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In this study, measurement methods of aldehydes and volatile organic compounds (VOCs) from off-road engine have been investigated. Also, their emission characteristics have been evaluated. By using high-performance liquid chromatograph (HPLC), aldehydes could be measured with small variation. Major aldehydes from off-road engine are formaldehyde and acetaldehyde. Total aldehydes emission is not necessarily low compared to THC emission. The emission characteristics of aldehydes are similar to that of CO, THC and PM. For VOCs sampling, sampling tube with absorbent was better than sampling bag because some kinds of VOCs tend to become absorbed on the sampling bag. Except for 1,3-butadiene, VOCs could be measured with small variation by using gas chromatography-mass spectrometer (GC-MS). Benzene, toluene and xylene were major species found in VOCs. The emission characteristics of VOCs were also similar to ones of CO, THC and PM.

The performance of a medium duty DME truck was evaluated by field tests and engine bench tests. The DME vehicle was given a public license plate on October 2004, after which running tests were continued on public roads and a test course. The DME vehicle could run the whole distance, about 500 km, without refueling. The average diesel equivalent fuel consumption of the fully loaded DME truck was 5.75 km/l, running at 80 km/h on public highways. Remedying several malfunctions that occurred in the power-train subsystems enhanced the vehicle performance and operation. The DME vehicle accumulated 13,000 km as of August, 2006 with no observed durability trouble of the fuel injection pump. Disassembly and inspection of the fuel injectors after 7,700 km operation revealed a few differences in the nozzle tip and the needle compared to diesel fuel operation. However, the injectors were used again after cleanup.

In this study, diesel exhaust emission characteristics were investigated as GTL (Gas To Liquid) fuel was applied to a heavy-duty diesel truck which had been developed to match a Japanese new long-term exhaust emission regulation (NOx < 2.0 g/kWh, PM < 0.027 g/kWh). The results in this study show that although the test vehicle has advanced technologies (e.g. high pressure fuel injection, oxidation catalyst, and urea-SCR aftertreatment system, etc.) which are applied to reduce diesel emissions, the neat GTL fuel has a great advantage to reduce particulate matter emissions and poly aromatic hydrocarbons. And regarding nano-size PM emissions, nuclei mode particles emitted during idling are significantly decreased by using the GTL fuel.

Biodiesel fuel has attracted much attention as a carbon neutral fuel because it is made from vegetable oil. Especially in Southeast Asia, there are numerous biofuel resources, such as palm oil and coconut oil, and it is desirable to utilize these for CO2 reduction. In this paper, we evaluate the properties of biodiesel fuel and biodiesel blended diesel oil. The low temperature performance of palm oil methyl ester (PME) is poor and it affects low temperature performance, even if the PME blending rate is low. The oxidation stability is a very important property of biodiesel fuel because degraded biodiesel fuel produces organic acids and polymeric substances. PME contains mainly saturated fatty acids methyl esters, so the oxidation stability is better than other fats and oils. When containing antioxidants such as beta carotene, biodiesel's oxidation stability is improved.

It has been clarified that diesel fuel properties have a great effect on the exhaust emissions and fuel consumption of a conventional diesel combustion regime. And as other diesel combustion regimes are applied in order to improve exhaust emissions and fuel consumption, it can be supposed that the fuel properties also have significant effects. The purpose of this study is to propose the optimum diesel fuel properties for a premixed compression ignition (PCI) combustion regime. In this paper, the effect of the auto-ignitability of diesel fuels on exhaust emissions and fuel consumption was evaluated using a heavy-duty single-cylinder test engine. In all experiments, fuels were injected using an electronically controlled, common-rail diesel fuel injector, and most experiments were conducted under high EGR conditions in order to reduce NOx emissions.

In this study, a piezo disk was used to generate a cloud of n-decane fuel drops, which were mixed with air, then carried into a combustion chamber and ignited by a platinum wire. Microgravity data obtained at the Japan Microgravity Center (JAMIC) were compared to normal gravity data, all at 1Atm pressure and 20+/-1°C initial temperature. Under normal gravity the lean limit was found to be 7.6x106/mm3 (Φ = 1.0), and from this point the flame front speed steadily increased from 20cm/s up to a maximum flame front speed of 210cm/s at a fuel drop density of about 14x106/mm3 (Φ = 1.85). Microgravity data showed a much richer lean limit - about 14.5x106/mm3 (Φ = 1.9), and the flame front speed did not gradually rise to a peak value. Instead, the measurements indicated a peak value of about 250cm/s, with a steep increase followed by a gradual decrease at richer fuel air ratios. A cellular flame structure appeared, and the cell size decreased as the mixture density increased.

