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The photocatalytic oxidation of VOCs was investigated using a novel countercurrent flow reactor designed to enable the treatment of toluene present in the gas and the aqueous phases simultaneously. The reactor was packed with silica-titania composites commingled with plastic pall rings. Using this mixed packing style was advantageous as it resulted in a higher UV penetration throughout the reactor. The average UV intensity in the reactor was determined to be 220 μW/g irradiated TiO2. It was found that under dry conditions, the STCs had a high adsorption capacity for toluene; however, this adsorption was completely hindered by the wetting of the STCs when the two phases were flowing simultaneously. The destruction of toluene in the aqueous phase was determined to follow a linear trend as a function of the contaminant concentration.

The partial electrochemical reduction of carbon dioxide (CO2) using ceramic oxygen generators (COGs) is well known and widely studied. Conventional COGs use yttria-stabilized zirconia (YSZ) electrolytes and operate at temperatures greater than 700 °C. Operating at a lower temperature has the advantage of reducing the mass of the ancillary components such as insulation and heat exchangers (to reduce the COG oxygen output temperature for comfortable inhalation). Moreover, complete reduction of metabolically produced CO2 (into carbon and oxygen) has the potential of reducing oxygen storage weight if the oxygen can be recovered. Recently, the University of Florida developed novel ceramic oxygen generators employing a bilayer electrolyte of gadolinia-doped ceria and erbia-stabilized bismuth oxide (ESB) for NASA's future exploration of Mars.

The removal of volatile organic compounds (VOCs) from the air aboard spacecrafts is necessary to maintain the health of crewmembers. The use of photocatalysis has proven effective for the removal of VOCs. A majority of studies have focused on thin films, which have a low adsorption capacity for contaminants and intermediate oxidation byproducts. Thus, this study investigates the use of adsorbent materials impregnated or coated with titania to: (1) provide a system that can remove VOCs for a period of time in the absence of UV irradiation to reduce power requirements and/or offer contaminant removal in the event of lamp failure and (2) improve the photocatalytic oxidation efficiency by concentrating VOCs and intermediate oxidation byproducts near the surface of the photocatalyst. Two adsorbent materials (porous silica gel and BioNuchar120 activated carbon) and glass beads were tested as catalyst supports for the destruction of a target VOC, in this case methanol (Co = 50 ppmv).

Operations involving autonomous vehicles require knowledge of the surrounding environment including other moving vehicles. The use of vision has been regarded as an enabling technology that can provide such information. Several important applications that would benefit from this technology is autonomous aerial refueling (AAR) and target tracking. This paper considers a sensor fusion approach using traditional IMU/GPS sensors with vision to facilitate the state estimation problem of moving targets. The proposed method makes use of a moving monocular camera to estimate the relative position and orientation of targets within the image by exploiting a known reference motion. The vision state estimation problem is solved using an homography approach that employs images containing both the reference and target vehicles. A simulation involving an unmanned aerial vehicle (UAV) and two ground vehicles is documented in this paper to demonstrate the algorithm and its accuracy.

Effective thermal and micrometeoroid protection as afforded by the Thermal Micrometeoroid Garment (TMG) is critical in achieving safe and efficient missions. It is also critical that the TMG does not increase torque or decreased range of motion which can cause crewmember discomfort, fatigue, and reduced efficiency. For future exploration missions, removable and replaceable TMGs will allow the use of different pressure garment protective covers and TMG configurations for launch, re-entry, 0-G Extra Vehicular Activity (EVA), and lunar surface EVA. A study was conducted with the goal of developing high Technology Readiness Level (TRL), scalable, interface design concepts for TMG systems. The affects of TMG segmentation on mobility and donning were assessed. Closure mechanisms were investigated and tested to determine their operability after exposure to lunar dust. A TMG configuration with the optimum number of segments and location of interfaces was selected for the Mark III spacesuit.

A trade study was conducted with a goal to develop relatively high TRL design concepts for an Exploration Cooling Garment (ExCG) that can accommodate larger metabolic loads and maintain physiological limits of the crewmembers health and work efficiency during all phases of exploration missions without hindering mobility. Effective personal cooling through use of an ExCG is critical in achieving safe and efficient missions. Crew thermoregulation not only impacts comfort during suited operations but also directly affects human performance. Since the ExCG is intimately worn and interfaces with comfort items, it is also critical to overall crewmember physical comfort. Both thermal and physical comfort are essential for the long term, continuous wear expected of the ExCG.

