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Nissan Motor Company has recently released the �Nissan Green Program 2016� which is a six-year action plan embodying the company�s environmental philosophy: Symbiosis of People, Vehicles and Nature. One of the key activities of this Program is the successful penetration of Zero-Emission Vehicles into the market which includes electric vehicle (EV) cumulative sales of 1.5M units with our Alliance partner Renault, introduction of a fuel cell electric vehicle (FCEV) into the market, taking a global leadership in supplying batteries for electric drive and creating zero-emission societies. This presentation will highlight some of these key activities. Presenter Kev Adjemian, Nissan Technical Center NA

This presentation will introduce the overall goals of the EcoCAR competition in brief, and will go into the third and final year of the competition in detail. The final year of competition saw teams refining and testing their student-built advanced technology vehicles including hybrids, plug-in hybrids, hydrogen fuel cell PHEVs and one battery electric. Important events, such as the Spring Workshop chassis dynamometer testing event at the U.S. Environmental Protection agency, as well as significant competition results, such as vehicle performance, consumer acceptability and efficiency will be presented. Presenter Patrick Walsh

A 2007 Cummins ISL 8.9L direct-injection common rail diesel engine rated at 272 kW (365 hp) was used to load the filter to 2.2 g/L and passively oxidize particulate matter (PM) within a 2007 OEM aftertreatment system consisting of a diesel oxidation catalyst (DOC) and catalyzed particulate filter (CPF). Having a better understanding of the passive NO2 oxidation kinetics of PM within the CPF allows for reducing the frequency of active regenerations (hydrocarbon injection) and the associated fuel penalties. Being able to model the passive oxidation of accumulated PM in the CPF is critical to creating accurate state estimation strategies. The MTU 1-D CPF model will be used to simulate data collected from this study to examine differences in the PM oxidation kinetics when soy methyl ester (SME) biodiesel is used as the source of fuel for the engine.

A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.

This technical paper collection covers the complete particulate filter system. There are papers covering the DOC aging as well as the effect of high sulfur fuel on the DOC. A couple of papers study the effect of ash accumulation and two papers cover a novel new asymmetric cell design and modeling of this new design. Finally we have a paper on gasoline particulate filters.

This technical paper collection will focus on ‘Advances in NOx Reduction Technology’. The topics covered will include: new materials for lean NOx traps (LNT) and Selective Catalytic Reduction (SCR); system integration and durability; advances in NOx catalyst substrates, novel reductants and mixing designs.

Abstract Catalytic converters, a primary component in most automotive emissions control systems, do not function well until they are heated substantially above ambient temperature. As the primary energy for catalyst heating comes from engine exhaust gases, plug-in hybrid electric vehicles (PHEVs) that have the potential for short and infrequent use of their onboard engine may have limited energy available for catalytic converter heating. This article presents a comparison of multiple hybrid supervisory control strategies to determine the ability to avoid engine cold starts during a blended charge-depleting propulsion mode. Full vehicle and catalytic converter simulations are performed in parallel with engine dynamometer testing in order to examine catalyst temperature variations during the course of the US06 City drive cycle. Emissions and energy consumption (E&EC) calculations are also performed to determine the effective number of engine starts during the drive cycle.

In this work a detailed model to simulate the transient behavior of catalytic converters is presented. The model is able to predict the unsteady and reacting flows in the exhaust ducts, by solving the system of conservation equations of mass, momentum, energy and transport of reacting chemical species. The en-gine and the intake system have not been included in the simulation, imposing the measured values of mass flow, gas temperature and chemical composition as a boundary condition at the inlet of the exhaust system. A detailed analysis of the diffusion stage triggering is proposed along with simplifications of the physics, finalized to the reduction of the calculation time. Submodels for water condensation and its following evaporation on the monolith surface have been taken into account as well as oxygen storage promoted by ceria oxides.

Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.

