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A literature review was conducted to survey recent research on the effects of fuel properties on exhaust emissions from gasoline and diesel vehicles, on-road and off-road. Most of the literature has been published in SAE papers, although data have also been reported in other journals and government reports. A full report and database are available from the Coordinating Research Council (www.crcao.org). The review identified areas of agreement and disagreement in the literature and evaluated the adequacy of experimental design and analysis of results. Areas where additional research would be helpful in defining fuel effects are also identified. In many of the research programs carried out to evaluate the effect of new blendstocks, the fuel components were splash blended in fully formulated fuels. This approach makes it extremely difficult to determine the exact cause of the emissions benefit or debit.

The goal of this research is to investigate the physical parameters of stoichiometric operation of a diesel engine under a light load operating condition (6∼7 bar IMEP). This paper focuses on improving the fuel efficiency of stoichiometric operation, for which a fuel consumption penalty relative to standard diesel combustion was found to be 7% from a previous study. The objective is to keep NOx and soot emissions at reasonable levels such that a 3-way catalyst and DPF can be used in an aftertreatment combination to meet 2010 emissions regulation. The effects of intake conditions and the use of group-hole injector nozzles (GHN) on fuel consumption of stoichiometric diesel operation were investigated. Throttled intake conditions exhibited about a 30% fuel penalty compared to the best fuel economy case of high boost/EGR intake conditions. The higher CO emissions of throttled intake cases lead to the poor fuel economy.

The present paper describes an experimental study on the effect of the compression ratio on the performance of a LD diesel engine operating with a PCCI calibration, near the estimated EURO 6/Tier2 Bin5 NOx emission limits. The research activity is the result of a collaborative project between Istituto Motori and Centro Ricerche Fiat aimed to carry out an exhaustive analysis of the compression ratio (CR) influence on the performance of a LD diesel engine. Starting from a reference engine configuration the CR was reduced in two steps sequentially. Each CR value was characterized under PCCI operation mode and, under conventional diesel operating mode, at maximum torque. The exploration of the PCCI application in the NEDC operating area was performed prefixing limits on maximum fuel consumption, maximum pressure rise and maximum tolerable smoke. The main result was that no significant increment in PCCI application area reducing the CR was possible without overcoming the limits.

A realistic modeling of the wall heat transfer is essential for an accurate analysis and simulation of the working cycle of internal combustion engines. Empirical heat transfer formulations still dominate the application in engine process simulations because of their simplicity. However, experiments have shown that existing correlations do not provide satisfactory results for all the possible operation modes of hydrogen internal combustion engines. This paper describes the application of a flow field-based heat transfer model according to Schubert et al. [1]. The models strength is a more realistic description of the required characteristic velocity; considering the influence of the injection on the global turbulence and on the in-cylinder flow field results in a better prediction of the wall heat transfer during the compression stroke and for operations with multiple injections. Further an empirical hypothesis on the turbulence generation during combustion is presented.

Because niobium-clad 304L stainless steel sheets are considered for use as bipolar plates in polymer electrolyte membrane (PEM) fuel cells, their mechanical behavior and failure mechanism are important to be examined. As-rolled and annealed specimens were tested in tension, bending and flattening. The effects of annealing temperature and time on the mechanical behavior and failure mechanism were investigated. Micrographic analyses of bent and flattened specimens showed that the as-rolled specimens have limited ductility and that the annealed specimens can develop an intermetallic layer of thickness of a few microns. The annealed specimens failed due to the breakage of intermetallic layer causing localized necking and the subsequent failure of Nb layer. The springback angles of the as-rolled and annealed specimens were also obtained from guided-bend tests.

Optimization of the engine cold start is critical for gasoline direct injection (GDI) engines to meet increasingly stringent emission regulations, since the emissions during the first 20 seconds of the cold start constitute more than 80% of the hydrocarbon (HC) emissions for the entire EPA FTP75 drive cycle. However, Direct Injection Spark Ignition (DISI) engine cold start optimization is very challenging due to the rapidly changing engine speed, cold thermal environment and low cranking fuel pressure. One approach to reduce HC emissions for DISI engines is to adopt retarded spark so that engines generate high heat fluxes for faster catalyst light-off during the cold idle. This approach typically degrades the engine combustion stability and presents additional challenges to the engine cold start. This paper describes a CFD modeling based approach to address these challenges for the Ford 3.5L V6 EcoBoost engine cold start.

