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Journal Article

ERRATUM: Study of Reproducibility of Pedal Tracking and Detection Response Task to Assess Driver Distraction

2015-04-14
2015-01-1388.01
1. On page 111, the authors have described a method to assess driver distraction. In this method, participants maintained a white square size on a forward display by using a game gas pedal of like in car-following situation. The size of the white square is determined by calculating the distance to a virtual lead vehicle. The formulas to correct are used to explain variation of acceleration of the virtual lead vehicle. The authors inadvertently incorporated old formulas they had used previously. In the experiments discussed in the article, the corrected formulas were used. Therefore, there is no change in the results. The following from the article:
Journal Article

Mechanical Behavior and Failure Mechanism of Nb-Clad Stainless Steel Sheets

2009-04-20
2009-01-1393
Because niobium-clad 304L stainless steel sheets are considered for use as bipolar plates in polymer electrolyte membrane (PEM) fuel cells, their mechanical behavior and failure mechanism are important to be examined. As-rolled and annealed specimens were tested in tension, bending and flattening. The effects of annealing temperature and time on the mechanical behavior and failure mechanism were investigated. Micrographic analyses of bent and flattened specimens showed that the as-rolled specimens have limited ductility and that the annealed specimens can develop an intermetallic layer of thickness of a few microns. The annealed specimens failed due to the breakage of intermetallic layer causing localized necking and the subsequent failure of Nb layer. The springback angles of the as-rolled and annealed specimens were also obtained from guided-bend tests.
Journal Article

Development and Testing of an Innovative Oil Condition Sensor

2009-04-20
2009-01-1466
In order to detect degradation of engine oil lubricant, bench testing along with a number of diesel-powered Ford trucks were instruments and tested. The purpose of the bench testing was primarily to determine performance aspects such as repeatability, hysteresis effects and so on. Vehicle testing was conducted by designing and installing a separate oil reservoir along with a circulation system which was mounted in the vicinity of the oil pan. An innovative oil sensor was directly installed on the reservoir which can measure five (5) independent oil parameters (viscosity, density, permittivity, conductance, temperature). In addition, the concept is capable of detecting the oil level continuously during normal engine operation. The sensing system consists of an ultrasonic transducer for the oil level detection as well as a Tuning Fork mechanical resonator for the oil condition measurement.
Journal Article

Hydrogen in Diesel Exhaust: Effect on Diesel Oxidation Catalyst Flow Reactor Experiments and Model Predictions

2009-04-20
2009-01-1268
Engine operating strategies typically geared towards higher fuel economy and lower NOx widely affect exhaust composition and temperature. These exhaust variables critically drive the performance of After Treatment (AT) components, and hence should guide their screening and selection. Towards this end, the effect of H2 level in diesel exhaust on the performance of a Diesel Oxidation Catalyst (DOC) was studied using flow reactor experiments, vehicle emission measurements and mathematical models. Vehicle chassis dynamometer data showed that exhaust from light-duty and heavy-duty diesel trucks contained very little to almost no H2 (FTP average CO/H2 ∼ 40 to 70) as compared to that of a gasoline car exhaust (FTP average CO/H2 ∼ 3). Two identical flow reactor experiments, one with H2 (at CO/H2 ∼ 3) and another with no H2 in the feed were designed to screen DOCs under simulated feed gas conditions that mimicked these two extremes in the exhaust H2 levels.
Journal Article

A Urea Decomposition Modeling Framework for SCR Systems

2009-04-20
2009-01-1269
Selective catalytic reduction (SCR) is allowing diesel engines to reach NOx emission levels which are unachievable in-cylinder. This technology is still evolving, and new catalyst formulations which provide higher performance and greater durability continue to be developed. Usually, their performance is measured on a flow reactor using ammonia as the reductant. However, in mobile applications a urea-water solution is used instead, and urea decomposition by thermolysis and hydrolysis provides the required ammonia to the catalyst. It is well known that urea decomposition is incomplete by the inlet face of the converter, and this is at least one reason why on-engine performance is generally lower than would be expected from reactor tests. Previous modeling of urea-water droplets has focused on developing detailed sub-models that can be implemented into computational fluid dynamics (CFD) codes.
Journal Article

