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The backward flow of the hot burned gas surrounding a diesel flame was found to be one of the factors dominating the set-off length (also called the lift-off length), that is, the distance from a nozzle exit into which a diffusion flame cannot intrude. In the combustion chamber of an actual diesel engine, the entrainment of the surrounding gas into a spray jet from a multi-hole nozzle is restricted by the walls and adjacent spray jets, which induces the backward flow of the surrounding gas. A new momentum theory to calculate the backward flow velocity was established by extending Wakuri's momentum theory. Shadowgraph imaging in an optical engine successfully visualized the backward flow of the hot burned gas.

A method of real time oil concentration measurment has been developed utilizing the effect of ultraviolet light absorption by lubricating oil in the liquid refrigerant line of an automotive air conditioning system. The light wavelengths from 200nm to 370nm are selected based on the ultraviolet light absorption sensitivity of the oils and refrigerants (CFC12,HFC134a). The effects of temperature,pressure and contaminantion on the absorbance of light are investigated in order to determine how these parameters affect the concentration measurement. The density changes of refrigerants are then compensated in the calculation for the oil concentration. The uncertainties of the overall concentration measurement are less than ±0.1 weight percent at 1 weight percent concentration. A transient oil circulation of the automotive air conditioner is measured by using this method.

The hole diameter of injection nozzles in diesel engines has become smaller and the nozzle coking could potentially cause injection characteristics and emissions to deteriorate. In this research, engine tests with zinc-added fuels, deposit analyses, laboratory tests and numerical calculations were carried out to clarify the deposit formation mechanisms. In the initial phase of deposit formation, lower zinc carboxylate formed close to the nozzle hole outlet by reactions between zinc in the fuel and lower carboxylic acid in the combustion gas. In the subsequent growth phase, the main component changed to zinc carbonate close to nozzle hole inlet by reactions with CO₂ in the combustion gas. Metal components and combustion gases are essential elements in the composition of these deposits. One way of removing these deposits is to utilize cavitations inside the nozzle holes.

In recent years, problems such as global warming, the depletion of natural resources, and air pollution caused by emissions are emerging on a global scale. These problems call for efforts directed toward the development of fuel-efficient engines and exhaust gas reduction measures. As a solution to these issues, performance improvements should be achieved on the oil that lubricates the sliding sections of engines. This report points to features required of future engine oil-such as contribution to fuel consumption, minimized adverse effects on the exhaust gas aftertreatment system, and improved reliability achieved by sludge reduction-and discusses the significance of these features. For engine oil to contribution of engine oil to lower fuel consumption, we examined the effects of reduced oil viscosity on friction using gasoline and diesel engines.

Fretting fatigue mechanism of rapidly solidified powder aluminum alloy has been studied by model tests and analysis using fracture mechanics. The factors which influences upon fretting scar formation and fatigue crack propagation were the main concerns in the present work. In order to investigate the mechanism of fretting scar formation in detail, fretting wear tests in which small amplitude oscillatory movement occurred in the contact region were carried out. Test results showed that the size of fretting scar increased with increasing tangential force coefficient. Characteristics of fretting fatigue crack propagation were analyzed using fracture mechanics. The fatigue limits under fretting conditions were estimated by connecting the applied stress intensity factor range calculated from applied cyclic stress and tangential force, with the threshold stress intensity factor range of small crack.

Diamond-like carbon (DLC) films are of significant interest for the automobile field, because they possess the potential to improve friction properties under various sliding conditions. Among the various DLC films, the authors focus on silicon-containing DLC (DLC-Si) films, which exhibit extremely low friction coefficient under dry sliding conditions in an ambient air atmosphere. The aim of this study is to examine the influence of silicon content in DLC-Si films on the friction property of the films, and to clarify the low friction mechanism of the films. The friction test was conducted under dry sliding conditions. It was found that the films have an exceedingly low friction coefficient (about 0.05) ranging in silicon content from 4 at% to 17 at%. In order to examine the low friction mechanism of the films, surface analyses were done on the wear surface of DLC-Si films slid against bearing steel.

More than twenty years have passed since we invented polymer-clay nanocomposites (PCN), in which only a few wt.-% of silicate is randomly and homogeneously dispersed in the polymer matrix. When molded, these nanocomposites show superior properties compared to pristine polymers such as tensile strength, tensile modulus, heat distortion temperature, gas barrier property, and so on. The number of papers on PCN has increased rapidly in recent years, reaching over 500 only in 2005. As the pioneers of the new technology, we will review its history highlighting our works. Epoch-making events of PCN are as follows: In 1985, The first PCN, nylon 6-clay hybrid (NCH), was invented. In 1987, NCH was first presented at the ACS Fall Meetings. In 1989, NCH was presented at the MRS Fall Meetings, firing PCN. In 1989, Toyota launched cars equipped with a NCH part. In 1996, Clay was found to cause a memory effect in liquid crystals.

