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Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Fuel wall impingement commonly occurs in small-bore diesel engines. Particularly during engine starting, when wall temperatures are low, the evaporation rate of fuel film remaining from previous cycles plays a significant role in the autoignition process that is not fully understood. Pre-injection chemiluminescence (PIC), resulting from low-temperature oxidation of evaporating fuel film and residual gases, was measured over 3200 μsec intervals at the end of the compression strokes, but prior to fuel injection during a series of starting sequences in an optical diesel engine. These experiments were conducted to determine the effect of this parameter on combustion phasing and were conducted at initial engine temperatures of 30, 40, 50 and 60°C, at swirl ratios of 2.0 and 4.5 at 1000 RPM. PIC was determined to increase and be highly correlated with combustion phasing during initial cycles of the starting sequence.

Lithium-ion polymer battery has been widely used for vehicle onboard electric energy storage ranging from 12V SLI (Starting, Lighting, and Ignition), 48V mild hybrid electric, to 300V battery electric vehicle. Formulation on cell parameters acquired from minimum numbers of experiments, the modeling and simulation could be an effective approach in predicting battery performance, thermal effectiveness, and degradation. This paper describes the modeling, simulation, and validation of Lithium-Nickel-Manganese-Cobalt-Oxide (LiNiMnCoO2) based cell with 3.6V nominal voltage and 20Ah capacity. Constant current 20A, 40A, 60A, and 80A discharge tests are conducted in the computer-controlled cycler and temperature chamber. Discharging voltage curves and cell surface temperature distributions are recorded in each discharging test. A three-dimensional cell model is constructed in the COMSOL multi-physics platform based on the cell parameters.

Use of ethanol as gasoline replacement can contribute to the reduction of nitrogen oxide (NOx) and carbon oxide (CO) emissions. Depending on ethanol production, significant reduction of greenhouse-gas emissions is possible. Concentration of certain species, such as unburned ethanol and acetaldehyde in the engine-out emissions are known to rise when ratio of ethanol to gasoline increases in the fuel. This research explores on hydrous ethanol fueled port-fuel injection (PFI) spark ignition (SI) engine emissions that contribute to photochemical formation of ozone, or so-called ozone precursors and the precursor of peroxyacetyl nitrates (PANs). The results are compared to engine operation on gasoline. Concentration obtained by FTIR gas analyzer, and mass-specific emissions of formaldehyde (HCHO), acetaldehyde (MeCHO) and methane (CH4) under two engine speed, four load and two spark advance settings are analyzed and presented.

Reactivity Controlled Compression Ignition (RCCI) is an approach to increase engine efficiency and lower engine-out emissions by using in-cylinder stratification of fuels with differing reactivity (i.e., autoignition characteristics) to control combustion phasing. Stratification can be altered by varying the injection timing of the high-reactivity fuel, causing transitions across multiple regimes of combustion. When injection is sufficiently early, combustion approaches a highly-premixed autoignition regime, and when it is sufficiently late it approaches more mixing-controlled, diesel-like conditions. Engine performance, emissions, and control authority over combustion phasing with injection timing are most favorable in between, within the RCCI regime.

Fast and accurate characterization of stability regions and operational range with respect to pull-in voltage and displacement is critical in the design and development of MEMS resonators and switches. This paper presents a mathematical and computational procedure for modeling and analysis of static and dynamic instabilities of capacitive microdevices employing resonant microbeams. The mathematical model consists of a nonlinear microbeam under distributed electrostatic actuation and squeeze film damping. The coupled system is described by the nonlinear beam equation and a modified compressible Reynolds equation to account for the rarefied gas in the narrow gap between the microbeam and substrate. The Differential Quadrature Method (DQM) is used to discretize partial differential equations of motion and solve for static deflection, natural frequencies, static pull-in voltage, and quality factors for various encapsulation air pressures and applied DC voltages.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.