Modeling the Emissions Control Performance of a Catalyzed Diesel Particulate Filter (CDPF) System for Light Duty Diesel Applications

2009-04-20
2009-01-1266
The use of catalyzed diesel particulate filter (CDPF) systems in light duty diesel (LDD) vehicles is becoming increasingly common. The primary functions of the system are to remove carbon monoxide (CO) and hydrocarbons (HC) from the vehicle exhaust stream, while simultaneously reducing the level of particulate matter (PM) emissions to ambient background levels. These systems can comprise either a separate diesel oxidation catalyst (DOC) and a downstream CDPF, or a single unit CDPF with the DOC functions incorporated within the CDPF. The single CDPF unit provides higher regeneration efficiency as it is located nearer to the engine and also cost benefits, as only a single unit is required compared to the alternative separate DOC and CDPF arrangement. A model describing the performance of the single unit CDPF for emissions control has been developed, with particular emphasis on achieving predictions of the CO and HC emissions over transient vehicle drive cycles.
Journal Article

Analysis of the Correlation Between Engine-Out Particulates and Local Φ in the Lift-Off Region of a Heavy Duty Diesel Engine Using Raman Spectroscopy

2009-04-20
2009-01-1357
The local equivalence ratio, Φ, was measured in fuel jets using laser-induced spontaneous Raman scattering in an optical heavy duty diesel engine. The measurements were performed at 1200 rpm and quarter load (6 bar IMEP). The objective was to study factors influencing soot formation, such as gas entrainment and lift-off position, and to find correlations with engine-out particulate matter (PM) levels. The effects of nozzle hole size, injection pressure, inlet oxygen concentration, and ambient density at TDC were studied. The position of the lift–off region was determined from OH chemiluminescence images of the flame. The liquid penetration length was measured with Mie scattering to ensure that the Raman measurement was performed in the gaseous part of the spray. The local Φ value was successfully measured inside a fuel jet. A surprisingly low correlation coefficient between engine-out PM and the local Φ in the reaction zone were observed.
Journal Article

Entrainment Waves in Diesel Jets

2009-04-20
2009-01-1355
Recent measurements in transient diesel jets have shown that fuel in the wake of the injection pulse mixes with ambient gases more rapidly than in a steady jet. This rapid mixing after the end of injection (EOI) can create fuel-lean regions near the fuel injector. These lean regions may not burn to completion for conditions where autoignition occurs after EOI, as is typical of low-temperature combustion (LTC) diesel engines. In this study, transient diesel jets are analyzed using a simple one-dimensional jet model. The model predicts that after EOI, a region of increased entrainment, termed the “entrainment wave,” travels downstream at twice the initial jet propagation rate. The entrainment wave increases mixing by up to a factor of three. This entrainment wave is not specific to LTC jets, but rather it is important for both conventional diesel combustion and LTC conditions.
Journal Article

Exhaust Valve & Valve Seat Insert – Development for an Industrial LPG Application

2009-05-13
2009-01-1602
Automotive engines are regularly utilized in the material handling market where LPG is often the primary fuel used. When compared to gasoline, the use of gaseous fuels (LPG and CNG) as well as alcohol based fuels, often result in significant increases in valve seat insert (VSI) and valve face wear. This phenomenon is widely recognized and the engine manufacturer is tasked to identify and incorporate appropriate valvetrain material and design features that can meet the ever increasing life expectations of the end-user. Alternate materials are often developed based on laboratory testing – testing that may not represent real world usage. The ultimate goal of the product engineer is to utilize accelerated lab test procedures that can be correlated to field life and field failure mechanisms, and then select appropriate materials/design features that meet the targeted life requirements.
Journal Article

1D Thermo-Fluid Dynamic Modeling of Reacting Flows inside Three-Way Catalytic Converters

2009-04-20
2009-01-1510
In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.
Journal Article

