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The use of advanced electron microscopy techniques to characterize both the bulk and near-atomic level microstructural evolution of catalyst materials during different dynamometer/vehicle aging cycles is an integral part of understanding catalyst deactivation. The study described here was undertaken to evaluate thermally-induced microstructural changes which caused the progressive loss of catalyst performance in a three-way automotive catalyst. Several different catalyst processing variables, for example changing the washcoat ceria content, were also evaluated as a function of aging cycle and thermal history. A number of thermally-induced microstructural changes were identified using high resolution electron microscopy techniques that contributed to the deactivation of the catalyst, including sintering of all washcoat constituents, γ-alumina transforming to α-, β-, and δ-alumina, precious metal redistribution, and constituent encapsulation.

A high pressure outwardly opening fuel injector has been developed to produce sprays that meet the stringent requirements of gasoline direct injection (DI) combustion systems. Predictions of spray characteristics have been made using KIVA-3 in conjunction with Star-CD injector flow modeling. After some modeling iterations, the nozzle design has been optimized for the required flow, injector performance, and spray characteristics. The hardware test results of flow and spray have confirmed the numerical modeling accuracy and the spray quality. The spray's average Sauter mean diameter (SMD) is less than 15 microns at 30 mm distance from the nozzle. The DV90, defined as the drop diameter such that 90% of the total liquid volume is in drops of smaller diameter, is less than 40 microns. The maximum penetration is about 70 mm into air at atmospheric pressure. An initial spray slug is not created due to the absence of a sac volume.

Dual-monolith catalyst systems containing Pd/Rh three-way catalysts (TWCs) provide effective emission solutions for LEV2/Bin 5 and Bin 4 close-coupled applications at low PGM loadings. These systems combine washcoat technology and PGM distribution for front and rear catalysts resulting in optimal hydrocarbon and NOx light-off and transient NOx control. The dual-catalyst [Pd/Rh + Pd/Rh] systems are characterized as a function of Pd-Rh content, PGM location, and catalyst technology for 4-cyl [close-coupled + underfloor] systems and 6-cyl close-coupled applications. The current Pd/Rh dual-catalyst converters significantly reduce NOx emissions compared to earlier [Pd + Pt/Rh] or [Pd + Pd/Rh] LEV/ULEV systems by utilizing uniform Rh distribution and new OSC materials. These new design strategies particularly impact NOx performance, especially during transient A/F excursions.

This paper presents a brake pressure estimation algorithm for Delphi Traction Control Systems (TCS). A control oriented lumped parameter model of a brake control system is developed using Matlab/Simulink. The model is derived based on a typical brake system and is generic to other types of brake control hardware systems. For application purposes, the model is simplified to capture the dominant dynamic brake pressure response. Vehicle experimental data collected under various scenarios are used to validate the algorithm. Simulation results show that the algorithm gives accurate pressure estimation. In addition, the calibration procedure is greatly simplified

There are an increasing number of applications for resonant micromachines. Accelerometers, angular rate sensors, voltage controlled oscillators, pressure and chemical sensors have been demonstrated using this technology. Several of these devices are employed in vehicles. Vibrating devices have been made from silicon, quartz, GaAs, nickel and aluminum. Resonant microsystems are in constant motion and so present new challenges in the area of reliability for vehicular applications. The impact of temperature extremes, cyclic fatigue, stiction, thermal and mechanical shock on resonant device performance is covered.

A dynamic EGR State Estimator (ESE) intended for production engine management systems (EMS) implementation is presented. It better describes the development of external exhaust gas recirculation (EGR) concentration at the engine intake ports during EGR transients than traditional models. The dynamics of EGR concentration time and spatial development in the intake manifold are described as a perfect mixing model in the intake manifold plenum volume and non-mixing plug flow in the intake manifold runners. The time scale of EGR transients precludes the use of traditional EGR measurement techniques for model verification. Instead a wide range air fuel (WRAF) sensor is used. Results are shown for a large variation in operating conditions and compared to the performance of a traditional model.

A parametric study on the effects of critical injector design parameters of inwardly-opening pressure-swirl injectors was carried out using 3-D internal flow simulations. The pressure variation and the integrated momentum flux across the injector, as well as the flow distributions and turbulence structure at the nozzle exit were analyzed. The critical flow effects on the injector design identified are the swirler efficiency, discharge coefficient, and turbulence breakup effects on the spray structure. The study shows that as a unique class of injectors, pressure-swirl injectors is complicated in fluid mechanics and not sufficiently characterized or optimized. The swirler efficiency is characterized in terms of the trade-off relationship between the swirl-to-axial momentum-flux ratio and pressure drop across the swirler. The results show that swirl number is inversely proportional to discharge coefficient, and that hole diameter and swirler height is the most dominant parameters.