In order to enhance the catalytic performance of the NOx Storage-Reduction Catalyst (NSR Catalyst), the sulfur tolerance of the NSR catalyst was improved by developing new support and NOx storage materials. The support material was developed by nano-particle mixing of ZrO2-TiO2 and Al2O3 in order to increase the Al2O3-TiO2 interface and to prevent the ZrO2-TiO2 phase from sintering. A Ba-Ti oxide composite material was also developed as a new NOx storage material containing highly dispersed Ba. It was confirmed that the sulfur tolerance and activity of the developed NSR catalyst are superior to that of the conventional one.

One of typical outcome of the desire for increasing passenger comfort is that especially for deodorant efficiency. Since customers are becoming so sensitive about cabin odor, development of more effective deodorant filter is strongly required. Out side of vehicle, which most being disliked is diesel odor, therefore, analysis on this diesel gas and investigation to identity the ingredient for the main cause of the strong odor were executed, and found that acetaldehyde gas is the one. Therefore, identification of the chemical that adsorb acetaldehyde gas with being impregnated in activated carbon was required, since activated carbon itself does not have ability of adsorbing acetaldehyde gas, and finally found appropriate chemical, vitamin Bx. At the end of this report, sensory evaluation result by twenty panelists with deodorant type cabin air filter impregnated with vitamin Bx, and its efficiency for deodorant will be shown at the end of this report.

The catalyst of the crystalline ceramics known as a perovskite-type oxide was designed and controlled at the atomic level in order to create a new function for self-regeneration of precious metals in a usage ambience without auxiliary treatment. We have already reported that a catalyst with Pd supported on the perovskite-type oxide has higher activity than a catalyst with Pd supported on alumina. It was also found that Pd supported on the perovskite catalyst is finely dispersed [1, 2 and 3] The object of this study was to investigate the mechanism of self-regeneration by using hyper-analytical facilities. XAFS analysis, at SPring-8 (8 GeV), revealed that Pd is in six-fold coordinations with oxygen in a perovskite crystal, which indicating that Pd occupies the B site of the unit formula of ABO3 in the perovskite crystal structure under oxidation atmosphere.

Recently, the demand of shortening the period of development of Mold and Die and the demand of reducing costs are increasing more and more with the shortening of the life cycle of products. In such a situation, Production workplaces for Molds and Dies need development of the environment that more efficiently produces a product with higher added value. Therefore, development of a high performance machine tool and automation of manufacturing by using computer support are more important. However, the determination of the machining process still depends on the experience of the workers and the past actual results. In this work, support of the computer is not fully developed. In this research, we develop process-planning systems for the machining of Molds and Dies (Mill-Plan) as one of the technologies, which solves such a problem. This report reports the result applied to the composition of this system, and some examples.

A new material recycling technology for crosslinked rubber was developed using the continuous reactive processing method. In this process of producing reclaimed rubber, breakage of crosslinking points in the crosslinked rubber occurs selectively under the controls of shear stress, reaction temperature, and internal pressure in a modular screw type reactor. Deodorization during the process has also become possible by a newly developed method. The reclaimed rubber obtained from rubber waste generated from both automobile manufacturing products and post-consumer products shows excellent mechanical properties applicable to new rubber compounds. Furthermore, an enhanced rubber recycling process for producing thermoplastic elastomer (TPE) based on rubber waste has been established. The obtained TPE exhibits highly recoverable rubber elasticity and mechanical properties comparable to commercial TPE.

We studied the adoption of plastics derived from plants (bioplastics) such as poly(lactic acid) (PLA) for automotive parts in order to contribute to suppressing the increase in CO, emissions. For this application. major improvements of heat and impact resistance are needed. As a method to improve heat resistance, we developed PLA combined with clay of high heat resistance. As a result. we succeeded in synthesizing a PLA-clay nanocomposite using 18(OH)2-Mont. In-mold crystallization of PLA-clay nanocomposite lead to the great suppression of storage modulus decrease at high temperature. which in turn improved the heat resistance of PLA.