Silica-titania composites (STC), a novel sorbent and photocatalytic technology developed at the University of Florida in Gainesville, Florida have been evaluated for removal of volatile organic compounds (VOCs) from aircraft cabin air. Currently, activated carbon filters are used, but must be replaced frequently due to their limited adsorption capacity. These filters must be disposed of and cannot be regenerated and reused. The STC technology is a significant improvement upon the current control technology because of its high adsorption capacity and the ability to regenerate via photocatalytic oxidation (PCO). When the STC sorbent is irradiated with UV, adsorbed VOCs are mineralized to CO2 and H2O and the material is regenerated and ready for reuse multiple times.

A sub-scale testbed for characterizing the dynamic performance of regenerable adsorbents for filtering trace contaminants (TCs) from cabin atmospheres was built and tested. Regenerable adsorbents employed in pressure-swing adsorption (PSA) systems operate in a dynamic environment, where they undergo repeated loading / regeneration cycles. Adsorbents have a given chemical specificity for non-methane TCs depending on their composition, and on the humidity and temperature at which they operate. However, their ability to filter TCs is also affected by contact time, cycle time, regeneration vacuum quality and thermal conditioning.

The initial task in the preparation for Flight Experiment PGIM-01 (Plant Growth in Microgravity - 01) was the optimization of the plant nutrient system within the environment of the Plant Growth Facility (PGF – a Space Shuttle middeck locker plant growth unit). PGIM-01 entailed using the Transgenic Arabidopsis Gene Expression System (TAGES) to monitor effects of spaceflight-associated stress on gene expression. TAGES plants are genetically engineered arabidopsis plants designed with a sensitive reporter gene system that responds to a variety of environmental stresses. However, transgene expression can also be influenced by background environmental conditions. Thus, minimizing sources of background stress on the plants was crucial to ensure optimal growth and a high scientific return.

Two widespread practices in water treatment are, removal of pollutants via adsorption onto activated carbon, and, oxidation of pollutants using a photocatalyst slurry and ultraviolet radiation. The ultimate goal of this research is to combine the adsorptive properties of carbon and the oxidative properties of titanium dioxide (TiO2), and construct a photocatalytically regenerative carbon filter for 100% water recovery. The premise is that the activated carbon, coated with TiO2, will capture the compounds through traditional filtration and adsorption. Once the carbon becomes exhausted, it can be regenerated in-situ by turning on the UV lamps thereby activating the photocatalyst.

The technical feasibility of applying anaerobic digestion for reduction and stabilization of the organic fraction of solid wastes generated during space missions was investigated. This process has the advantages of not requiring oxygen or high temperature and pressure while producing methane, carbon dioxide, nutrients, and compost as valuable products. High-solids leachbed anaerobic digestion employed here involves a solid-phase fermentation with leachate recycle between new and old reactors for inoculation, wetting, and removal of volatile organic acids during startup. After anaerobic conversion is complete, the compost bed may be used for biofiltration and plant growth medium. The nutrient-rich leachate may also be used as a vehicle for nutrient recycle. Physical properties of representative waste feedstocks were determined to evaluate their space requirements and hydraulic leachability in the selected digester design.

The monitoring and control of an artificial climate is necessitated by the Mars Dome Project (MDP) [ref 1]. MDP is designed to grow plants in an enclosed structure under reduced pressure. This system includes a dome enclosure, an environmental control system, a plant growth system, a data logging system, and an external vacuum vessel [ref 2]. Each of these systems is integrated by the use of a solid-state control device located inside the base of the Atmospheric Tower Management System (ATMS). Details of the controller follow a short summary of the major components of the MDP.

Previous work demonstrated that the Photo-Cat® developed by Purifics is capable of reducing the total organic carbon (TOC) concentration of 51 mg/L to below 0.5 ppm using Degussa P25 titanium dioxide (TiO2) as a photocatalyst. The work also showed that ammonium bicarbonate had a detrimental effect on the rate of photocatalytic oxidation, but did not prevent the system from reaching the potable water specification. Nanometer sized Degussa P25 is very popular and quite frequently used as a benchmark of performance in literature, but it may not be the most effective for oxidizing all waste streams. It is critical that each component of the water recovery system be optimized for power consumption and the effectiveness of the photocatalyst plays an important role in accomplishing this.

