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Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.

The study measured Mass Air Flow, (MAF), Manifold Absolute Pressure, (MAP), and emissions of NO and soot during fourteen transients of speed and load, representative of the Extra Urban Drive Cycle (EUDC). The tests were conducted on a typical passenger car/light-duty truck powertrain (a turbocharged common-rail diesel engine, of in-line 4-cylinder configuration). The objective was to compare NO and soot with corresponding steady-state emission results and propose an engine measurement methodology that will potentially quantify deviation (i.e. deterioration with respect to steady state optimum) in emissions of NO and soot during transients. Comparison between steady state, quasi-steady-states (defined later in the paper) and transients indicated that discrete quasi-steady-state engine operation, can be used for accurate prediction of transient emissions of NO and soot.

Prior technical work by various OEMs and lubricant formulators has identified lubricant-derived phosphorus as a key element capable of significantly reducing the efficiency of modern emissions control systems of gasoline-powered vehicles ( 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ). However, measuring the exact magnitude of the detriment is not simple or straightforward exercise due to the many other sources of variation which occur as a vehicle is driven and the catalyst is aged ( 1 ). This paper, the second one in the series of publications, examines quantitative sets of results generated using various vehicle and exhaust catalyst testing methodologies designed to follow the path of lubricant-derived phosphorous transfer from oil sump to exhaust catalytic systems ( 1 ).

A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.

Two major barriers to wider use of ethanol as an engine fuel are ethanol's low heating value per volume relative to gasoline and higher hydrocarbon emissions at startup. Ethanol provides about one-third lower fuel economy than gasoline on a volumetric basis if the two fuels are utilized with equal efficiency, making ethanol less attractive to consumers. In addition, it is difficult to meet emissions standards such as SULEV when using E85 or hydrous ethanol, because ethanol's low volatility and high heat of vaporization compared to gasoline result in incomplete combustion when the engine is cold. A catalyst consisting of a copper-plated nickel sponge has recently been developed that enables ethanol to be reformed at around 300°C to a mixture of hydrogen (H₂), carbon monoxide (CO), and methane (CH₄). This low reforming temperature enables heat to be supplied from the engine exhaust.

This paper deals with experimental study of in-cylinder tumble flows in a single-cylinder, four-stroke, two-valve internal combustion engine using a pentroof-offset-bowl piston under non-reacting conditions with four intake manifold orientations at an engine speed of 1000 rev/min., during suction and compression strokes using particle image velocimetry. Two-dimensional in-cylinder tumble flow measurements and analysis are carried out in combustion space on a vertical plane passing through cylinder axis. Ensemble average velocity vectors are used to analyze the tumble flows. Tumble ratio (TR) and average turbulent kinetic energy (TKE) are evaluated and used to characterize the tumble flows. From analysis of results, it is found that at end of compression stroke, 90° intake manifold orientation shows an improvement in TR and TKE compared other intake manifold orientations considered.

Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.

A dilute spark-ignited engine concept has been developed as a potential low cost competitor to diesel engines by Southwest Research Institute (SwRI), with a goal of diesel-like efficiency and torque for light- and medium-duty applications and low-cost aftertreatment. The targeted aftertreatment method is a traditional three-way catalyst, which offers both an efficiency and cost advantage over typical diesel aftertreatment systems. High levels of exhaust gas recirculation (EGR) have been realized using advanced ignition systems and improved combustion, with significant improvements in emissions, efficiency, and torque resulting from using high levels of EGR. The primary motivation for this work was to understand the impact high levels of EGR would have on particulate matter (PM) formation in a port fuel injected (PFI) engine. While there are no proposed regulations for PFI engine PM levels, the potential exists for future regulations, both on a size and mass basis.

Prior work by various OEMs has identified the ability of phosphorus-containing compounds to interfere with the efficiency of modern emissions control systems utilized by gasoline-powered vehicles. Considering the growing societal concerns about ecological effects of exhaust emissions, greenhouse gas emissions and related global climatic changes, it becomes desirable to examine the effect of reduced phosphorous (P) deposits in various vehicle makes, models and types of service, over the lifetime of a vehicle's operation. This paper assesses advantages and disadvantages of various methods to examine the path of P transfer throughout exhaust catalytic systems. Test types discussed include examples of bench testing focusing on catalyst compatibility, dyno mileage accumulation and field trial examinations.

Regarding the strongly growing two-wheeler market fuel economy, price and emission legislations are in focus of current development work. Fuel economy as well as emissions can be improved by introduction of engine management systems (EMS). In order to provide the benefits of an EMS for low cost motorcycles, efforts are being made at BOSCH to reduce the costs of a port fuel injection (PFI) system. The present paper describes a method of how to reduce the number of sensors of a PFI system by the use of sophisticated software functions based on high-resolution engine speed evaluation. In order to improve the performance of a system working without a MAP-sensor (manifold air pressure sensor) an air charge feature (ACFn) based on engine speed is introduced. It is shown by an experiment that ACFn allows to detect and adapt changes in manifold air pressure. Cross-influences on ACFn are analyzed by simulations and engine test bench measurements.

This study deals with reduced-order modeling of intake air dynamics in single-cylinder four-stroke naturally-aspirated spark-ignited engines without surge tanks. It provides an approximate calculation method for embedded micro computers to estimate intake manifold pressures in real time. The calculation method is also applicable to multi-cylinder engines with individual throttle bodies since the engines can be equated with parallelization of the single-cylinder engines. In this paper, we illustrate the intake air dynamics, describe a method to estimate the intake manifold pressures, and show experimental results of the method.

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at λ=0.96 for nearly all conditions studied. At the λ=0.96 condition, HC emissions were relatively minimal, but CO emissions were significant.