Performance of two types of NOx adsorber catalysts, one based on Ba and the other based on Ba with alkali metals, was compared fresh and after thermal aging. Incorporation of sodium(Na), potassium(K) and cesium(Cs) into NOx adsorber washcoat containing barium significantly increases the NOx conversions in the temperature range of 350-600°C over that of the alkali metal free NOx adsorber catalysts. NOx performance benefit and HC performance penalty were observed on both engine dynamometer and vehicle tests for the “Ba+alkali metals” NOx adsorber catalysts. “Ba+alkali metals” NOx adsorber catalysts also demonstrate superior sulfur resistance with better NOx performance after repeated sulfur poisonings and desulfations over the “Ba based” NOx adsorber catalysts.

Several heater cores failed due to erosion by cavitation. After analysis, most of failures were explained by the presence of impurities in the heater core. It was then decided with the customer to use CFD simulation in order to prove that the cavitation was not caused by design concept of the tank. In this paper, we present the results of heater core simulations done in 2D and in 3D with Fluent. The objective is to simulate the pressure and velocity distribution within the heater core and to verify if the zones of low pressure are below the saturation vapour pressure of the fluid causing cavitation. In these areas, the deterioration of the tubes might occur due to erosion by cavitation.

Dual-brick catalyst systems containing Pd-only catalysts followed by Pt/Rh three-way catalysts (TWCs) are effective emission solutions for both close-coupled and underfloor LEV/ULEV applications due to optimal hydrocarbon light-off, NOx control, and balance of precious metal (PGM) usage. Dual-brick [Pd +Pt/Rh] systems on 3.8L V-6 LEV-calibrated vehicles were characterized as a function of PGM loading, catalyst technology, converter volumes, and substrate cell density. While hydrocarbon emissions improve with increasing Pd loading, decreasing the front catalyst volume at constant Pd content (resulting in higher Pd density) improved light-off emissions. Use of 600cpsi substrates improved underfloor NMHC emissions on a 3.8L vehicle by ∼ 6-10mg/mi compared to 400cpsi catalysts, and thus allowing reduction of catalyst volume while achieving ULEV emission levels without air addition.

With new legislation and federal regulation for vehicle emission levels, automotive and truck manufacturers have been prompted to focus on emission control technologies that limit the level of exhaust pollutants. One of the primary pollutants, especially from diesel engines, is oxides of nitrogen (NOx). One possible solution to this pollution challenge is to design a more efficient internal combustion engine, which would require better engine operating parameter controls. However, there are limitations associated with such tight engine management. This need has led researchers and engineers to focus on the development of exhaust aftertreatment devices that will reduce NOx emissions with current diesel engines. An optimum aftertreatment device must be unaffected by exhaust-gas impurity poisoning such as sulfur products, and must have minimal impact on vehicle operations and fuel economy.

In the catalytic converter, the thermal conductivity of the insulation material (intumescent mat) placed between the ceramic catalyst and the metal shell is strongly dependent on the temperature, resulting in the solving of non-linear heat conduction equations. In this paper, the analytic solution for the steady heat flow in a cylinder with temperature dependent conductivity is given. Using this analytic solution for the mat and including convection and radiation at the converter skin, an analytical expression for calculating converter skin temperature is obtained. This expression can be easily incorporated in a Fortran code to calculate the temperatures.

Accurately predicting converter assembly deformation and mat pressure is essential in converter packaging design and manufacturing. In stuffing packaging, the annulus between the deformed shell and the catalyst is larger than that between the stuffing cone and the catalyst. As a result, the mat expands and undergoes unloading process. Tests show that the mat exhibits different loading and unloading characteristics. Using such a hysteresis mat pressure vs density curve in finite element analysis, the computed converter deformations closely agree with test data. Conversly, neglecting the mat hysteresis behavior may overestimate the deformation and pressure by a factor of three to four.

