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Particulate Matter (PM) legislation for gasoline engines and the introduction of gasoline/ethanol blends, make it important to know the effect of fuel composition on PM emissions. Tests have been conducted with fuels of known composition in both a single-cylinder engine and V8 engine with a three-way catalyst. The V8 engine used an unleaded gasoline (PURA) with known composition and distillation characteristics as a base fuel and with 10% by volume ethanol. The single-cylinder engine used a 65% iso-octane - 35% toluene mixture as its base fuel. The engines had essentially the same combustion system, with a centrally mounted 6-hole spray-guided direct injection system. Particle size distributions were recorded and these have also been converted to mass distributions. Filter samples were taken for thermo-gravimetric analysis (TGA) to give composition information. Both engines were operated at 1500 rpm under part load.

In light of forthcoming particle number legislation for light-duty passenger vehicles, time-resolved Particle Mass (PM) and Particle Number (PN) emissions over the New European Drive Cycle (NEDC) are reported for four current vehicle technologies; modern diesel, with and without a Diesel Particulate Filter (DPF), Direct Injection Spark Ignition (DISI) gasoline and multi-point Port Fuel Injection (PFI) gasoline. The PN and PM emissions were ordered (highest to lowest) according to: Non-DPF diesel ≻ DISI ≻ PFI ~ DPF diesel. Both the non-DPF diesel and DISI vehicles emitted PN and PM continuously over the NEDC. This is in contrast with both the DPF diesel and PFI vehicles which emitted nearly all their PN and PM during the first 200 seconds. The PFI result is thought to be a consequence of cold-start mixture preparation whilst several possible explanations are offered for the DPF diesel trend.