Flame propagation at elevated pressures for propane, butane and autogas (20% propane and 80% butane by mass) were investigated. Flame arrival time was measured using ionization probes installed along the wall of a cylindrical combustion chamber. Flame radius was also measured using a laser schlieren technique. Results showed that the flame front speed decreased with increasing initial pressure, and the initial pressure effect on maximum flame front speed was correlated by the relationship Sf = 175·pi-0.15 (for Φ=1.0). Characteristics of flame front speed between propane, butane and autogas were very similar, whereas at fuel-rich conditions flame front speed of butane and autogas were higher than that of propane. A thermodynamic model to predict flame radius and speed as a function of time was derived and tested using measured pressure-time curves.

The combustion mechanism of a fuel droplet cloud was studied by numerical simulation. We investigated how the flame front speed and combustion products changed depending on the equivalence ratio and initial temperature. Modeling was performed using the KIVA-III software package, a three dimensional analysis software used mainly for internal combustion engine applications. The computational domain was a horizontal 1x1x100 cell sector of a spherical combustion chamber and the fuel was n-decane. Results showed that when all the fuel droplets were assumed to have evaporated, the flame front speed increased from 28 cm/s to 152 cm/s as the equivalence ratio increased. The maximum flame front speed was reached at ϕ=1.1, beyond which it decreased (at richer overall equivalence ratios). With a constant equivalence ratio, the flame front speed decreased near the outside region, because the unburned gas was compressed by the expanding burned gas.

DME as a fuel for compression ignition (diesel) engines has been actively studied for about ten years due to its characteristically low pollution and reputation as a “smokeless fuel”. During this time, the practical application is taking shape based on necessary tasks such as analysis of injection and combustion, engine performance, and development of experimental vehicles. At this moment, standardization of DME as a fuel was started under ISO in 2007. There are concerns regarding the impurities in DME regarding the mixing during production and distribution as well as their effect on additives for lubricity and odor. In this report, the effect of DME fuel impurities on performance of a DME powered diesel engine was investigated. The platform was a DME engine with common-rail fuel injection and was evaluated under partial load stable mode and Japanese transient mode (JE05) testing parameters.

The tasks to improve diesel emissions and fuel consumption must be accomplished with urgency. However, due to the trade-off relationship between NOx emissions, soot emissions and fuel consumption, clean diesel combustion should be achieved by both innovative combustion and fuel technologies. The objective of this study is to extend the clean diesel combustion operating range (Engine-out emission: NOx ≺ 0.2 g/kWh, Soot ≺ 0.02 g/kWh). In this study, performance of a single-cylinder test engine equipped with a hydraulic valve actuation system and an ultra-high pressure fuel injection system was investigated. Also evaluated, were the effects of fuel properties such as auto-ignitability, volatility and aromatic hydrocarbon components, on combustion performance. The results show that applying a high EGR (Exhaust gas recirculation) rate can significantly reduce NOx emission with an increase in soot emission.

In this study, advantages of GTL fueled DI diesel engine were observed, then, some cautionary areas, notably the aptitude for sealing materials, were investigated. Some advantages of using GTL as a diesel engine fuel include reduction of soot emission levels, power output and fuel consumption with GTL to conventional diesel fuel operation is equivalent, super-low sulfur content of GTL and its liquid state at normal temperature and pressure. However, there are some problems with putting GTL fuel on the market, such as lubricity, aptitude for sealing materials, high cetane index and high pour point. It is necessary to use additives to improve GTL's lubricity, and selecting the most appropriate type of lubricity improver is also important. The influence of GTL on the swelling properties of standard rubber materials seem basically the same, but it is necessary to notice on used rubbers.

For better understanding of the combustion characteristics in a direct injection dimethyl ether (DME) engine, the chemiluminescences of a burner flame and in-cylinder flame were analyzed using the spectroscopic method. The emission intensities of chemiluminescences were measured by a photomultiplier after passing through a monochrome-spectrometer. For the burner flame, line spectra were found nearby the wave length of 310 nm, 430 nm and 515 nm, arising from OH, CH and C2 radicals, respectively. For the in-cylinder flame, a strong continuous spectrum was found from 340 nm wave length to 550 nm. Line spectra were also detected nearby 310 nm, 395 nm and 430 nm, arising from OH, HCHO, and C2 radicals, respectively, partially overlapping with the continuous spectrum. Of these line spectra, 310 nm of OH radical did not overlapped with the continuous spectrum.

In this research, a test apparatus (VPT-HFRR) for evaluating lubricity was manufactured at an arbitrary pressure according to the lubricity test method (HFRR) for diesel fuel. The lubricity of LPG blended fuel (LBF) for diesel engines was examined using VPT-HFRR., This was a value close to that of diesel fuel, and when a suitable lubricity had been maintained, it was checked. Prototype trucks were manufactured and their durability was examined. After a run of 70,000km or more, no serious trouble had occurred, and when LBF was maintained at a suitable lubricity, it was checked.

