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Some soot particles emitted from common-rail diesel engines are so small that can penetrate deep into the human pulmonary system, causing serious health issues. The analysis of nano-scale internal structure of these soot particles sampled from the engine tailpipe has provided useful information about their reactivity and toxicity. However, the variations of carbon fringe structures during complex soot formation/oxidation processes occurring inside the engine cylinder are not fully understood. To fill this gap, this paper presents experimental methods for direct sampling and nanostructure analysis of in-flame soot particles in a working diesel engine. The soot particles are collected onto a lacey carbon-coated grid and then imaged in a high-resolution transmission electron microscope (HR-TEM). The HR-TEM images are post-processed using a Matlab-based code to obtain key nanostructure parameters such as carbon fringe length, fringe-to-fringe separation distance, and fringe tortuosity.

The importance of radiative heat transfer on the combustion and soot formation characteristics under nominal ECN Spray A conditions has been studied numerically. The liquid n-dodecane fuel is injected with 1500 bar fuel pressure into the constant volume chamber at different ambient conditions. Radiation from both gas-phase as well as soot particles has been included and assumed as gray. Three different solvers for the radiative transfer equation have been employed: the discrete ordinate method, the spherical-harmonics method and the optically thin assumption. The radiation models have been coupled with the transported probability density function method for turbulent reactive flows and soot, where unresolved turbulent fluctuations in temperature and composition are included and therefore capturing turbulence-chemistry-soot-radiation interactions. Results show that the gas-phase (mostly CO2 ad H2O species) has a higher contribution to the net radiation heat transfer compared to soot.

Stringent particulate emission regulations are applied to spark-ignition direct-injection (SIDI) engines, calling for a significant in-cylinder reduction of soot particles. To enhance fundamental knowledge of the soot formation and oxidation process inside the cylinder of the engine, a new in-flame particle sampling system has been developed and implemented in a working optical SIDI engine with a side-mounted, wall-guided injection system. Using the sampling probes installed on the piston top, the soot particles are directly sampled from the petrol flame for detailed analysis of particle size distribution, structure, and shape. At the probe tip, a transmission electron microscope (TEM) grid is stored for the soot collection via thermophoresis, which is imaged and post-processed for statistical analysis. Simultaneously, the flame development was recorded using two high-speed cameras to evidence the direct exposure of the sampling grids to the soot-laden diffusion flames and pool fires.

In-flame soot sampling based on the thermophoresis of particles and subsequent transmission electron microscope (TEM) imaging has been conducted in a diesel engine to study size, shape and structure of soot particles within the reacting diesel jet. A direct TEM sampling is pursued, as opposed to exhaust sampling, to gain fundamental insight about the structure of soot during key formation and oxidation stages. The size and shape of soot particles aggregate structure with stretched chains of spherical-like primary particles is currently an unknown for engine soot modelling approaches. However, the in-flame sampling of soot particles in the engine poses significant challenges in order to extract meaningful data. In this paper, the engine modification to address the challenges of high-pressure sealing and avoiding interference with moving valves and piston are discussed in detail.

Wall-deposition of soot particles occurs during the cylinder liner wall/flame interaction, which can potentially deteriorate engine oil quality and alter the heat loss rate in a diesel engine. These issues motivate a detailed study on structure and size of the wall-deposited soot particles. A morphological difference between the wall-deposited soot and in-flame soot particles is another focus of this study. We performed thermophoretic soot sampling in the cylinder liner wall using an in-liner-type sampler. Obtained soot particles were imaged by a transmission electron microscope and post-processed to acquire the number of particles, projection area on the sampling grid, and size distribution. The same set of data was also obtained for soot particles within the diesel flame using a probe-type sampler.

Influence of the injection pressure on the temporal evolution of lifted jet flame base upon the bowl wall impingement has been studied in a small-bore optical diesel engine. Previous studies suggest that the jet-wall interaction causes re-entrainment of combustion products into the incoming jet, which shortens the lift-off length during the injection and thereby increasing downstream soot. After the end of injection, the flame base slowly moves downstream as the diminishing jet momentum results in reduced re-entrainment. How the injection pressure impacts this transient behaviour of the flame base is a main focus of the present study. Common-rail pressure was varied from 70 to 160 MPa at a fixed injection mass (10 mg per hole) and timing (7°CA bTDC).

One major drawback of spark-ignition direct-injection (SIDI) engines is increased particulate matter (PM) and unburned hydrocarbon emissions at high load, due to wall wetting and a reduction in available air/fuel mixing time when compared to port-fuel injection (PFI). It is therefore necessary to understand the mechanics behind injection strategies which are capable of reducing these emissions while also maintaining the performance and efficiency of the engine. This study investigates the effect of varying the number fuel injection events and equivalence ratio on the operation of a wall-guided SIDI (WG-SIDI) engine. Of particular interest is how increased mixture homogeneity achieved by the double injection events impacts in-cylinder conditions and flame development.

