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Unregulated emissions have become an important factor restricting the development of methanol and ethanol alternative alcohols fuels. Using two light-duty vehicles fuelled with pure gasoline, gasoline blend of 10% and 20% volume fraction of ethanol fuels, gasoline blend of 15% and 30% volume fraction of methanol fuels, New European Driving Cycle (NEDC) emission tests were carried on a chassis dynamometer according to ECE R83-05. High performance liquid chromatography (HPLC), Gas chromatography - Mass spectrometry (GC-MS), Fourier transform infrared spectrometer (FTIR) were used to measure methanol, formaldehyde, acetaldehyde, acetone, benzene, toluene, xylene, ethylene, propylene, 1,3-butadiene and isobutene emissions in the exhaust during the NEDC.

Wide Distillation Fuel (WDF) refers to the fuels with a distillation range from Initial Boiling Point (IBP) of gasoline to Final Boiling Point (FBP) of diesel. Polyoxymethylene Dimethyl Ethers (PODEn) have high oxygen content and cetane number, are promising green additive to diesel fuel. In this paper, WDF was prepared by blending diesel and gasoline at ratio of 1:1, by volume; the mass distribution of oligomers in the PODE3-4 product was 88.9% of PODE3 and 8.46% of PODE4. Diesel fuel (Diesel), WDF (G50D50) and WDF (80%)-PODE3-4 (20%) (G40D40P20) were tested in a light-duty single-cylinder diesel engine, combustion characteristic, fuel consumption and exhaust emissions were measured. The results showed that: at idling condition, G40D40P20 has better combustion stability, higher heat release rate, higher thermal efficiency compared with G50D50.

Dieseline combustion as a concept combines the advantages of gasoline and diesel by offline or online blending the two fuels. Dieseline has become an attractive new compression ignition combustion concept in recent years and furthermore an approach to a full-boiling-range fuel. High speed imaging with near-parallel backlit light was used to investigate the spray characteristics of dieseline and pure fuels with a common rail diesel injection system in a constant volume vessel. The results were acquired at different blend ratios, and at different temperatures and back pressures at an injection pressure of 100MPa. The penetrations and the evaporation states were compared with those of gasoline and diesel. The spray profile was analyzed in both area and shape with statistical methods. The effect of gasoline percentage on the evaporation in the fuel spray was evaluated.

Super-knock has been a significant obstacle for the development of highly turbocharged (downsized) gasoline engines with spark ignition, due to the catastrophic damage super-knock can cause to the engine. According to previous research by the authors, one combustion process leading to super-knock may be described as hot-spot induced pre-ignition followed by deflagration which can induce detonation from another hot spot followed by high pressure oscillation. The sources of the hot spots which lead to pre-ignition (including oil films, deposits, gas-dynamics, etc.) may occur sporadically, which leads to super-knock occurring randomly at practical engine operating conditions. In this study, a spark plasma was used to induce preignition and the correlation between super-knock combustion and the thermodynamic state of the reactant mixture was investigated in a four-cylinder production gasoline engine.

In this paper, a hybrid combustion mode in four-stroke gasoline direct injection engines was studied. Switching cam profiles and injection strategies simultaneously was adopted to obtain a rapid and smooth switch between SI mode and HCCI mode. Based on the continuous pressure traces and corresponding emissions, HCCI steady operation, HCCI transient process (combustion phase adjustment, SI-HCCI, HCCI-SI, HCCI cold start) were studied. In HCCI mode, HCCI combustion phase can be adjusted rapidly by changing the split injection ratio. The HCCI control strategies had been demonstrated in a Chery GDI2.0 engine. The HCCI engine simulation results show that, oxygen and active radicals are stored due to negative valve overlap and split fuel injection under learn burn condition. This reduces the HCCI sensitivity on inlet boundary conditions, such as intake charge and intake temperature. The engine can be run from 1500rpm to 4000rpm in HCCI mode without spark ignition.

