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A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-06-18
Currently, two consolidated aftertreatment technologies are available for the reduction of NOx emissions from diesel engines: Urea SCR (Selective Catalytic Reduction) systems and LNT (Lean NOx Trap) systems. Urea SCR technology, which has been widely used for many years at stationary sources, is becoming nowadays an attractive alternative also for light-duty diesel applications. However, SCR systems are much more effective in NOx reduction efficiency at high load operating conditions than light load condition, characterized by lower exhaust gas temperatures.
Journal Article

Advanced Control System of Variable Compression Ratio (VCR) Engine with Dual Piston Mechanism

2009-04-20
2009-01-1063
A dual piston Variable Compression Ratio (VCR) engine has been newly developed. This compact VCR system uses the inertia force and hydraulic pressure accompanying the reciprocating motion of the piston to raise and lower the outer piston and switches the compression ratio in two stages. For the torque characteristic enhancement and the knocking prevention when the compression ratio is being switched, it is necessary to carry out engine controls based on accurate compression ratio judgment. In order to accurately judge compression ratio switching timing, a control system employing the Hidden Markov Model (HMM) was used to analyze vibration generated during the compression ratio switching. Also, in order to realize smooth torque characteristics, an ignition timing control system that separately controls each cylinder and simultaneously performs knocking control was constructed.
Technical Paper

Onboard Ethanol-Gasoline Separation System for Octane-on-Demand Vehicle

2020-04-14
2020-01-0350
Bioethanol is being used as an alternative fuel throughout the world based on considerations of reduction of CO2 emissions and sustainability. It is widely known that ethanol has an advantage of high anti-knock quality. In order to use the ethanol in ethanol-blended gasoline to control knocking, the research discussed in this paper sought to develop a fuel separation system that would separate ethanol-blended gasoline into a high-octane-number fuel (high-ethanol-concentration fuel) and a low-octane-number fuel (low-ethanol-concentration fuel) in the vehicle. The research developed a small fuel separation system, and employed a layout in which the system was fitted in the fuel tank based on considerations of reducing the effect on cabin space and maintaining safety in the event of a collision. The total volume of the components fitted in the fuel tank is 6.6 liters.
Journal Article

Multi-Variable Air-Path Management for a Clean Diesel Engine Using Model Predictive Control

2009-04-20
2009-01-0733
Recently, emission regulations have been strict in many countries, and it is very difficult technical issue to reduce emissions of diesel cars. In order to reduce the emissions, various combustion technologies such as Massive EGR, PCCI, Rich combustion, etc. have been researched. The combustion technologies require precise control of the states of in-cylinder gas (air mass flow, EGR rate etc.). However, a conventional controller such as PID controller could not provide sufficient control accuracy of the states of in-cylinder gas because the air-pass system controlled by an EGR valve, a throttle valve, a variable nozzle turbo, etc. is a multi-input, multi-output (MIMO) coupled system. Model predictive control (MPC) is well known as the advanced MIMO control method for industrial process. Generally, the sampling period of industrial process is rather long so there is enough time to carry out the optimization calculation for MPC.
Journal Article

Ag-Type PM Oxidation Catalyst with Nd Added to Increase Contact Property between PM and Catalyst

2018-04-03
2018-01-0328
Honda diesel engine vehicles that go on the market in 2018 will be equipped with a newly developed silver (Ag)-type catalyzed diesel particulate filter (cDPF). Ag has high particulate matter (PM) oxidation performance, but conventional catalyst-carrying methods cause weak contact property between PM and Ag; therefore, the newly Ag-type cDPF was developed on the concept of enhancing the property of contact between PM and the catalyst to realize contact property enhancement at the macro, meso, and nano scales. As a result, the newly developed catalyst showed an enhancement of T90 performance by a factor of approximately 2 relative to the conventional Ag-type catalyst in fresh condition. Durability in the environment of an automobile in use was examined through hydrothermal aging, lean-rich (L/R) aging, sulfur (S) poisoning, and ash deposition. The results have confirmed that hydrothermal aging is the greatest factor in deterioration.
Journal Article

NOx Trap Three-Way Catalyst (N-TWC) Concept: TWC with NOx Adsorption Properties at Low Temperatures for Cold-Start Emission Control