One major drawback of spark-ignition direct-injection (SIDI) engines is increased particulate matter (PM) emissions at high load, due to increased wall wetting and a reduction in available mixture preparation time when compared to port-fuel injection (PFI). It is therefore necessary to understand the mechanics behind injection strategies which are capable of reducing these emissions while also maintaining the performance and efficiency of the engine. Splitting the fuel delivery into two or more injections is a proven way of working towards this goal, however, many different injection permutations are possible and as such there is no clear consensus on what constitutes an ideal strategy for any given objective. In this study, the effect of the timing of the first and second injections for an evenly split dual injection strategy are investigated in an optical SIDI engine running at 1200 RPM with an unthrottled intake.

Soot particles emitted from modern diesel engines, despite significantly lower total mass, show higher reactivity and toxicity than black-smoking old engines, which cause serious health and environmental issues. Soot nanostructure, i.e. the internal structure of soot particles composed of nanoscale carbon fringes, can provide useful information to the investigation of the particle reactivity and its oxidation status. This study presents the nanostructure details of soot particles sampled directly from diesel flames in a working diesel engine as well as from exhaust gases to compare the internal structure of soot particles in the high formation stage and after in-cylinder oxidation. Thermophoretic soot sampling was conducted using an in-house-designed probe with a lacy transmission electron microscope (TEM) grid stored at the tip.

For better understanding of soot formation and oxidation processes applicable to diesel engines, the size, morphology, and nanostructure of soot particles directly sampled in a diesel spray flame generated in a constant-volume combustion chamber have been investigated using Transmission Electron Microscopy (TEM). For this soot diagnostics, the effects of the sampling processes, TEM observation methodology and image processing methods on the uncertainty in the results have not been extensively discussed, mainly due to the complexity of the analysis.

This paper reports experimental conversion of spent vegetable oil with bio-ethanol to long chain biodiesel fuel in presence of a new developed solid K3PO4 heterogeneous catalyst. Examined catalyst was synthesized following dipping impregnation of γ-Al2O3 solid support in an aqueous solution of potassium phosphate tri-basic K3PO4. K3PO4/γ-Al2O3 catalyst samples were distinguished based on their percentage loadings of K3PO4 (CK3PO4) and averaged particle size (dp). Produced catalyst samples were characterized in terms of their textural and surface properties using nitrogen adsorption-desorption isotherms and carbon dioxide & ammonia temperature programmed desorption techniques respectively. While the liquid phase of the product was analyzed using a GC-Mass spectroscopy technique. Ethanolysis runs were carried out following surface response methodology, central composite design (CCD).

The present study focuses on the observation of knock phenomena in a small-bore optical diesel engine. Current understanding is that a drastic increase of pressure during the premixed burn phase of the diesel combustion causes gas cavity resonances, which in turn induce a high frequency pressure ringing. The frequency and severity of this ringing can be easily measured by using a pressure transducer. However, visual information of flames under knocking conditions is limited especially for a small-bore diesel engine. To fill this gap, high-speed imaging of soot luminosity is performed in conjunction with in-cylinder pressure measurement during knocking cycles in an automotive-size optical diesel engine. From the experiments, flames were observed to oscillate against the direction of the swirl flow when the pressure ringing occurred.

High-speed soot luminosity movies are widely used to visualise flame development in optical diesel engines thanks to its simple setup and relatively low cost. Recent studies demonstrated the high-speed soot luminosity movies are not only effective in showing the overall distribution and temporal evolution of sooting flames but also flow fields within the flame through the application of combustion (or flame) image velocimetry. The present study aims to improve this imaging technique by systematically evaluating key image processing parameters based on high-speed soot luminosity movies obtained from a single-cylinder, small-bore optical diesel engine. The raw soot luminosity movies are processed using PIVlab - a Matlab-based open-source code widely used for particle image velocimetry (PIV) applications.

The present study explores the effect of in-cylinder generated non-thermal plasma on hydroxyl and soot development. Plasma was generated using a newly developed Microwave Discharge Igniter (MDI), a device which operates based on the principle of microwave resonation and has the potential to accentuate the formation of active radical pools as well as suppress soot formation while stimulating soot oxidation. Three diagnostic techniques were employed in a single-cylinder small-bore optical diesel engine, including chemiluminescence imaging of electronically excited hydroxyl (OH*), planar laser induced fluorescence imaging of OH (OH-PLIF) and planar laser induced incandescence (PLII) imaging of soot. While investigating the behaviour of MDI discharge under engine motoring conditions, it was found that plasma-induced OH* signal size and intensity increased with higher in-cylinder pressures albeit with shorter lifetime and lower breakdown consistency.