Search Results

A new technology for controlling the partial pressure of CO2 (pCO2) in a plant growth chamber (PGC) has been demonstrated. CO2 is gathered from the source atmosphere across a membrane gas exchanger and stored in an alkanolamine solution. The CO2 loading of the alkanolamine reservoir is monitored using specific conductance and controlled by the exposure time and temperature. The PGC pCO2 is maintained using a second membrane exchanger through which the alkanolamine circulates, absorbing or releasing CO2 to maintain equilibrium. The equilibrium pCO2 is determined by the CO2 loading and the temperature. Constant PGC feed pCO2 levels of roughly 1000 ppm have been maintained using sources with pCO2 both above and below this value.

Magnetically Assisted Gasification (MAG) is a relatively new concept for the destruction of solid wastes aboard spacecraft, lunar and planetary habitations. Three sequential steps are used to convert the organic constituents of waste materials into useful gases: filtration, gasification, and ash removal. In the filtration step, an aqueous suspension of comminuted waste is separated and concentrated using a magnetically consolidated depth filter composed of granular ferromagnetic media. Once the filter is fully loaded, the entrapped solids are thermochemically gasified via a variety of mechanisms including pyrolysis, isomerization, and oxidation reactions. Finally, the inorganic ash residue is removed from the magnetic media by fluidization and trapped downstream by filtration. Importantly, for each of these steps, the degree of consolidation or fluidization of the granular ferromagnetic media is controlled using magnetic forces.

Small, highly polar organics such as urea, alcohols, acetone, and glycols are not easily removed by the International Space Station's Water Recovery System. The current design utilizes the Volatile Removal Assembly (VRA) which operates at 125°C to catalytically oxidize these contaminants. Since decomposition of these organics under milder conditions would be beneficial, several ambient temperature biocatalytic and catalytic processes were evaluated in our laboratory. Enzymatic oxidation and ambient temperature heterogeneous catalytic oxidation of these contaminants were explored. Oxidation of alcohols proceeded rapidly using alcohol oxidase; however, effective enzymes to degrade other contaminants except urea were not found. Importantly, both alcohols and glycols were efficiently oxidized at ambient temperature using a highly active, bimetallic noble metal catalyst.

A cyclic two-step process is described which forms the basis for a simple and highly efficient air purification technology. Low molecular weight organic vapors are removed from contaminated airstreams by passage through an optimized sequence of sorbent media layers. The contaminant loaded sorbents are subsequently regenerated by thermal desorption into a low volume inert gas environment. A mixture of airborne organic contaminants consisting of acetone, 2-butanone, ethyl acetate, Freon-113 and methyl chloroform has been quantitatively removed from breathing quality air using this technique. The airborne concentrations of all contaminants have been reduced from initial Spacecraft Maximum Allowable Concentration (SMAC) levels to below the analytical limits of detection. No change in sorption efficiency was observed through multiple cycles of contaminant loading and sorbent regeneration via thermal desorption.

Several solid waste management (SWM) systems currently under development for spacecraft deployment result in the production of a variety of toxic gaseous contaminants. Examples include the Plastic Melt Waste Compactor (PMWC) at NASA - Ames Research Center1, the Oxidation/Pyrolysis system at Advanced Fuel Research2, and the Microwave Powered Solid Waste Stabilization and Water Recovery (MWSWS&WR) System at UMPQUA Research Company (URC). The current International Space Station (ISS) airborne contaminant removal system, the Trace Contaminant Control Subassembly (TCCS), is designed to efficiently process nominal airborne contaminants in spacecraft cabin air. However, the TCCS has no capability to periodically process the highly concentrated toxic vapors of variable composition, which are generated during solid waste processing, without significant modifications.

The Microbial Check Valve (MCV) is a reloadable flow-through canister containing iodinated ion exchange resin, which is used aboard the Shuttle Orbiter as a disinfectant to maintain water potability. The MCV exhibits a significant contact kill and imparts a biocidal residual I2 concentration to the effluent. MCVs in current use have nominal 30 day lives. MCVs baselined for Space Station Freedom will have 90 day lives, and will require replacement 120 times over 30 years. Means to extend MCV life are desirable to minimize resupply penalties. New technology has been developed for fully autonomous in situ regeneration of an expended MCV canister. The Regenerative Microbial Check Valve (RMCV) consists of an MCV, a packed bed of crystalline I2, a flow diverter valve, an in-line iodine monitor and a microcontroller. During regeneration, flow is directed first through the packed I2 bed and then into the MCV where the resin is replenished.