Reconstruction of Time-Resolved Vehicle Emissions Measurements by Deconvolution

2009-04-20
2009-01-1513
A thorough understanding of vehicle exhaust aftertreatment system performance requires time-resolved emissions measurements that accurately follow driving transients, and that are correctly time-aligned with exhaust temperature and flow measurements. The transient response of conventional gas analyzers is characterized by both a time delay and an attenuation of high-frequency signal components. The distortion that this imposes on transient emissions measurements causes significant errors in instantaneous calculations of aftertreatment system efficiency, and thus in modal mass analysis. This creates difficulties in mathematical modeling of emissions system performance and in optimization of powertrain control strategies, leading to suboptimal aftertreatment system designs. A mathematical method is presented which improves the response time of emissions measurements. This begins with development of a model of gas transport and mixing within the sampling and measurement system.
Journal Article

Cost and Fuel Efficient SCR-only Solution for Post-2010 HD Emission Standards

2009-04-20
2009-01-0915
A promising SCR-only solution is presented to meet post-2010 NOx emission targets for heavy duty applications. The proposed concept is based on an engine from a EURO IV SCR application, which is considered optimal with respect to fuel economy and costs. The addition of advanced SCR after treatment comprising a standard and a close-coupled SCR catalyst offers a feasible emission solution, especially suited for EURO VI. In this paper, results of a simulation study are presented. This study concentrates on optimizing SCR deNOx performance. Simulation results of cold start FTP and WHTC test cycles are presented to demonstrate the potential of the close-coupled SCR concept. Comparison with measured engine out emissions of an EGR engine shows that a close-coupled SCR catalyst potentially has NOx reduction performance as good as EGR. Practical issues regarding the use of an SCR catalyst in close-coupled position will be addressed, as well as engine and exhaust layout.
Journal Article

Evaluation of SCR Catalyst Technology on Diesel Particulate Filters

2009-04-20
2009-01-0910
Selective Catalytic Reduction (SCR) catalysts have been demonstrated as effective for controlling NOx emissions from diesel engines, maintaining high NOx conversion even after the extended high temperature exposure encountered in systems with active filter regenerations. As future diesel emission regulations are expected to be further reduced, packaging a large volume of SCR catalysts in diesel exhaust systems, along with DOC and particulate filter catalysts, will be challenging. One method to reduce the total volume of catalysts in diesel exhaust systems is to combine the SCR and DPF catalysts by coating SCR catalyst technology on particulate filters. In this work, engine evaluation of SCR coated filters has been conducted to determine the viability of the technology. Steady-state engine evaluations demonstrated that high NOx conversions can be achieved for SCR coated filters after high temperature oven aging.
Journal Article

SCR Catalyst Systems Optimized for Lightoff and Steady-State Performance

2009-04-20
2009-01-0901
A laboratory study was performed to optimize a zoned configuration of an iron (Fe) SCR catalyst and a copper (Cu) SCR catalyst in order to provide high NOx conversion at lean A/F ratios over a broad range of temperature for diesel and lean-burn gasoline applications. With an optimized space velocity of 8,300 hr-1, a 67% (by volume) Fe section followed by a 33% Cu section provided at least 80% NOx conversion from approximately 230°C to 640°C when evaluated with 500 ppm NO and NH3. To improve the lean lightoff performance of the SCR catalyst system during a cold start, a Cu SCR catalyst that was 1/4 as long as the rear Cu SCR catalyst was placed in front of the Fe SCR catalyst. When evaluated with an excess of NH3 (NH3/NO ratio of 2.2), the Cu+Fe+Cu SCR system had significantly improved lightoff performance relative to the Fe+Cu SCR system, although the front Cu SCR catalyst did decrease the NOx conversion at temperatures above 475°C by oxidizing some of the NH3 to N2 or NO.
Journal Article

The Poisoning and Desulfation Characteristics of Iron and Copper SCR Catalysts

2009-04-20
2009-01-0900
A laboratory study was performed to assess the effects of SO2 poisoning on the NOx conversion of iron (Fe) and copper (Cu) SCR catalysts. Thermally aged samples of the catalysts were poisoned with SO2 under lean conditions. At various times during the poisonings, the samples were evaluated for NOx conversion with NO and NH3 using lean temperature ramps. The low temperature NOx conversions of both catalysts decreased by 10 to 20% after 1 to 4 hours of poisoning but were stable with continued exposure to the SO2. The poisoned Cu SCR catalyst could be desulfated repeatedly with 5 minutes of lean operation at 600°C. Initially, the poisoned Fe SCR catalyst required 5 minutes of lean operation at 750°C to recover its maximum NOx conversion.
Journal Article