Ford Motor Company is introducing “EcoBoost” gasoline turbocharged direct injection (GTDI) engine technology in the 2010 Lincoln MKS. A logical enhancement of EcoBoost technology is the use of E85 for knock mitigation. The subject of this paper is the optimal use of E85 by using two fuel systems in the same EcoBoost engine: port fuel injection (PFI) of gasoline and direct injection (DI) of E85. Gasoline PFI is used for starting and light-medium load operation, while E85 DI is used only as required during high load operation to avoid knock. Direct injection of E85 (a commercially available blend of ∼85% ethanol and ∼15% gasoline) is extremely effective in suppressing knock, due to ethanol's high inherent octane and its high heat of vaporization, which results in substantial cooling of the charge. As a result, the compression ratio (CR) can be increased and higher boost levels can be used.

The internal combustion engine and associated powertrain are likely to remain the mainstay of mobility over the next twenty years and to remain a significant portion of the portfolio of technologies employed over a much longer period of time. Efficient combustion of all fuels (petroleum based or alternative) requires copious amounts of air particularly with downsized engines. Turbocharging technology thus becomes an even more critical part of reducing both global warming gas and urban pollutant emissions from IC engines. Gasoline engine downsizing and turbocharging have been shown to improve fuel economy by ∼20% in production vehicles. In addition to data over a wide range of engines/vehicles, the results of a simple analysis done on vehicles/engines/drive cycles are presented to show the benefits of turbocharging and downsizing in a parametric variation of downsizing in combination with other technologies.

Diesel engines have been used in large vehicles, locomotives and ships as more efficient alternatives to the gasoline engines. They have also been used in small passenger vehicle applications, but have not been as popular as in other applications until recently. The two main factors that kept them from becoming the major contender in the small passenger vehicle applications were the low power outputs and the noise levels. A combination of improved mechanical technologies such as multiple injection, higher injection pressure, and advanced electronic control has mostly mitigated the problems associated with the noise level and changed the public notion of the Diesel engine technology in the latest generation of common-rail designs. The power output of the Diesel engines has also been improved substantially through the use of variable geometry turbines combined with the advanced fuel injection technology.

The Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model incorporated fuel economy and electricity use of alternative fuel/vehicle systems simulated by the Powertrain System Analysis Toolkit (PSAT) to conduct a well-to-wheels (WTW) analysis of energy use and greenhouse gas (GHG) emissions of plug-in hybrid electric vehicles (PHEVs). Based on PSAT simulations of the blended charge depleting (CD) operation, grid electricity accounted for a share of the vehicle’s total energy use ranging from 6% for PHEV 10 to 24% for PHEV 40 based on CD vehicle mile traveled (VMT) shares of 23% and 63%, respectively. Besides fuel economy of PHEVs and type of on-board fuel, the type of electricity generation mix impacted the WTW results of PHEVs, especially GHG emissions.

Toyota Motor Corporation has developed the new compact-class hybrid vehicle (HV). This vehicle incorporates Toyota Hybrid System II (THS-II) to improve fuel efficiency. For this system we have developed a new power control unit (PCU) that features size reduction, light weight, and high efficiency. We have also improved the ability to mass produce these units with the expectation of rapid popularization of HV. The PCU, which plays an important role in THS-II, is our main focus in this paper. Its development is described.

Engine operating strategies typically geared towards higher fuel economy and lower NOx widely affect exhaust composition and temperature. These exhaust variables critically drive the performance of After Treatment (AT) components, and hence should guide their screening and selection. Towards this end, the effect of H2 level in diesel exhaust on the performance of a Diesel Oxidation Catalyst (DOC) was studied using flow reactor experiments, vehicle emission measurements and mathematical models. Vehicle chassis dynamometer data showed that exhaust from light-duty and heavy-duty diesel trucks contained very little to almost no H2 (FTP average CO/H2 ∼ 40 to 70) as compared to that of a gasoline car exhaust (FTP average CO/H2 ∼ 3). Two identical flow reactor experiments, one with H2 (at CO/H2 ∼ 3) and another with no H2 in the feed were designed to screen DOCs under simulated feed gas conditions that mimicked these two extremes in the exhaust H2 levels.

Automotive engines are regularly utilized in the material handling market where LPG is often the primary fuel used. When compared to gasoline, the use of gaseous fuels (LPG and CNG) as well as alcohol based fuels, often result in significant increases in valve seat insert (VSI) and valve face wear. This phenomenon is widely recognized and the engine manufacturer is tasked to identify and incorporate appropriate valvetrain material and design features that can meet the ever increasing life expectations of the end-user. Alternate materials are often developed based on laboratory testing – testing that may not represent real world usage. The ultimate goal of the product engineer is to utilize accelerated lab test procedures that can be correlated to field life and field failure mechanisms, and then select appropriate materials/design features that meet the targeted life requirements.