A magnetically agitated photocatalytic reactor (MAPR) has been developed and tested as a post-processor in the past using phenol and reactive red dye to simulate these waste components, yet these components ignore factors that may hinder a photocatalytic post processor including competitive adsorption of various organic compounds and their oxidation byproducts and the demonstrated detrimental effect of inorganic compounds such as ammonium bicarbonate on photocatalytic oxidation. To assess these effects, this work looks at photocatalytic oxidation of air evaporation subsystem (AES) ersatz water while modifying the photocatalyst mass, magnetic field current and frequency to find the optimal conditions. Additionally, the magnetic photocatalyst has been characterized to observe the assembled structures formed when exposed to the magnetic field array in the MAPR and the crystallinity of the titanium dioxide coating.

Post-treatment of anaerobically digested residue produced during long term space missions was investigated. Solid waste was anaerobically digested by employing the SEBAC system. One of the goals of post-treatment step is to convert ammonia in the residue to nitrates via biological nitrification processes. It was found that anaerobically digested residue contained nitrifying microorganisms which could be activated by aeration. Without supplying any external nitrifying inoculum, nitrification was initiated within 2 days by continuously blowing air at 15 ml/min. The maximum rate was 0.78 mg /g dry weight /day. However, denitrification process occurred soon after nitrification and ∼ 50% of nitrate was denitrified. A modified system in which aeration was carried out by holding air within the reactor at a pressure of ∼ 10 psi yielded a higher initial specific nitrification rate of 1.7 mg/g dry weight/day. Moreover, nitrification was initiated within a day.

Efforts to develop sensor and control system technology to monitor air quality for life support have resulted in the development and preliminary testing of a concept based on expert systems and ion trap mass spectrometry (ITMS). An ITMS instrument provides the capability to identify and quantitate a large number of suspected contaminants at trace levels through the use of a variety of multidimensional experiments. An expert system provides specialized knowledge for control, analysis, and decision making. The system is intended for real-time, on-line, autonomous monitoring of air quality. The key characteristics of the system, performance data and analytical capabilities of the ITMS instrument, the design and operation of the expert system, and results from preliminary testing of the system for trace contaminant monitoring are described.

This paper describes an opportunity for commercial application of NASA space-based technology. Specifically, it describes application of the University of Florida's patented space-based SEBAC-II solid waste management technology to the US beet sugar industry. The project is entitled “Conversion of Biomass into Energy and Compost through Sequential Batch Anaerobic Composting”, and is being funded by the Xcel Energy Renewable Development Fund. It will be carried out by a team of researchers from the University of Florida in partnership with American Crystal Sugar Company (ACSC) of Moorhead, MN, and Minnesota Technology Inc. (MTI) in Minneapolis, MN. American Crystal Sugar generates 400 tons of sugar beet tailings daily. These tailings are a waste by-product of the raw sugar beet receiving, handling and washing operations. Currently, the company pays to have this material hauled away at the rate of 16 truckloads per day.

Finding a manner to effectively filter water to the purest standards is an ongoing battle for various sectors of science. We present a set of experiments that will report the preparation of the photocatalytic component of our composite particle via sol-gel coatings with titanium n-butoxide with subsequent heat treatment at 500°C for three hours in Argon. Our ultimate goal is to create a particle with regenerative capabilities along with a surface enhanced Raman scattering effect. Characterization techniques were performed using SEM-EDS, and XRD.

Surface defects were demonstrated to result from high productivity machining (HPM) as well as conventional machining of a titanium alloy Ti-6Al-4V, with HPM causing the larger sized defects. These defects could act as initiation sites for fatigue cracks showing that machining would affect fatigue strength and life of the part produced. A finishing pass appears to remove the defects. Better understanding is needed of the relationships between machining, surfaces, and strength.

High speed machining of aluminum and magnesium helicopter gearcases was experimentally demonstrated to be five times more productive than contemporary conventional commercial practice for suitable operations. Appropriate techniques and performance characteristics are discussed for face milling, endmilling and planetary milling operations. Potential problem areas, such as surface characteristics and machine tool performance requirements are discussed.