This study evaluates the performance of an indirect injection (IDI) diesel engine fueled with cotton seed biodiesel while assessing the engine's multi-fuel capability. Millions of tons of cotton seeds are available in the south of the US every year and approximately 10% of oil contained in the seeds can be extracted and transesterified. An investigation of combustion, emissions, and efficiency was performed using mass ratios of 20-50% cotton seed biodiesel (CS20 and CS50) in ultra-low sulfur diesel #2 (ULSD#2). Each investigation was run at 2400 rpm with loads of 4.2 - 6.3 IMEP and compared to the reference fuel ULDS#2. The ignition delay ranged in a narrow interval of 0.8-0.97ms across the blends and the heat release rate showed comparable values and trends for all fuel blends. The maximum volume averaged cylinder temperature increased by approximately 100K with each increase in 1 bar IMEP load but the maximum remained constants across the blends.

Several mechanisms are discussed to understand the particulate matter (PM) characterization in a high speed, direct injection, single cylinder diesel engine using low sulfur diesel fuel. This includes their formation, size distribution and number density. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios, therefore covering both conventional and low temperature combustion regimes. A micro dilution tunnel was used to immediately dilute a small part of the exhaust gases by hot air. A Scanning Mobility Particle Sizer (SMPS) was used to measure the particulate size distribution and number density. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the root cause of PM characterization and their relationship with the combustion process under different operating conditions.

One of the most challenging problems in diesel engines is to reduce unburned HC emissions that appear as (white smoke) during cold starting. In this paper the research is carried out on a 4-cylinder diesel engine with a common rail fuel injection system, which is able to deliver multiple injections during cold start. The causes of combustion failure at lower temperature limits are investigated theoretically by considering the rate of heat release. The results of this clearly indicate that in addition to low cranking engine speed, heat transfer and blow-by losses at lower ambient temperatures, fuel injection events would contribute to the failure of combustion. Also, combustion failure takes place when the compression temperature is lower than some critical value. Based on these results, split-main injection strategy was applied during engine cold starting and validated by experiments in a cold room at lower ambient temperatures.

Several mechanisms are discussed to understand the formation of both regulated and unregulated emissions in a high speed, direct injection, single cylinder diesel engine using low sulphur diesel fuel. Experiments were conducted over a wide range of injection pressures, EGR rates, injection timings and swirl ratios. The regulated emissions were measured by the standard emission equipment. Unregulated emissions such as aldehydes and ketones were measured by high pressure liquid chromatography and hydrocarbon speciation by gas chromatography. Particulate mass was measured with a Tapered Element Oscillating Microbalance (TEOM). Analysis was made of the sources of different emission species and their relationship with the combustion process under the different operating conditions. Special attention is given to the low temperature combustion (LTC) regime which is known to reduce both NOx and soot. However the HC, CO and unregulated emissions increased at a higher rate.

The short NiTi fiber-reinforced NiTi/Al6061-SiC composite was recently developed through the U.S. Army SBIR Phase-II program [1]. The objectives of this project are to use short NiTi fiber reinforcement to induce compressive stress through shape memory effect, to use silicon carbide (SiC) particulate reinforcement to enhance the mechanical properties of the aluminum matrix, to gain fundamental knowledge of short NiTi fiber-reinforced aluminum matrix composite, and eventually to improve fatigue resistance, impact damage tolerance and fracture toughness of the composite. The fatigue life, damage and fracture behavior of TiNi/Al6061-SiC, TiNi/Al6061, Al6061-SiC composites as well as monolithic Al6061 alloy were investigated under fully reversed cyclic loading. It was found that fatigue life of NiTi/Al6061-SiC composite, in term of the cycles, increased by two orders of magnitude, compared to monolithic Al6061 alloy

This paper presents an experimental investigation conducted to determine the parameters that control the behavior of autoignition in a small-bore, single-cylinder, optically-accessible diesel engine. Depending on operating conditions, three types of autoignition are observed: a single ignition, a two-stage process where a low temperature heat release (LTHR) or cool flame precedes the main premixed combustion, and a two-stage process where the LTHR or cool flame is separated from the main heat release by an apparent negative temperature coefficient (NTC) region. Experiments were conducted using commercial grade low-sulfur diesel fuel with a common-rail injection system. An intensified CCD camera was used for ultraviolet imaging and spectroscopy of chemiluminescent autoignition reactions under various operating conditions including fuel injection pressures, engine temperatures and equivalence ratios.