Spray-guided gasoline direct injection SI engines attract as one of new generation lean-burn engines to promise CO2 reduction. These typically adopt “narrow-spacing” concept in which an injector is centrally mounted close to a spark plug. Therefore, geometric targets of the fuel spray and a position of the spark plug have to be exactly limited to maintain a proper mixture in the spark gap. In addition, the stable combustion window is narrow because the spark ignition is limited in a short time during and immediately after the injection. These spatial and temporal restrictions involve some intractable problems concerning the combustion robustness due to the complicate phenomena around the spark plug. The local mixture preparation near the spark plug significantly depends on the spray-induced charge motion. The intense flow induced by the motion blows out and stretches the spark, thereby affecting the spark discharge performance.

The challenges of flex-fuel vehicle (FFV) emissions measurements have recently come to the forefront for the emissions testing community. The proliferation of ethanol blended gasoline in fractions as high as 85% has placed a new challenge in the path of accurate measures of NMHC and NMOG emissions. Test methods need modification to cope with excess amounts of water in the exhaust, assure transfer and capture of oxygenated compounds to integrated measurement systems (impinger and cartridge measurements) and provide modal emission rates of oxygenated species. Current test methods fall short of addressing these challenges. This presentation will discuss the challenges to FFV testing, modifications made to Ford Motor Company’s Vehicle Emissions Research Laboratory test cells, and demonstrate the improvements in recovery of oxygenated species from the vehicle exhaust system for both regulatory measurements and development measurements.

A production version of a V-8 engine was redesigned to run on partially premixed charge compression ignition (PCCI) combustion mode with conventional diesel fuel. The objective of the PCCI combustion experiments was to obtain low engine-out nitrogen oxide (NOx) and after-treatment tolerant soot emission level. Two fuel injection strategies were used during the PCCI combustion experiments: a) pilot-with-main injection strategy (Pil-M), b) pilot-with-main-and-post (PMP) injection strategy. In the Pil-M injection strategy, a significant fraction of the fuel was delivered early during the compression stroke. The early pilot helped to prepare a lean-mixture of enhanced homogeneity before the combustion was initiated. The combustion of this pilot injection followed by the main combustion helped to reduce soot for a constant NOx value. The pilot-injection timing and quantity had to be selected appropriately to retain the fuel-efficiency.

Quantitative planar laser-induced fluorescence (PLIF) of gaseous acetone as a fuel-tracer has been used in an optically accessible engine, fueled by direct hydrogen injection. The purpose of this article is to assess the accuracy and precision of the measurement and the associated data reduction procedures. A detailed description of the acetone seeding system is given as well. The key features of the experiment are a high-pressure bubbler saturating the hydrogen fuel with acetone vapor, direct injection into an optical engine, excitation of acetone fluorescence with an Nd:YAG laser at 266 nm, and detection of the resulting fluorescence by an unintensified camera. Key steps in the quantification of the single-shot imaging data are an in-situ calibration and a correction for the effect of local temperature on the fluorescence measurement.

A promising SCR-only solution is presented to meet post-2010 NOx emission targets for heavy duty applications. The proposed concept is based on an engine from a EURO IV SCR application, which is considered optimal with respect to fuel economy and costs. The addition of advanced SCR after treatment comprising a standard and a close-coupled SCR catalyst offers a feasible emission solution, especially suited for EURO VI. In this paper, results of a simulation study are presented. This study concentrates on optimizing SCR deNOx performance. Simulation results of cold start FTP and WHTC test cycles are presented to demonstrate the potential of the close-coupled SCR concept. Comparison with measured engine out emissions of an EGR engine shows that a close-coupled SCR catalyst potentially has NOx reduction performance as good as EGR. Practical issues regarding the use of an SCR catalyst in close-coupled position will be addressed, as well as engine and exhaust layout.

A laboratory study was performed to optimize a zoned configuration of an iron (Fe) SCR catalyst and a copper (Cu) SCR catalyst in order to provide high NOx conversion at lean A/F ratios over a broad range of temperature for diesel and lean-burn gasoline applications. With an optimized space velocity of 8,300 hr-1, a 67% (by volume) Fe section followed by a 33% Cu section provided at least 80% NOx conversion from approximately 230°C to 640°C when evaluated with 500 ppm NO and NH3. To improve the lean lightoff performance of the SCR catalyst system during a cold start, a Cu SCR catalyst that was 1/4 as long as the rear Cu SCR catalyst was placed in front of the Fe SCR catalyst. When evaluated with an excess of NH3 (NH3/NO ratio of 2.2), the Cu+Fe+Cu SCR system had significantly improved lightoff performance relative to the Fe+Cu SCR system, although the front Cu SCR catalyst did decrease the NOx conversion at temperatures above 475°C by oxidizing some of the NH3 to N2 or NO.

Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.