2015-04-14
2015-01-1002
A new concept for trapping NOx and HC during cold start, the NOx Trap Three-Way Catalyst (N-TWC), is proposed. N-TWC adsorbs NOx at room temperature, and upon reaching activation temperature under suitable air-fuel ratio conditions, it reduces the adsorbed NOx. This allows a reduction in NOx emissions during cold start. N-TWC's reduction mechanism relies on NOx adsorption sites which are shown to be highly dispersed palladium on acid sites in the zeolite. Testing on an actual vehicle equipped with N-TWC confirmed that N-TWC is able to reduce emissions of NOx and HC during cold start, which is a challenge for conventional TWCs.
Technical Paper

Study on Emission Reducing Method with New Lean NOX Catalyst for Diesel Engines

2007-07-23
2007-01-1933
In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For diesel engines, reducing NOX emissions is a difficult technical challenge.[1],[2],[3],[4]. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows the effective reduction of NOX. However, in order to realize cleaner emission gases, precise engine control in response to the state of the exhaust aftertreatment system is essential.
Technical Paper

Study on Low NOX Emission Control Using Newly Developed Lean NOX Catalyst for Diesel Engines

2007-04-16
2007-01-0239
In recent years, emission regulations have become more stringent as a result of increased environmental awareness in each region of the world. For lean-burn diesel engines, since it is not possible to use three-way catalytic converters, reducing NOX emissions is a difficult technical challenge. To respond to these strict regulations, an exhaust gas aftertreatment system was developed, featuring a lean NOX catalyst (LNC) that uses a new chemical reaction mechanism to reduce NOX. The feature of the new LNC is the way it reduces NOX through an NH3-selective catalytic reduction (SCR), in which NOX adsorbed in the lean mixture condition is converted to NH3 in the rich mixture condition and reduced in the following lean mixture condition. Thus, the new system allows more efficient reduction of NOX than its conventional counterparts. However, an appropriate switching control between lean and rich mixture conditions along with compensation for catalyst deterioration was necessary.
Technical Paper

Performance of Motorcycle Engine Oil with Sulfur-Based Additive as Substitute Zn-DTP

2008-09-09
2008-32-0005
Just as CO2 reduction is required of four wheeled vehicles for environmental protection, similar environmental concerns drive the development of motorcycle oil technology. Zinc dialkyldithiophosphate (Zn-DTP) type additives are widely used for engine oil formulations. However, phosphorus compounds are environmental load materials. The reduction of the quantity of phosphorus compounds in engine oils is required to reduce poisoning of three-way catalysts used to purify exhaust gases from internal combustion engines. Mr. Ito and his co-authors1) reported that they developed a sulfur-based additive as a substitute for Zn-DTP. Their non-phosphorus engine oil formulation for four-wheeled vehicles with a sulfur-based additive was examined to evaluate its anti-wear performance using the following test methods:JASO M328 for gasoline engines (KA24E) and JASO M354 for Diesel engine (4D34T4).
Technical Paper

Study on Engine Management System Using In-cylinder Pressure Sensor Integrated with Spark Plug

2004-03-08
2004-01-0519
There has been strong public demand for reduced hazardous exhaust gas emissions and improved fuel economy for automobile engines. In recent years, a number of innovative solutions that lead to a reduction in fuel consumption rate have been developed, including in-cylinder direct injection and lean burn combustion technologies, as well as an engine utilizing a large volume of exhaust gas recirculation (EGR). Furthermore, a homogeneous charge compression ignition (HCCI) engine is under development for actual application. However, one of the issues common to these technologies is less stable combustion, which causes difficulty in engine management. Additionally, it is now mandatory to provide an onboard diagnosis (OBD) system. This requires manufacturers to develop a technology that allows onboard monitoring and control of the combustion state. This paper reports on an innovative combustion diagnostic method using an in-cylinder pressure sensor.
Technical Paper