This study improved the computational efficiency significantly using parallel computation and reduced mechanisms. A 3-dimensional engine moving mesh of intake port, exhaust port and combustion chamber was established for HCCI engine cycle simulation. To achieve a more accurate analysis, chemical kinetics was implemented into the CFD code to study the intake, spray, ignition, combustion, and pollution formation process in HCCI engine. The simulations were run on a cluster of 16-CPU, parallelized by Message-Passing Interface (MPI) mode. The cases with detailed and reduced reaction mechanisms were calculated using 1, 2, 4, 8, 16 CPUs respectively and the corresponding computational time and speed-up were discussed. Using MPI 8-CPU with reduced mechanism (less than 40 species) is the optimal scheme for CFD/Chemistry calculation of typical HCCI engine.

A method to design a feasible multi-component fuel for fuel concentration measurements by using PLIF was developed based on thermal gravity (TG) analysis and vapor-liquid equilibrium (VLE) calculations. Acetone, toluene, and 1,2,4-trimethylbenzene were respectively chosen as tracers for the light, medium, and heavy components of gasoline. A five-component test fuel was designed for LIF measurement, which contains n -pentane (light), isooctane, n -octane (medium), n -nonane and n -decane (heavy). The TG analysis and VLE calculation were used to ensure that the fuel had volatility similar to real gasoline and that all the tracers had a good coevaporation ratio. The fully optimized results of the six-component fuel and the disadvantages of this case are discussed. The results indicated that optimization based on the six-component fuel, which included C4 compounds such as n -butane, controlled acetone's coevaporation ratio.

Homogeneous charge combustion and emissions of ethanol ignited by pilot diesel fuel were investigated on a two-cylinder diesel engine. The results show that emissions depend on loads and ethanol volume fraction. At low loads, ethanol has little effects on smoke. With the increase of ethanol, NOx decreases, but CO emissions increase. At high loads, smoke emissions reduce greatly with increasing ethanol, but NOx and total hydrocarbon (THC) emissions increase. With the increase of ethanol, ignition delays, combustion duration shortens. The maximum rates of heat release for the fuel containing 10 vol% ethanol (E10) and 30 vol% ethanol (E30) increase. Brake specific energy consumption (BSEC) of E10 and E30 is improved slightly only at full loads. Compared to smoke emissions obtained on the same engine using ethanol blended diesel fuels, the tendency of smoke reduction is similar to that of homogeneous charge combustion of ethanol at the same operating conditions.

In this paper, the detailed chemical kinetics was implemented into the three-dimensional CFD code to study the combustion process in HCCI engines. An extended hydrocarbon oxidation reaction mechanism (89 species, 413 reactions) used for high octane fuel was constructed and then used to simulate the chemical process of the ignition, combustion and pollutant formation in HCCI conditions. The three-dimensional CFD / chemistry model (FIRE/CHEMKIN) was validated using the experimental data from a Rapid Compression Machine. The simulation results show good agreements with experiments. Finally, the improved multi-dimensional CFD code has been employed to simulate the intake, spray, combustion and pollution formation process of the gasoline direct injection HCCI engine with multi-stage injection strategy. The models account for intake flow structure, spray atomization, spray/wall interaction, droplet evaporation and gas phase chemistry in complex multi-dimensional geometries.

Experiment is carried out on an engine dynamometer bench for simulating the cold-start of port-injected gasoline engines. Based on the measured temperatures and HC emissions at the inlet and outlet of the catalytic converter as well as cylinder pressure, how to achieve minimum catalytic-converter-out HC emissions prior to catalyst light-off has been discussed. In this experiment, the cold-start period is divided into three stages referred to the opening of the throttle valve. Most of the HC are emitted in the first stage, i.e. from cranking to the opening of the throttle valve. Retarding of spark timing could cause incomplete combustion in the cylinder and lead to the oxidization of the unburned HC in the exhaust manifold, which results in reductions of tail-pipe HC emissions. Incomplete combustion could also occur when throttle valve is open by setting proper spark timing.

