paper, a prismatic LiFePO4 battery cell cooled by composite PCM is comprehensively analyzed by changing the phase change temperature, thermal conductivity and amount of composite PCM. The influence of the composite PCM parameters on the cooling and temperature homogenization effect of the TMS is analyzed. which can give useful guide to the preparation of composite PCMs and design of the heat transfer enhancement methods for TMSs.

As one of the most crucial components in electric vehicles, power batteries generate abundant heat during charging and discharging processes. Thermal management system (TMS), which is designed to keep the battery cells within an optimum temperature range and to maintain an even temperature distribution from cell to cell, is vital for the high efficiency, long calendar life and reliable safety of these power batteries. With the desirable features of low system complexity, light weight, high energy efficiency and good battery thermal uniformity, thermal management using composite phase change materials (PCMs) has drawn great attention in the past fifteen years. In the hope of supplying helpful guidelines for the design of the PCM-based TMSs, this work begins with the summarization of the most commonly applied heat transfer enhancement methods (i.e., the use of thermally conductive particles, metal fin, expanded graphite matrix and metal foam) for PCMs by different researchers.

Proton exchange membrane fuel cell (PEMFC) system is considered as one of the most popular power sources because of its high energy density, fast dynamic response and zero pollution. However, the start-up at low temperature (e.g. - 30 °C) is still a major challenge for its wide application due to water freezing in Membrane Electrode Assembly (MEA). In this paper, a cold start test process in an environment cabin with auxiliary heat was carried out for a full power automotive PEMFC system, including normal operation, shutdown purge and cold start processes analysis from -30°C. Rated power of this stack is 100kW at the current density of 1.4A/cm2 and relevant maximum output power can reach to 120kW. In order to reduce the damage of high potential to MEA, on-load purge with a current of 30A is conducted to removing extra water in stack for improving cold start ability. Based on corresponding control strategy, cold start was realized successfully within 110s.

Cold start capability is one of remaining major challenges in realizing PEMFC (Proton Exchange Membrane Fuel Cell) technology for automotive applications. Gas purge is a common and integral shutdown procedure of a PEMFC automotive in subzero temperature. A dryer membrane electrode assembly (MEA) can store more water before it gets saturated and ice starts to penetrate in the open pores of porous media, thus enhancing cold start capability of a PEMFC. Therefore, gas purge is always performed prior to fuel cell shutdown to minimize residual water in a PEMFC. In the hope of improving effectiveness of purge in a PEMFC vehicle, two important purge parameters are evaluated including purge time and energy requirement. In practice, an optimized gas purge protocol should be developed with minimal parasitic energy, short purge duration and no degradation of components. To conclude, the cold start capability and performance can be consolidated by proper design of gas purge strategies.

Cold start remains a major obstacle to the commercialization of proton exchange membrane fuel cell (PEMFC), however, there are few studies on the cold start characteristics, especially at a complicated stack level. In this study, a novel layer-lumped numerical model with higher computational efficiency is proposed to investigate the cold start behavior of PEMFC stack, in which phase transition, heat transfer and electrochemical reaction are comprehensively considered. Besides, phase transition mechanisms are reconstructed based on the assumption that super-cooled water exists within the cell. With this model, the inconsistency of the stack temperature distribution and output performance is presented, some constant loading voltage strategies are investigated, and a linear variable controlling voltage strategy is developed.