With ever more stringent CO2 emissions mandates, many automobile manufacturers are seeking the fuel economy benefits of diesel and lean-burn gasoline engines. At the same time the emissions standards that diesel and gasoline engines will have to meet in the next decade continue to reduce. Proposed solutions for meeting the stringent emissions standards all appear to have limitations, such as propensities to poisoning from sulfur, narrow operating temperature windows, and requirements for controls that give rapid rich excursions. Non-thermal plasma-catalyst systems have shown good performance in bench testing while being largely unaffected by these same issues. A two-stage system with a unique non-thermal plasma reactor combined with a zeolite-based catalyst has been constructed and shown to work over a wide temperature range.

Mean Value Engine Models (MVEMs) are simplified, dynamic engine models which are physically based. Such models are useful for control studies, for engine control system analysis and for model based engine control systems. Very few published MVEMs have included the effects of Exhaust Gas Recirculation (EGR). The purpose of this paper is to present a modified MVEM which includes EGR in a physical way. It has been tested using newly developed, very fast manifold pressure, manifold temperature, port and EGR mass flow sensors. Reasonable agreement has been obtained on an experiemental engine, mounted on a dynamometer.

Automotive multi-sensor modules, capable of vehicle-wide communications via a data bus will be discussed. Proper sensor grouping, packaging and device placement are key issues in the implementation of smart sensor modules. Sensors that are candidates for clustering include temperature, acceleration, angular rate, barometric pressure, chemical, and light sensors. The capability to accommodate a variety of data bus communication protocols is required to satisfy the majority of automotive systems. System integration must be considered when employing a smart sensor network through-out an automobile in a cost effective manner. This paper will cover the module issues associated with sensing, packaging, electronics, communication and system integration.

A Barometric Pressure Estimator (BPE) algorithm was implemented in a production speed-density Engine Management System (EMS). The BPE is a model-based, easily calibrated algorithm for estimating barometric pressure using a standard set of production sensors, thereby avoiding the need for a barometric pressure sensor. An accurate barometric pressure value is necessary for a variety of engine control functions. By starting with the physics describing the flow through the induction system, an algorithm was developed which is simple to understand and implement. When used in conjunction with the Pneumatic and Thermal State Estimator (PSE and TSE) algorithms [2], the BPE requires only a single additional calibration table, generated with an automated processing routine, directly from measured engine data collected at an arbitrary elevation, in-vehicle or on a dynamometer. The algorithm has been implemented on several different engines.

In this paper we discuss in detail an algorithm that addresses cylinder-to-cylinder imbalance issues. Maintaining even equivalence-ratio (ϕ) control across all the cylinders of an engine is confounded by imbalances which include fuel-injector flow variations, fresh-air intake maldistribution and uneven distribution of Exhaust Gas Re-circulation (EGR). Moreover, in markets that are growing increasingly cost conscious, with ever tightening emissions regulations, correcting for such mismatches must not only be done, but done at little or no additional cost. To address this challenge, we developed an Individual Cylinder Fuel Control (ICFC) algorithm that estimates each cylinder's individual ϕ and then compensates to correct for any imbalance using only existing production hardware. Prior work in this area exists1,2, yet all disclosed production-intent work was performed using wide-range oxygen sensors, representing cost increases.

TPO is getting wider acceptance for automotive applications. An exterior application like a fascia is a very good example. Interiors are still a challenge due to many reasons including overall system cost. For interior applications, “all-olefin” means it mainly consists of three materials: TPO skin, cross-linked olefinic-based foam and PP substrate. The driving force for TPO in Europe is mainly recyclability while in the USA, it is long-term durability. This paper describes the key limitations of the current TPO systems which are: poor grain retention of TPO skin, shrinkage in-consistency of the skin, high cost of priming (or other treatments) and painting of the skin, lower process window of the semi-crystalline TPO material during thermoforming or In-mold lamination / Low pressure molding, high cost of the foam, low tear strength of the foam for deep draw ratio etc.

A double dielectric barrier discharge reactor driven by an alternating voltage is a relatively simple approach to promote oxidation of NO to NO2 for subsequent reduction in a catalyst bed. The chemical performance of such a non-thermal plasma reactor is determined by its current and electric field behavior in the gap, and by the fraction of the current carried by electrons, because the key reactants which initiate the NO oxidation and accompanying chemical changes are produced there, mostly by electron impact. We have tried to determine by models and experiments the bounds on performance of double dielectric barrier reactors and guidelines for optimization. Models reported here predict chemical results from time-resolved applied voltage and series sense capacitor data.