The effect of ethanol blended diesel fuels on brake specific fuel consumption (BSFC), brake specific energy consumption (BSEC), smoke and NOx emissions has been investigated in a direct-injection diesel engine. Unregulated emissions including formaldehyde, acetaldehyde and unburned ethanol emissions are also analyzed. The results indicate that with the increase of ethanol in the blends, smoke reduces significantly, BSEC improves slightly and combustion duration decreases. However, the rate of heat release increases. Ignition delays. BSFC, NOx, acetaldehyde and unburned ethanol emissions increase. The maximum acetaldehyde emissions reached up to 100 ppm at low load. Compared to a gasoline engine using ethanol blended gasoline fuels, unburned ethanol emissions of the diesel engine are higher than those of the gasoline engine at the same ethanol concentrations and similar loads.

Homogeneous Charge Compression Ignition (HCCI) combustion concept has advantages of high thermal efficiency and low emissions. However, how to control HCCI ignition timing is still a challenge in the application. This paper tries to control HCCI ignition timing using gasoline direct injection (DI) into cylinder to form a desired mixture of fuel and air. A homogeneous charge can be realized by advancing injection timing in intake stroke and a stratified charge can be obtained by retarding injection timing in compression stroke. Multi-stage injection strategy is used to control the mixture concentration distribution in the cylinder for HCCI combustion. A three-dimensional Computational Fluid Dynamics (CFD) code FIRE™ is employed to simulate the effects of single injection timing and multi-stage injection on mixture formation and combustion. Effects of mixture concentration and inlet temperature on HCCI ignition timing are also investigated in this paper.

The spray characteristics is the key to achieve the clean combustion in diesel engines and the in-cylinder conditions are one of the factors affecting the spray process. In this work, the diesel spray characteristics were studied over a range of injection pressures and ambient pressures in a constant volume chamber and a single-hole common rail diesel injector was used. The present work is to decouple the effects of ambient pressure and ambient density on near-field spray processes by using different ambient gas (N2, and CO2). The spray processes were captured by a Photron SA X2 camera with speed of 300,000 fps and resolution of 256 by 80 pixels. The spray processes were analyzed in terms of penetration length and spray tip velocity. Difference in penetration length and tip velocity were found at the same ambient density and/or ambient pressure when different ambient gases were used.

Wide Distillation Fuel (WDF) refers to the fuels with a distillation range from initial boiling point of gasoline to final boiling point of diesel. Recent experimental results have shown WDF by blending 50% gasoline and 50% diesel (G50) exhibits much lower soot emissions than diesel at medium load with similar thermal efficiency. However, the engine performances fueled by G50 at both low load end and high load end are still unknown. In this study, the combustion and emission characteristics of G50 and diesel are compared over a wide load range from 0.2 MPa IMEP to 1.4 MPa IMEP at a light-duty diesel engine. The results shown that at 0.2 MPa IMEP, G50 exhibits low combustion stability and thermal efficiency. With the increase of load, the poor combustion quality of G50 is improved. G50 can achieve soot-free combustion up to 1.0 MPa IMEP, while diesel cannot.

Polyoxymethylene dimethyl ethers (PODEn) are promising alternative fuel candidates for diesel engines because they present advantages in soot reduction. This study uses a PODEn mixture (contains PODE3-6) from mass production to provide oxygen component in blend fuels. The spray combustion of PODEn-diesel bend fuels in a constant volume vessel was studied using high speed imaging, PLII-LEM and OH* chemiluminescence. Fuels of several blend ratios are compared with pure diesel. Flame luminance data show a near linear decrease tendency with the blend ratio increasing. The OH* images reveal that the ignition positions of all the cases have small differences, which indicates that using a low PODEn blend ratio of no more than 30% does not need significant adjustment in engine combustion control strategies. It is found that 30% PODEn blended with diesel (P30) can effectively reduce the total soot by approximately 68% in comparison with pure diesel.