Engine Knock Toughness Improvement Through Water Jacket Optimization

2003-10-27
2003-01-3259
Improvement of engine cycle thermal efficiency is an effective way to increase engine torque and to reduce fuel consumption simultaneously. However, the extent of the improvement is limited by engine knock, which is more evident at low engine speeds when combustion flame propagation is relatively slow. To prevent engine damage due to knock, the spark ignition timing of a gasoline engine is usually controlled by a knock sensor. Therefore, an engine's ignition timing cannot be set freely to achieve best engine performance and fuel economy. Whether ignition timings for a multi-cylinder engine are the same or can be set differently for each cylinder, it is not desirable for each cylinder has big deviation from the median with respect to knock tendency. It is apparent that effective measures to improve engine knock toughness should address both uniformity of all cylinders of a multi-cylinder engine and improvement of median knock toughness.
Technical Paper

Intake and Exhaust Systems Equipped with a Variable Valve Control Device for Enhancing of Engine Power

2001-03-05
2001-01-0247
The variable intake and exhaust control valve system for the in-line four-cylinder motorcycle engine was developed for realization of high engine power in all the engine speed ranges. Both the variable intake and exhaust control valves are operated by one servomotor. For high engine speeds, the exhaust collector pipe design for merging of each exhaust gas flow at 180 degrees phase difference is used. For mid engine speeds, the design for merging of each exhaust gas flow at 360 degrees phase difference is used. Two modes are provided to the intake control, and three modes are provided to the exhaust control. Along with exhaust-gas treatment systems such as the catalyst and air-injection system, high engine performance with optimum driveability and reduced emission are realized.
Technical Paper

Improvement of Heat Resistance for Lean NOx Catalyst

2004-03-08
2004-01-1495
When the alkali metal-supported catalyst was treated at 830°C, the NOx conversion decreased because the alkali metals in the catalyst layer gradually moved to the cordierite honeycomb layer and reacted with the cordierite elements. This phenomena decreased to be added the basic metal oxide (α) in the catalyst layer. The improved catalyst with α 2 showed higher performance than the conventional catalyst in the model gas test. Moreover, the emission values of NOx, HC, and CO were 50% or less than Japanese domestic regulation values even after 830°C×60h heat treatment in a vehicle test.
Technical Paper

Study on Combustion Monitoring System for Formula One Engines Using Ionic Current Measurement

2004-06-08
2004-01-1921
Formula One engines, which are the pursuit of the ultimate in performance, tend to be comparatively vulnerable to durability issues. These engines sometimes run under a state of unstable combustion as compensation for improved fuel economy. To cope with these issues, there have been strong demands in the racing field for a technology that will allow constant monitoring and prompt action to be carried out on system malfunctions and failures, as well as unstable combustion. The research program described in this paper deals with an onboard technology for monitoring combustion under all the operational conditions using ionic current measurement. The technology will possibly be applied to engine management and car-to-pit communications via telemetering. The scope of the control it offers includes; detection of misfire and hesitation, detection and management of detonation, and management of lean-burn combustion.
Technical Paper

Improvement of Thermal Resistance for Lean NOx Catalyst

2003-03-03
2003-01-1166
A new type of lean NOx catalyst has been developed with improved thermal resistance. This lean NOx catalyst contains precious metals and NO2 adsorbents. The precious metals are used mainly for the oxidation reaction of NO, and the NO2 adsorbents are for the adsorption removal of generated NO2. The thermal resistance of the catalyst was raised by paying attention to the following points. 1) Improvement of thermal resistance for the NO oxidation activity by addition of a different precious metal element. 2) Prevention of thermal degradation of the NO2 adsorbent by addition of a new metal oxide. For item 1, Pd was added to the catalyst which had already included Pt. By having Pd coexist with Pt, the precious metal dispersion was kept high even after heat treatment, so the NO oxidizing ability was improved. For item 2, thermal degradation of NO2 adsorbent was prevented by addition of the new metal oxide (B) to the adsorbent.
Technical Paper

On Demand Octane Number Enhancement Technology by Aerobic Oxidation

2016-10-17
2016-01-2167
For the purpose of developing onboard gasoline reforming technology for higher octane number fuel on demand, octane number enhancement of gasoline surrogate by aerobic oxidation using N-hydroxyphthalimide catalyst was investigated. At first, octane numbers of the oxygen-containing products from alkane and aromatic compound were estimated using a fuel ignition analyzer. As a result, not only alcohol but also ketones and aldehydes have higher octane numbers than the original alkanes and aromatic compound. Next, gasoline surrogate was oxidized aerobically with N-hydroxyphthalimide derivative catalyst and cobalt catalyst at conditions below 100 °C. As a result, fuel molecules were oxidized to produce alcohols, ketones, aldehydes, and carboxylic acids. N-hydroxyphthalimide derivative catalyst with higher solubility in gasoline surrogate has higher oxidation ability. Furthermore, the estimated octane number of the oxidized gasoline surrogate improves 17 RON.
Technical Paper