The effect of GTL diesel fuel on organic materials used in fuel delivery systems of vehicles was investigated. Specimens made from 16 kinds of organic materials were immersed in GTL diesel fuels synthesized at Refinery-A and Refinery-B (referred to as GTL-A and GTL-B, respectively) and then subjected to tensile testing. The tensile test results revealed that elongation of the nylon sample immersed in GTL-A was extremely small, about 4% of that of untreated nylon. In the light of this finding, the GTL diesel fuels and nylons before and after immersion test were analyzed in detail using about 20 analysis methods to determine the cause for poor elongation. The following points were found. (1) GTL-A consisted of low molecular-weight paraffins. (2) GTL-A had low molecular-weight i-paraffins. (3) The nylon immersed in GTL-A contained low molecular-weight paraffins. (4) The paraffins in the nylon immersed in GTL-A were richer in i-paraffins than the original GTL-A.

In order to improve corrosion resistance and thermal efficiency of the air conditioner evaporator, a coating which provides hydrophilicity was formed over the chromate coating. In addition, there has been greater demand for air with fewer smells. This report describes the cause of “dusty odor” and a method to reduce it. The dusty odor is caused by a little corrosion of the substrate aluminum. Hydrophilic coating film dissolves little by little in condensed water, and substrate aluminum is exposed. A method to prevent the odor was developed by forming a coating giving hydrophilicity and durability to the evaporator surface.

We have developed a high capacity electromagnetic clutch by means of Si-containing diamond-like carbon (DLC-Si) coating. The durability of the new clutch is enhanced up to 8 times higher than that of the conventional one. Such a superior performance is due to several tribological properties of the DLC-Si film and micro morphology on the clutch surface. In particular, the DLC-Si plays a significant role in maintaining the groove shape of the clutch and giving sufficient friction in fluid, which is required for a drivetrain device. Besides, our deposition process (using direct current plasma-assisted chemical vapor deposition) has afforded homogeneous DLC-Si-coated clutches in large quantities. These techniques have enabled us to reduce the number of clutch discs per coupling and achieve a more compact and higher capacity AWD coupling at a lower cost.

In conventional gasoline engine vehicles, three-way catalysts are used to simultaneously remove HC, CO and NOx from the exhaust gas. The effectiveness of the catalyst to remove these harmful species depends strongly on the oxygen concentration in the exhaust gas. Deterioration of three-way catalyst results in a reduction in its purification activity and OSC (oxygen storage capacity). In this investigation, additive elements were used to enhance the durability and OSC of the catalyst support material. An optimized formulation of a CeO2-ZrO2 and a ZrO2 material was developed to have excellent durability, improved OSC, enhanced interaction between precious metals and support materials, and increase thermal stability. Using these newly developed support materials, catalysts with increased performance was designed.

The influence of engine oil viscosity on the wear of piston rings and cam faces has been investigated by fired engine tests using a radioisotope (RI) tracer technique. High-temperature and high-shear-rate (HTHS; 150°C, 1O6 s-1) viscosities of the experimental oils prepared are 2.2, 2.4, 2.6 and 3.1 mPa•s. At an oil temperature of 90°C the wear of piston rings and cam faces did not increase, even if the HTHS viscosity was lowered down to 2.2 mPa•s. However, both piston rings and cam faces exhibited an increase in wear below 2.4 mPa•s at 130°C. It was also recognized that valve train wear did not significantly increase with reducing viscosity in the motored engine tests at a temperature of 50°C. From these test results, it was suggested that the oil with the HTHS viscosity of 2.6 mPa•s sufficiently demonstrates the antiwear performance equivalent to that with around 3.0 mPa•s for application to piston rings and cam faces.

According to the principle of pH measurement, an on-board type engine oil deterioration sensor has been developed. The developed sensor is composed of a Pb and oxidized stainless steel electrodes. The sensor signal shows a good linear relationship to the quasi-pH value of the oil. Especially in the region where the oil deterioration proceeds, the remaining basic additives in the oil is easily estimated from the sensor signal.

The purposes of this paper are to develop a new laboratory oxidation stability testing method and to clarify factors relative to the viscosity increase of engine oil. Polymerized products, obtained from the oil after a JASO M333-93 engine test, were found to consist mainly of carboxyl, nitrate and nitro compounds and to increase the oil viscosity. A good similarity between the JASO M333-93 test and the laboratory simulation test was found for the polymerized products. The products were obtained not by heating oil only in air but by heating oil while supplying a synthetic blowby gas consisting of fuel pyrolysis products, NO, SO2 and air. The laboratory test has also revealed that the viscosity increase depends on oil quality, organic Fe content and hydrocarbon composition in the fuel. Moreover, it has been found that blowby gas and organic Fe accelerate ZnDTP consumption and that aromatics concentration in the fuel correlates with the viscosity increase of oil.