Wide Distillation Fuel (WDF), with a distillation range from Initial Boiling Point of gasoline to Final Boiling Point of diesel, can be easily gained directly by blending diesel with gasoline. However, the reduced auto-ignitability of WDF could lead to higher HC emissions. Polyoxymethylene Dimethyl Ethers (PODE), with good volatility and oxygen content of up to 49%, have great potential to improve combustion and emission characteristics, especially for soot reduction. Experiments were carried out in a light-duty four-cylinder diesel engine fueled with neat diesel, gasoline/diesel blends (GD), GD/PODE blends (GDP) and the combustion and emission characteristics were carefully examined. Results showed that GDP had the lowest PM emission and diesel had the poorest one among the three fuels. Due to the addition of gasoline and the relatively poor ignitability, GD had lower combustion efficiency and higher Soluble Organic Fraction (SOF) emissions than diesel.

A new combustion mode namely multiple premixed compression ignition (MPCI) for gasoline engines was proposed. The MPCI mode can be realized by two or more times gasoline injections into cylinder with a high pressure around the compression TDC and featured with a premixed combustion after each injection in the cylinder, which is different from the existed gasoline direct injection compression ignition (GDICI) modes such as homogeneous charge compression ignition (HCCI) mode with gasoline injection occurred in intake stroke, and partially premixed compression ignition (PPCI) mode with multiple gasoline injections in intake and compression strokes before the start of combustion (SOC). Therefore the spray and combustion of the MPCI mode are alternatively occurred as "spray-combustion-spray-combustion" near the TDC, rather than "spray-spray-combustion" sequence as traditional PPCI gasoline engines.

The detailed chemical kinetics was implemented into the 0D single-zone model, 1D engine cycle model and 3D CFD model respectively. Both simulation and experiment were carried out on a four-stroke gasoline HCCI engine with direct injection. The 0D model (HRG) was developed to study the isolating effect of HCCI parameters. The 1D engine cycle model with HRG was established to study the gas exchange process and the direct injection strategy in the gasoline HCCI engine with two-stage direct injection (TSDI) and negative valve overlap (NVO). The 3D model with HRG was constructed to study the ignition control mechanism in “two-zone HCCI” combustion via analysis the auto-ignition spots distribution in combustion chamber. “Two-zone HCCI” is defined in this paper as premixed ultra-lean compression ignition combining with premixed ultra-rich compression ignition. The three models were validated by experiments.

HCCI combustion was studied in a 4-stroke gasoline engine with a direct injection system. The electronically controlled two-stage gasoline injection and spark ignition system were adopted to control the mixture formation, ignition timing and combustion rate in HCCI engine. The engine could be operated in HCCI combustion mode in a range of load from 1 to 5 bar IMEP and operated in SI combustion mode up to load of 8 bar IMEP. The HCCI combustion characteristics were investigated under different A/F ratios, engine speeds, starts of injection, as well as spark ignition enabled or not. The test results reveal the HCCI combustion features as a high-pressure gradient after ignition and has advantages in high thermal efficiency and low NOx emissions over SI combustion. At the part load of 1400rpm and IMEP of 3.5bar, ISFC in HCCI mode is 25% lower and NOx emissions is 95% lower than that in SI mode.

In order to enhance the thermal efficiency of gasoline engines, a combustion mode namely Homogeneous Charge Induced Ignition (HCII) was introduced and examined in this paper. Port-injected gasoline was used as the main fuel and formed a homogeneous charge in the cylinder. Diesel was used as the pilot fuel, directly injected into the cylinder, and self-ignited and this induced the ignition of the premixed gasoline-air charge. The images of HCII combustion process were taken on an optical engine through a high-speed CMOS camera. The multi-point induced ignition phenomena were observed and the parameters like flame luminance, ignition delay and combustion duration were analyzed by image analysis. The result shows that as the gasoline/diesel ratio increases with a fixed low pilot amount, the ignition delay increases, the initial ignition area extends from the center towards the periphery of the combustion chamber, and the combustion velocity increased.