The focus of this study is to determine the effect of using B-20 (a blend of 20% soybean methyl ester biodiesel and 80% ultra low sulfur diesel fuel) on the combustion process, performance and exhaust emissions in a High Speed Direct Injection (HSDI) diesel engine equipped with a common rail injection system. The engine was operated under simulated turbocharged conditions with 3-bar indicated mean effective pressure and 1500 rpm engine speed. The experiments covered a wide range of injection pressures and EGR rates. The rate of heat release trace has been analyzed in details to determine the effect of the properties of biodiesel on auto ignition and combustion processes and their impact on engine out emissions. The results and the conclusions are supported by a statistical analysis of data that provides a quantitative significance of the effects of the two fuels on engine out emissions.

Digital human modeling (DHM) progress worldwide will be much faster and cohesive if the diverse community now developing simulations has a global blueprint for DHM, and is able to work together efficiently. DHM developers and users can save time by building on each other's work. This paper highlights a panel discussion on DHM goals and strategic plans for the next decade to begin formulating the international blueprint. Four subjects are chosen as the starting points: (1) moving DHM into the public safety and internet arenas, (2) role of DHM in computer assisted surgery and automotive safety, (3) DHM in defense applications, and (4) DHM to improve workplace ergonomics.

The objective of this work is to develop a strategy to reduce the penalties in the diesel engine performance, fuel economy and HC and CO emissions, associated with the operation in the low temperature combustion regime. Experiments were conducted on a research high speed, single cylinder, 4-valve, small-bore direct injection diesel engine equipped with a common rail injection system under simulated turbocharged conditions, at IMEP = 3 bar and engine speed = 1500 rpm. EGR rates were varied over a wide range to cover engine operation from the conventional to the LTC regime, up to the misfiring point. The injection pressure was varied from 600 bar to 1200 bar. Injection timing was adjusted to cover three different LPPCs (Location of the Peak rate of heat release due to the Premixed Combustion fraction) at 10.5° aTDC, 5 aTDC and 2 aTDC. The swirl ratio was varied from 1.44 to 7.12. Four steps are taken to move from LTC to ALTC.

Engine-out HC emissions were investigated during cold and hot starts. The tests were conducted at room temperature, on a new Chrysler 2.4-L, 4-cylinder, 16-valve, DOHC, multipoint-port-fuel-injection gasoline engine. Real time engine-out HC emissions were measured using Cambustion Fast Response Flame Ionization Detector (FRFID). Sources of unburned hydrocarbon emissions were discussed in details. Unburned hydrocarbons emitted during the cold-start were much higher than the hot-start. Cylinder-to-cylinder variation was investigated. A fuel inventory program was used to characterize total injected fuel, burned fuel, unburned HC, and fuel unaccounted for (mainly accumulated fuel in the engine system and CO). A fuel interrupt test was run to examine the possibility of burning the leftover fuel after the fuel shut-off. The contribution of the cold and hot start modes in engine-out HC emissions was determined.

As diesel emission regulations continue to increase, the use of exhaust aftertreatment systems containing, for example the diesel oxidation catalyst (DOC) and diesel particulate filter (DPF) will become necessary in order to meet these stringent emission requirements. The addition of a DOC and DPF in conjunction with utilizing biodiesel fuels requires extensive research to study the implications that biodiesel blends have on emissions as well as to examine the effect on aftertreatment devices. The proceeding work discusses results from a 2006 VM Motori four-cylinder 2.8L direct injection diesel engine coupled with a diesel oxidation catalyst and catalyzed diesel particulate filter. Tests were done using ultra low sulfur diesel fuel blended with 20% choice white grease biodiesel fuel to evaluate the effects of biodiesel emission products on the performance and effectiveness of the aftertreatment devices and the effect of low temperature combustion modes.