Treatment of Vehicle Emissions from the Combustion of E85 and Gasoline with Catalyzed Hydrocarbon Traps

2009-04-20
2009-01-1080
Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.
Journal Article

Metering Characteristics of a Closed Center Load - Sensing Proportional Control Valve

2009-10-06
2009-01-2850
The investigation of the flow through the metering section of hydraulic components plays a fundamental role in the design and optimization processes. In this paper the flow through a closed center directional control valve for load -sensing application is studied by means of a multidimensional CFD approach. In the analysis, an open source fluid-dynamics code is used and both cavitation and turbulence are accounted for in the modeling. A cavitation model based on a barotropic equation of state and homogeneous equilibrium assumption, including gas absorption and dissolution in the liquid medium, is adopted and coupled to a two equation turbulence approach. Both direct and inverse flows through the metering section of the control valve are investigated, and the differences in terms of fluid - dynamics behavior are addressed In particular, the discharge coefficient, the recirculating regions, the flow acceleration angle and the pressure and velocity fields are investigated and compared.
Journal Article

Performance of a Fuel Reformer, LNT and SCR Aftertreatment System Following 500 LNT Desulfation Events

2009-10-06
2009-01-2835
An advanced exhaust aftertreatment system is characterized following end-of-life catalyst aging to meet final Tier 4 off-highway emission requirements. This system consists of a fuel dosing system, mixing elements, fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF), and a selective catalytic reduction (SCR) catalyst. The fuel reformer is used to generate hydrogen (H2) and carbon monoxide (CO) from injected diesel fuel. These reductants are used to regenerate and desulfate the LNT catalyst. NOx emissions are reduced using the combination of the LNT and SCR catalysts. During LNT regeneration, ammonia (NH3) is intentionally released from the LNT and stored on the downstream SCR catalyst to further reduce NOx that passed through the LNT catalyst. This paper addresses system durability as the catalysts were aged to 500 desulfation events using an off-highway diesel engine.
Journal Article

Development of Flax Fibre Reinforced Biocomposites for Potential Application for Automotive Industries

2009-10-06
2009-01-2867
{ Natural fibre-reinforced composite has the potential to replace current materials used for automotive industrial applications. Oilseed flax fibre could be used as reinforcement for composites because it is readily available, environmentally friendly and possesses good mechanical properties. In this research, oilseed flax fibre reinforced-LLDPE and -HDPE biocomposites were developed through extrusion and injection molding. The flax fibre was chemically treated to improve the bond between the fibre and polymer. Flax fibre was mixed with low linear density polyethylene (LLDPE) and high density polyethylene (HDPE) with fibre content varying from 10 to 30% by mass and processed by extrusion and injection molding to biocomposites. The mechanical properties, surface properties, and thermal properties of biocomposites were measured to analyze the treatment and processing effect and to compare the effect of different flax fibre concentrations on the biocomposites.
Journal Article

Development of Flax oil-based Biopolymer for Biocomposites

2009-10-06
2009-01-2869
Flax oil is the main goal of growing flaxseed. Flax oil has been used for nutrition, food, paint binder, putty, and wood finish. However, synthetic resin from flax oil has not been developed. In this paper we will develop a biopolymer derived from flax oil and the goal is to use it as a resin to produce a viable, biodegradable composite using natural fiber as reinforcement. First, the functionalization of the triglyceride group of the flax oil fatty acids with polymerizable chemical groups was studied. The triglyceride molecule of flax oil was epoxidized by the reaction of double bonds in the fatty acid with a peroxy acid (formic acid) to get epoxidized oil; the epoxidized oil was then reacted with ethylenically substituted carboxylic acid (acrylic acid) to form acrylated epoxidized flax oil. Polymer resins were prepared from flax oil by blending acrylated epoxidized flax oil with styrene and a free radical initiator.
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