A well balanced use of alternative fuels is an important objective for a sustainable development of individual transportation worldwide. Several countries have objectives to substitute a part of the energy of traffic by ethanol as the renewable energy source. Investigations of limited and unregulated emissions of two 2-S scooters with gasoline-ethanol blend fuels have been performed in the present work according to the measuring procedures, which were established in the previous research in the Swiss Scooter Network (since 2000). The investigated fuels contained ethanol (E), in the portion of 5, 10, 15 and 20% by volume. The investigated 2-S scooters represented a newer and an older 2-stroke technology with carburettor. The newer one was investigated with and without catalyst and the older one only in the original state without catalyst.

An experimental study was performed to develop a more fundamental understanding of the effects of secondary air injection (SAI) on exhaust gas emissions and catalyst light-off characteristics during cold start of a modern SI engine. The effects of engine operating parameters and various secondary air injection strategies such as spark retardation, fuel enrichment, secondary air injection location and air flow rate were investigated to understand the mixing, heat loss, and thermal and catalytic oxidation processes associated with SAI. Time-resolved HC, CO and CO₂ concentrations were tracked from the cylinder exit to the catalytic converter outlet and converted to time-resolved mass emissions by applying an instantaneous exhaust mass flow rate model. A phenomenological model of exhaust heat transfer combined with the gas composition analysis was also developed to define the thermal and chemical energy state of the exhaust gas with SAI.

This study aims to identify the factors that control particulate matter (PM) formation and size distribution in direct-injection spark-ignition (DISI) engines. The test engine used for this research was a 1.6 litre, wall-guided DISI, turbocharged, intercooled, in-line 4 cylinder, Euro IV engine. The exhaust sampling point was before the catalytic converter, i.e. engine-out emissions were measured. The first part of this paper investigates the characteristics of PM number and size distribution of DISI and throttle body injected (TBI) engines. The second part investigates the effect of combustion characteristics of DISI engines on the number of 5nm and 10nm (nucleation) and 200nm (accumulation) PM. A statistical analysis of the coefficient of variance (COV) of the maximum rate of pressure rise (RPmax) over 100 cycles was performed against the COV of 5nm, 10nm and 200nm total particle number.

The application of accelerated catalyst aging procedures on an engine dynamometer test bed for the purpose of demonstrating catalyst durability is examined. A proof-of-principle approach is followed using catalysts from vehicles certified to U.S. Tier 2 Bin 4 and California SULEV 2 levels. Accelerated durability demonstration methods based upon conventional fuel cut cycles were employed to age catalysts to levels predicted by quantification of thermal catalyst bed severity on the Standard Road Cycle (SRC) relative to the fuel cut aging cycle using the Bench Aging Time (BAT) equation. Emissions deterioration on the accelerated aging cycle is compared to the automobile manufacturers' certification values and to whole vehicle emissions performance results from several different in-use vehicle fleets. The influence of technology on whole vehicle emissions levels and deterioration characteristics is also evaluated.

In recognizing the potential for large, damaging impacts from climate change, California enacted Executive Order S-03-05, requiring a reduction in statewide greenhouse gas (GHG) emissions to 80% below 1990 levels by 2050. Given that the transportation light-duty vehicle (LDV) segment accounts for 28% of the state's GHG emissions today, it will be difficult to meet the 2050 goal unless a portfolio of near-zero carbon transportation solutions is pursued. Because it takes decades for a new propulsion system to capture a large fraction of the passenger vehicle market due to vehicle fleet turn-over rates, it is important to accelerate the introduction of these alternatives to ensure markets enter into early commercial volumes (10,000s) between 2015 and 2020. This report summarizes the results and conclusions of a modeling exercise that simulated GHG emissions from the LDV sector to 2050 in California.

This review summarizes the latest developments in diesel emissions regarding regulations, engines, NOx (nitrogen oxides) control, particulate matter (PM) reductions, and hydrocarbon (HC) and CO oxidation. Regulations are advancing with proposals for PN (particle number) regulations that require diesel particulate filters (DPFs) for Euro VI in 2013-14, and SULEV (super ultra low emission vehicle) fleet average light-duty (LD) emissions likely to be proposed in California for ~2017. CO₂ regulations will also impact diesel engines and emissions, probably long into the future. Engine technology is addressing these needs. Heavy-duty (HD) research engines show 90% lower NOx at the same PM or fuel consumption levels as a reference 2007 production engine. Work is starting on HD gasoline engines with promising results. In light duty (LD), engine downsizing is progressing and deNOx is emerging as a fuel savings strategy.