Novel water management and reactant distribution strategies are critical to next generation polymer electrolyte membrane fuel cell systems (PEMFCs). Improving these strategies in PEMFCs leads to higher power density and reduced stack size for vehicle applications, which reduces weight and improves the price competitiveness of these systems. Interdigitated flow fields induce convective transport (cross flow) through the porous GDL between adjacent channels and are superior at water removal beneath land areas, which can lead to higher cell performance. However, the head loss due to flow, among other factors, may cause cross flow maldistribution of reactants down the channel. Such maldistribution may lead to areas of low or areas of excess cross flow. This, in turn, can cause areas of low oxygen concentration and water build up, and therefore higher pressure losses and uneven membrane hydration, all of which reduce overall cell performance.

Operation of spark-ignition (SI) engines with high levels of charge dilution through exhaust gas recirculation (EGR) achieves significant efficiency gains while maintaining stoichiometric operation for compatibility with three-way catalysts. Dilution levels, however, are limited by cyclic variability-including significant numbers of misfires-that becomes significant with increasing dilution. This variability has been shown to have both stochastic and deterministic components. Stochastic effects include turbulence, mixing variations, and the like, while the deterministic effect is primarily due to the nonlinear dependence of flame propagation rates and ignition characteristics on the charge composition, which is influenced by the composition of residual gases from prior cycles.

Driven by the desire to implement low-cost, high-efficiency NOx aftertreatment systems, such as Three Way Catalysts (TWC) or Lean NOx Traps (LNT), a novel 6-Stroke engine cycle was explored to determine the feasibility of implementing such a cycle on a compression ignition engine while continuing to deliver fuel efficiency. Fundamental questions regarding the abilities and trade-offs of a 6-stroke engine cycle were investigated for near-stoichiometric and lean operation. Experiments were performed on a single-cylinder 15-liter (equivalent) research engine equipped with flexible valvetrain and fuel injection systems to allow direct comparison between 4-stroke and 6-stroke performance across multiple hardware configurations. 1-D engine simulations with predictive combustion models were used to support, iterate on, and explore the 6-stroke operation in conjunction with the experiments.

Transport limitations inside the porous washcoat layer have an important influence in the light-off and overall conversions even in the case of relatively thin layers used in automotive three way catalysts (TWC). The porous structure of the washcoat layer is controlled at two levels: i) at the level of mesoporous structure, which can be determined by the use of specific synthesis techniques (e.g., sol-gel or pore-templating method), and ii) at the level of macroporous structure, which is influenced by the particle size distribution of mesoporous in a slurry that has undergone a specific thermal treatment. This paper investigates the influence of the washcoat structure in the performance of automotive TWC. Furthermore, the article presents a method that allows to quantify the magnitude of the reaction resistance (chemical kinetics), internal mass transfer resistance (washcoat diffusion), and external mass transfer resistance on the TWC conversions.

The Torque from an engine is a very critical parameter which controls the drivability of the vehicle, better torque availability at Partially Open Throttle (POT) condition improves drivability at city driving condition and better torque at Wide Open Throttle (WOT) condition improves cruising at highway driving condition, conventionally engine produces better torque at one particular operating condition leaving poor drivability at others. The Torque characteristics of an engine depends upon the volumetric efficiency of the engine. The volumetric efficiency of a naturally aspirated engine can be improved by tuning the intake manifold. With an overall improvement in volumetric efficiency throughout the engine operating conditions better torque curve can be achieved, which facilitates improved drivability.

The present paper describes a CAE analysis approach to evaluate the design of exhaust manifold of a turbo charged gasoline engine. It allows design engineers to identify structural weakness at the early stage or to find the root cause of exhaust manifold failures. A transient none-linear finite element method is used to calculate the plastic deformation and thermal mechanical behaviors of the exhaust manifold assembly during thermal shock cycles, which include rated speed full load, rated speed motored and idle speed conditions. A transient heat transfer simulation is performed to provide thermal boundary conditions for the nonlinear stress/strain analysis. The finite element model includes a part of cylinder head, exhaust manifold, gaskets, turbo charger housing, catalytic converter, brackets, bolts and nuts. The results show that plastic deformation is the main cause of manifold cracking and the manifold flange distortion causes the exhaust leakage.

The in-cylinder tumble intensity of GDI engine is crucial to combustion stability and thermal efficiency, required to be different for the different operation conditions. A new variable tumble system (VTS) applied to GDI engine was introduced to meet tumble ratio requirements in various situations. The transient gas exchange of four combustion systems all were investigated during both intake and compression strokes based on CFD simulation, namely (1) Case 1-Intake port B (with flap valve)/Spherical piston crown; (2) Case 2-Intake port B (without flap valve)/Spherical piston crown; (3) Case 3- Intake port A/Spherical piston crown; (4) Case 4-Intake port A/Dented piston crown. The simulated results of dynamic tumble ratio showed that during the whole intake process the dynamic tumble ratio of Case1 was obviously higher than other Cases with the same boundary conditions, and the maximum value was about 5∼6 times higher.

Cost reduction of engine management systems (EMS) for two-wheeler applications is the key to utilize their potentials compared to carburetor bikes regarding emissions, fuel economy and system robustness. In order to reduce the costs of a system with port fuel injection (PFI) Bosch is developing an EMS without a manifold air pressure (MAP) sensor. The pressure sensor is usually used to compensate for different influences on the air mass, which cannot be detected via the throttle position sensor (TPS) and mean engine speed. Such influences are different leakage rates of the throttle body and changing ambient conditions like air pressure. Bosch has shown in the past that a virtual sensor relying on model based evaluation of engine speed can be used for a detection of leakage air mass in idling to improve the pre-control of the air-fuel ratio. This provides a functionality which so far was only possible with an intake pressure sensor.