Development of a New 1.5L I4 Turbocharged Gasoline Direct Injection Engine

2016-04-05
2016-01-1020
A 1.5 L downsizing turbocharged engine was developed to achieve both driving and environmental performance. The engine is intended to replace 1.8 - 2.4 L class NA engines. In downsizing turbocharged engines, mixture homogeneity is important for suppressing knocking and emission reduction. Particularly under high load, creating rapid combustion and a homogeneous mixture are key technologies. The authors used a long-stroke direct injection engine, which has outstanding rapid combustion and thermal efficiency, as a base engine meeting these requirements. They combined this with a high-tumble port and shallow-dish piston intended to support tumble flow. The combination enhanced flow within the cylinder. The combustion system was built to include a sodium-filled exhaust valve to reduce knocking and a multi-hole injector (six holes) for mixture homogeneity and to reduce the fuel wall wetting.
Technical Paper

Study of an Aftertreatment System for HLSI Lean-burn Engine

2018-04-03
2018-01-0945
Lean-burn is an effective means of reducing CO2 emissions. To date, Homogenous Lean Charge Spark Ignition (HLSI) combustion, which lowers emissions of both CO2 and NOx, has been studied. Although HLSI realizes lower emission, it is a major challenge for lean-burn engines to meet SULEV regulations, so we have developed a new aftertreatment system for HLSI engines. It consists of three types of catalysts that have different functions, as well as special engine control methods. As the first stage in achieving SULEV emissions, this study focused on enhancing performance under lean conditions. HLSI engine exhaust gases contain high concentrations of hydrocarbons, including a large amount of paraffin, which are difficult to purify, rather than low concentrations of NOx. Therefore, the key point in low emissions is to purify not only NOx, but also high concentrations of paraffin at the same time.
Technical Paper

A Study of PGM-Free Oxidation Catalyst YMnO3 for Diesel Exhaust Aftertreatment

2012-04-16
2012-01-0365
Manganese oxides show high catalytic activity for CO and HC oxidation without including platinum group metals (PGM). However, there are issues with both thermal stability and resistance to sulfur poisoning. We have studied perovskite-type YMnO₃ (YMO) with the aim of simultaneously achieving both activity and durability. This paper describes the oxidation activity of PGM-free Ag/i-YMO, which is silver supported on improved-YMO (i-YMO). The Ag/i-YMO was obtained by the following two methods. First, Mn⁴+ ratio and specific surface area of YMO were increased by optimizing composition and preparation method. Second, the optimum amount of silver was supported on i-YMO. In model gas tests and engine bench tests, the Ag/i-YMO catalyst showed the same level of activity as that of the conventional Pt/γ-Al₂O₃ (Pt = 3.0 g/L). In addition, there was no degradation with respect to either heat treatment (700°C, 90 h, air) or sulfur treatment (600°C to 200°C, total 60 h, 30 ppm SO₂).
Technical Paper

Study on Ignition Timing Control for Diesel Engines Using In-Cylinder Pressure Sensor

2006-04-03
2006-01-0180
As technologies for simultaneously maintaining the current high thermal efficiency of diesel engines and reducing particulate matter (PM) and nitrogen oxide (NOX) emissions, many new combustion concepts have been proposed, including premixed charge compression ignition (PCCI) and low-temperature combustion[1]. However, it is well known that since such new combustion techniques precisely control combustion temperatures and local air-fuel ratios by varying the amount of air, the exhaust gas recirculation (EGR) ratio and the fuel injection timing, they have the issues of being less stable than conventional combustion techniques and of performance that is subject to variance in the fuel and driving conditions. This study concerns a system that addresses these issues by detecting the ignition timing with in-cylinder pressure sensors and by controlling the fuel injection timing and the amount of EGR for optimum combustion onboard.
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