Exhaust and evaporative emissions systems have been developed to match the characteristics and usage of the Toyota THS II plug-in hybrid electric vehicle (PHEV). Based on the commercially available Prius, the Toyota PHEV features an additional external charging function, which allows it to be driven as an electric vehicle (EV) in urban areas, and as an hybrid electric vehicle (HEV) in high-speed/high-load and long-distance driving situations. To reduce exhaust emissions, the conventional catalyst warm up control has been enhanced to achieve emissions performance that satisfies California's Super Ultra Low Emissions Vehicle (SULEV) standards in every state of battery charge. In addition, a heat insulating fuel vapor containment system (FVS) has been developed using a plastic fuel tank based on the assumption that such a system can reduce the diffusion of vapor inside the fuel tank and the release of fuel vapor in to the atmosphere to the maximum possible extent.

Today turbo-diesel powertrains offering low fuel consumption and good low-end torque comprise a significant fraction of the light-duty vehicle market in Europe. Global CO₂ regulation and customer fuel prices are expected to continue providing pressure for powertrain fuel efficiency. However, regulated emissions for NO and particulate matter have the potential to further expand the incremental cost of diesel powertrain applications. Vehicle segments with the most cost sensitivity like compacts under 1400 kg weight look for alternatives to meet the CO₂ challenge but maintain an attractive customer offering. In this paper the concepts of downsizing and downspeeding gasoline engines are explored while meeting performance needs through increased BMEP to maintain good driveability and vehicle launch dynamics. A critical enabler for the solution is adoption of gasoline direct injection (GDi) fuel systems.

We investigated the catalytic performance of a porous-structured paper coated with precious metals such as palladium (Pd) and others. A honeycomb-shaped paper catalyst was successfully produced by paper making techniques, which are often used in the friction material manufacturing process for clutch system and the following newly developed molding process. As a new catalyst on the paper, Pd supported on Mn-substituted lanthanum hexa-aluminate (LaMnAl₁₁O₁₉, magnetoplumbite, MPB) crystallites with appropriate surface area was prepared and the catalytic performance, such as exhaust purification ability, was assessed using a model gas containing HC (hydrocarbon), CO (carbon monoxide) and NO (nitrogen oxide) gas. The results showed that Pd/MPB did not deteriorate even after 180 h aging at 1000°C. We concluded that the MPB has good potential as a catalyst component material for internal combustion engines because of the high thermal stability.

At the engine restart, when the temperature of the catalytic converter is low, additional fuel consumption would be required to warm up the catalyst for controlling exhaust emission.The aim of this study is to find a thermally optimal way to reduce fuel consumption for the catalyst warm up at the engine restart, by improving the thermal retention of the catalytic converter in the cool down process after the previous trip. To make analysis of the thermal flow around the catalytic converter, a 2-D thermal flow model was constructed using the thermal network method. This model simulates the following processes: 1) heat conduction between the substrate and the stainless steel case, 2) heat convection between the stainless steel case and the ambient air, 3) heat convection between the substrate and the gas inside the substrate, 4) heat generation due to chemical reactions.

Modern exhaust systems contain not only a piping network to transport hot gas from the engine to the atmosphere, but also functional components such as the catalytic converter and turbocharger. The turbocharger is common place in the automotive industry due to their capability to increase the specific power output of reciprocating engines. As the exhaust system is a main heat source for the under body of the vehicle and the turbocharger is located within the engine bay, it is imperative that accurate surface temperatures are achieved. A study by K. Haehndel [1] implemented a 1D fluid stream as a replacement to solving 3D fluid dynamics of the internal exhaust flow. To incorporate the 3D effects of internal fluid flow, augmented Nusselt correlations were used to produce heat transfer coefficients. It was found that the developed correlations for the exhaust system did not adequately represent the heat transfer of the turbocharger.