Since dimethyl ether (DME) is a synthetic fuel, it is possible to make it from natural gas, coal and biomass. It is a low-emission, oxygenated fuel, which does not generate soot in the exhaust. Therefore, it has recently been identified as a possible replacement for diesel fuel. In Japan, the new short-term emissions regulations will be enforced beginning in 2003, and the long-term emissions regulations are scheduled to be enforced in 2005. In order to meet these more stringent emissions regulations, existing diesel engines would not be as widely used in the near future as they currently are. This will thus bring about a more widespread use of DME engines due to their low emissions potential. Moreover, when the modification of existing diesel engines into DME engines is available at a moderate cost, the wider use of DME engines can be expected. This study targeted development and application of DME engine technology for diesel engine retrofit, in a used diesel vehicle.

To date, the DME combustion mechanism has been investigated by in-cylinder gas sampling, numerical calculations and observation of combustion radicals. It has been possible to quantify the emission intensities of in-cylinder combustion using a monochromator, and to observe the emitting species as images by using band-pass filters. However, the complete band images were not observed since the broadband (thermal) intensity may be stronger than band spectra intensities. Emission intensities of DME combustion radicals from a pre-mixed burner flame have been measured using a spectroscope and photomultiplier. Results were compared to other fuels, such as n-butane and methane, then, in this study, to better understand the combustion characteristics of DME, emission intensities near CH bands of an actual DI diesel engine fueled with DME were measured, and band spectra emitted from the engine were defined. Near TDC, emission intensities did not vary with wavelength.

In this study, a MPT-HFRR (Multi-Pressure/Temperature High-Frequency Reciprocating Rig) was manufactured based on a diesel fuel lubricity test apparatus. The MPT-HFRR was designed to be used for conventional test methods as well as for liquefied gas fuel tests. Lubricity tests performed on a calibration standard sample under both atmospheric pressure and high pressure produced essentially constant values, so it was determined that this apparatus could be used for assessing the lubricity of fuel. Using this apparatus, the improvement of lubricity due to the addition of a DME (Dimethyl Ether) fuel additive was investigated. It was found that when 50ppm or more of a fatty acid lubricity improver was added, the wear scar diameter converged to 400μm or less, and a value close to the measured result for Diesel fuel was obtained. The lubricity obtained was considered to be generally satisfactory.

In order to remove the diesel particulate matter (PM) and nitrogen oxides (NOx) from diesel exhaust, the gas is passed through a corona discharge collector for PM and another corona discharge device for NOx oxidation. With the PM collector, PM is accumulated on the central electrode, after that, it is removed by incineration technique. NOx concentration is decreased by oxidation to HNO3. In this study, these corona discharge reactors were coupled for removal of PM and NOx in progression, and attempted to remove these emissions in a slipstream of 14 liters/min of an experimental diesel engine and an actual vehicle, respectively. In case of the experimental test engine, it is found that nearly 100% and 15% of the PM and NOx emissions were removed even at a low input power of 26W (1560 J/L specific energy deposition). In the vehicle tests 1) a PM removal rate of 60% is obtained at an input power of over 40W, 2) a NOx removal rate of 97% is obtained at an input power of over 100W.

Alternative fuels such as butane and DME have different properties including high vapor pressure, low viscosity, and low surface tension, compared to other conventional fuels. These properties may lead to different atomization characteristics such as liquid core breakup, droplet size distribution, and evaporation process. To investigate these effects, a method based on shadowgraph technique to take spray images for droplets and surrounding gas was tested and evaluated. Experiments were performed at low injection pressure for early stage direct injection. It could be concluded from the results that the proposed method could be used to investigate the structure of evaporating spray, and the vapor layer around the spray core could be correlated to the turbulent mixing length for both of butane and DME sprays by observing vapor and spray core.

This work aimed to develop an LPG fueled direct injection SI engine, especially in order to improve the exhaust emission quality while maintaining high thermal efficiency comparable to a conventional engine. In-cylinder direct injection engines developed recently worldwide utilizes the stratified charge formation technique at low load, whereas at high load, a close-to-homogeneous charge is formed. Thus, compared to a conventional port injection engine, a significant improvement of fuel consumption and power can be achieved. To implement such a combustion strategy, the stratification of mixture charge is very important, and an understanding of its combustion process is also inevitably necessary. In this work, a numerical simulation was performed using a CFD code (KIVA-3), where the shape of a combustion chamber, swirl intensity, injection timing and duration, etc. were varied and their effects on the mixture formation and combustion process were investigated.

In this study, engine performances and exhaust emissions characteristics of compression ignition engine fueled with GTL were investigated by comparison with diesel fuel. Diesel engine could be operated fueled with GTL without any special modify for the test engine. With the high cetane number of GTL, the ignition lag was shorter, and the combustion started earlier than that of diesel fuel. Brake thermal efficiency operated with GTL increased at middle load conditions due to incomplete combustion emission such as CO and THC were lower than that of diesel fuel operation. NOx emission with GTL was comparable to diesel fuel, and there was a little decrease at high load. With GTL, soot emission was lower than with diesel fuel at above middle load condition. It seemed to be a reason of soot reduction that there was little sulphur contained in GTL.