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Simple tests were performed to investigate the operating characteristics of zirconia galvanic cells (lambda sensors) in automotive closed loop “three-way” emission control systems. Commercially available cells were exposed to typical gaseous components of exhaust gas mixtures. The voltages generated by the cells were at their maximum values when hydrogen, and, in some instances, carbon monoxide, was available for reaction with atmospheric oxygen that migrated through the cells' ceramic thimbles in ionic form. This dependence of galvanic activity on the availability of these particular reducing agents indicated that the cells were voltaic devices which operated as oxidation/reduction reaction cells, rather than simple oxygen concentration cells.

The Schatz Heat Battery stores excess heat energy from the engine cooling system during vehicle operation. This excess energy may be returned to the coolant upon the ensuing cold start, shortening the engine warm-up period and decreasing cold start related emissions of unburned fuel and carbon monoxide (CO). A Heat Battery was evaluated on a test vehicle to determine its effect on unburned fuel emissions, CO emissions, and fuel economy over the cold start portion (Bag 1) of the Federal Test Procedure (FTP) at 24°C and -7°C ambient conditions. The Heat Battery was mounted in a vehicle fueled alternately with indolene clear (unleaded gasoline) and M85 high methanol blend fuels. Several Heat Battery/coolant flow configurations were evaluated to determine which would result in lowest cold start emissions.

A modified constant volume sampling (CVS) system has been used to sample fugitive hydrocarbon (HC) emissions to determine whether such systems can help identify excess vehicular HC sources, such as leaking gas caps. The approach was successful in distinguishing tightly sealed, marginally leaking and grossly leaking caps. The technique may be useful in motor vehicle inspection and maintenance (I/M) facilities as a less intrusive alternative to techniques requiring pressurization of the fuel system.

A simple, inexpensive, critical flow blender has been developed for filling a tedlar bag with controllable concentrations of HC, NOx, CO2, and CO gases at levels encountered in automobile emissions testing. According to a daily schedule, a technician takes the bag to all analyzer sites in the laboratory for analysis. The concentrations indicated by each site are compared to the overall averages. The results are stored in a computerized data base from which control charts, statistical analyses, and interpretations of significant differences among test sites can be made. The precision, accuracy, and statistical interpretations of the data are discussed.

The application of resistive materials as part of an exhaust emission control system is presented and discussed. The importance of cold start emissions is emphasized, and results are presented from experiments conducted with two different conductive materials. Most of the testing was conducted using methanol as the fuel, although some tests were run using gasoline-fueled vehicles.