The Microbial Check Valve (MCV) is a canister containing an iodinated ion exchange resin and is used on the Shuttle Orbiter to provide microbial control of potable water. The MCV provides a significant contact kill, and imparts a biocidal iodine residual to the water. The Orbiter MCV has a design life of 30 days. For longer duration applications, such as Space Station Freedom, an extended life is desirable to avoid resupply penalties. A method of in situ MCV regeneration with elemental iodine is being developed. During regeneration water en route to the MCV first passes through a crystalline iodine bed where a concentration between 200 - 300 mg/L I2 is attained. When introduced into the MCV, this high concentration causes an equilibrium shift towards iodine loading, effecting regeneration of the resin. After regeneration normal flow is re-established. Life cycle regeneration testing is currently in progress.

The investigation and development of a chemiluminescence based ethanol detection concept into a biosensor system is described. The biosensor uses alcohol oxidase to catalyze the reaction of short chain primary alcohols with elemental oxygen to produce hydrogen peroxide and the corresponding aldehyde. The reaction of hydrogen peroxide with an organic luminophore in the presence of a sufficient electric field results in emission of blue light with peak intensity at 425nm. The chemiluminescent light intensity is directly proportional to the alcohol concentration of the sample. The aqueous phase chemistry required for sensor operation is implemented using solid phase modules which adjust the pH of the influent stream, catalyze the oxidation of alcohol, provide the controlled addition of the luminophore to the flowing aqueous stream, and minimize the requirement for expendables. Precise control of the pH has proven essential for the long-term sustained release of the luminophore.

Gradient magnetically assisted fluidized bed (G-MAFB) methods are under development for the decomposition of solid waste materials in microgravity and hypogravity environments. The G-MAFB has been demonstrated in both laboratory and microgravity flight experiments. In this paper we summarize the results of gasification reactions conducted under a variety of conditions, including: combustion, pyrolysis (thermal decomposition), and steam reforming with and without oxygen addition. Wheat straw, representing a typical inedible plant biomass fraction, was chosen for this study because it is significantly more difficult to gasify than many other typical forms of solid waste such as food scraps, feces, and paper. In these experiments, major gasification products were quantified, including: ash, char, tar, carbon monoxide, carbon dioxide, methane, oxygen, and hydrogen.

Solid wastes can be separated from aqueous streams and concentrated by filtration in a magnetically assisted fluidized bed. In this work the filtration of solid waste materials using filter beds consisting of granular ferromagnetic media is demonstrated. The degree of bed consolidation (or conversely fluidization) is controlled by the application of magnetic forces. In the Magnetically Assisted Gasification (MAG) process, solids are first entrapped by filtration, and then fluidized and transferred to a high temperature reactor where they are thermally decomposed. The maximum particle loading for the filter bed is determined by the intergranular void space. Using magnetic methods, it is possible to manipulate the degree of compaction as the filtration progresses to increase the void space and thereby maximize the loading capacity and efficiency of the filter. This process is completely compatible with operation in microgravity and hypogravity.

The electrosynthesis of expendable reagents including acids, bases, and oxidants from simple salts or salt mixtures has been demonstrated using a variety of electrochemical cells. A five chambered electrodialytic water splitting (EDWS) cell with bipolar membranes was utilized to efficiently convert sodium sulfate, sodium chloride, potassium nitrate, and potassium chloride to conjugate acids and bases. With the same cell, selective segregation of cations and anions from mixed salt solutions occurred, resulting in relatively pure acids and bases. These results suggest that pure acids and bases can be produced from composite spacecraft brines. Chemical oxidants such as sodium and ammonium persulfate were also synthesized with high current efficiencies by the electrooxidation of salts and acids in a two chambered electrochemical cell.

A variety of techniques, including supercritical water oxidation, fluidized bed combustion, and microwave incineration have been applied to the destruction of solid wastes produced in regenerative life support systems supporting long duration manned missions. Among potential problems which still deserve attention are the need for operation in a variety of gravitational environments, and the requirement for improved methods of presenting concentrated solids to the reactor. Significant improvements in these areas are made possible through employment of the magnetically assisted gasification process. In this paper, magnetic methods are described for manipulating the degree of consolidation or fluidization of granular ferromagnetic media, for application in a gravity independent three step solid waste destruction process.