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Turbulent Jet Ignition is an advanced spark-initiated pre-chamber combustion system for otherwise standard spark ignition engines. Combustion in the main chamber is initiated by jets of partially combusted (reacting) pre-chamber products which provide a high energy ignition source. The resultant widely distributed ignition sites allow relatively small flame travel distances enabling short combustion durations and high burn rates. Demonstrated benefits include ultra lean operation (λ≻2) at part load and high load knock improvement. This study compared the knock limit of conventional spark ignition and pre-chamber jet ignition combustion with reducing fuel quality in a modern PFI engine platform. Seven PRF blends ranging from 93-60 octane were experimentally tested in a stoichiometric normally aspirated single-cylinder research engine at 1500 rev/min and ~WOT (98 kPa MAP).