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A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.

Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.

Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.

Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.

The study measured Mass Air Flow, (MAF), Manifold Absolute Pressure, (MAP), and emissions of NO and soot during fourteen transients of speed and load, representative of the Extra Urban Drive Cycle (EUDC). The tests were conducted on a typical passenger car/light-duty truck powertrain (a turbocharged common-rail diesel engine, of in-line 4-cylinder configuration). The objective was to compare NO and soot with corresponding steady-state emission results and propose an engine measurement methodology that will potentially quantify deviation (i.e. deterioration with respect to steady state optimum) in emissions of NO and soot during transients. Comparison between steady state, quasi-steady-states (defined later in the paper) and transients indicated that discrete quasi-steady-state engine operation, can be used for accurate prediction of transient emissions of NO and soot.

Prior technical work by various OEMs and lubricant formulators has identified lubricant-derived phosphorus as a key element capable of significantly reducing the efficiency of modern emissions control systems of gasoline-powered vehicles ( 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ). However, measuring the exact magnitude of the detriment is not simple or straightforward exercise due to the many other sources of variation which occur as a vehicle is driven and the catalyst is aged ( 1 ). This paper, the second one in the series of publications, examines quantitative sets of results generated using various vehicle and exhaust catalyst testing methodologies designed to follow the path of lubricant-derived phosphorous transfer from oil sump to exhaust catalytic systems ( 1 ).

The global use of biodiesel fuel blends derived from fatty acid methyl esters (FAME) is increasing; driven by legislation derived from political, economic and environmental factors. The presence of FAME biodiesel changes the operating environment of the engine and after treatment devices, affecting the performance characteristics and requirements of the lubricant. As part of a wider research project into the impact of biologically-sourced fuels on crankcase lubricant performance, this paper documents the impact of biodiesel on corrosion-related performance. The effect of FAME biodiesel on lubricant corrosion control and the differences in performance due to FAME source are described. Mechanistic studies into the corrosive nature of FAME are reported. Novel lubricant technologies tailored to control the negative impact of FAME in the crankcase are demonstrated.

Organic acid degradation products and other anions in engine oil were speciated by capillary electrophoresis (CE) and liquid chromatography-mass spectrometry (LCMS) with electrospray ionization. The sample preparation procedure involved selectively extracting the acids and other water soluble salts into 0.05M aqueous potassium hydroxide. Samples of engine-aged mineral oil and synthetic engine oil contained formic acid, acetic acid, and complex mixtures of fatty acid degradation products. CE analysis of formic acid, acetic acid and selected fatty acids is proposed as a new chemical analysis method for evaluating the condition of engine oil and for studying the effects of high temperature-high load (HTHL) oxidation. Because the overall pattern of CE peaks in the electropherogram changes with oil age or condition, CE-fingerprint (i.e., pattern recognition) techniques may also be useful for evaluating an aged oil's condition or remaining service life.

A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.

Two major barriers to wider use of ethanol as an engine fuel are ethanol's low heating value per volume relative to gasoline and higher hydrocarbon emissions at startup. Ethanol provides about one-third lower fuel economy than gasoline on a volumetric basis if the two fuels are utilized with equal efficiency, making ethanol less attractive to consumers. In addition, it is difficult to meet emissions standards such as SULEV when using E85 or hydrous ethanol, because ethanol's low volatility and high heat of vaporization compared to gasoline result in incomplete combustion when the engine is cold. A catalyst consisting of a copper-plated nickel sponge has recently been developed that enables ethanol to be reformed at around 300°C to a mixture of hydrogen (H₂), carbon monoxide (CO), and methane (CH₄). This low reforming temperature enables heat to be supplied from the engine exhaust.

This paper deals with experimental study of in-cylinder tumble flows in a single-cylinder, four-stroke, two-valve internal combustion engine using a pentroof-offset-bowl piston under non-reacting conditions with four intake manifold orientations at an engine speed of 1000 rev/min., during suction and compression strokes using particle image velocimetry. Two-dimensional in-cylinder tumble flow measurements and analysis are carried out in combustion space on a vertical plane passing through cylinder axis. Ensemble average velocity vectors are used to analyze the tumble flows. Tumble ratio (TR) and average turbulent kinetic energy (TKE) are evaluated and used to characterize the tumble flows. From analysis of results, it is found that at end of compression stroke, 90° intake manifold orientation shows an improvement in TR and TKE compared other intake manifold orientations considered.

Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.

A dilute spark-ignited engine concept has been developed as a potential low cost competitor to diesel engines by Southwest Research Institute (SwRI), with a goal of diesel-like efficiency and torque for light- and medium-duty applications and low-cost aftertreatment. The targeted aftertreatment method is a traditional three-way catalyst, which offers both an efficiency and cost advantage over typical diesel aftertreatment systems. High levels of exhaust gas recirculation (EGR) have been realized using advanced ignition systems and improved combustion, with significant improvements in emissions, efficiency, and torque resulting from using high levels of EGR. The primary motivation for this work was to understand the impact high levels of EGR would have on particulate matter (PM) formation in a port fuel injected (PFI) engine. While there are no proposed regulations for PFI engine PM levels, the potential exists for future regulations, both on a size and mass basis.

Prior work by various OEMs has identified the ability of phosphorus-containing compounds to interfere with the efficiency of modern emissions control systems utilized by gasoline-powered vehicles. Considering the growing societal concerns about ecological effects of exhaust emissions, greenhouse gas emissions and related global climatic changes, it becomes desirable to examine the effect of reduced phosphorous (P) deposits in various vehicle makes, models and types of service, over the lifetime of a vehicle's operation. This paper assesses advantages and disadvantages of various methods to examine the path of P transfer throughout exhaust catalytic systems. Test types discussed include examples of bench testing focusing on catalyst compatibility, dyno mileage accumulation and field trial examinations.

The authors have developed a measurement technique using a new digital telemeter which measures the piston secondary motion as ensuring high accuracy while under the operation. We applied this new digital telemeter to several measurements and analysis on the piston secondary motion that can cause piston noises, and here are some of the results from our measurement. We have confirmed that these piston motions vary by only several tenths of millimeter changes of the piston specifications such as the piston-pin offset and the center of gravity of the piston. As in other cases, we have found that a mere change of pressure in the crankcase or the amount of lubricating oil supplied on the cylinder bore varies the piston motion that may give effect on the piston noises.

This paper presents the comparison of two different approaches for crankcase structural analysis. The first approach is a conventional quasi-static simulation, which will not be detailed in this work and the second approach involves determining the dynamic loading generated by the crankshaft torsional, flexural and axial vibrations on the crankcase. The accuracy of this approach consists in the development of a robust mathematical model that can couple the dynamic characteristics of the crankshaft and the crankcase, representing realistically the interaction between both components. The methodology to evaluate these dynamic responses is referred to as hybrid simulation, which consists of the solution of the dynamics of an E-MBS (Elastic Multi Body System) coupled with consecutive FEA (Finite Element Analysis).

Regarding the strongly growing two-wheeler market fuel economy, price and emission legislations are in focus of current development work. Fuel economy as well as emissions can be improved by introduction of engine management systems (EMS). In order to provide the benefits of an EMS for low cost motorcycles, efforts are being made at BOSCH to reduce the costs of a port fuel injection (PFI) system. The present paper describes a method of how to reduce the number of sensors of a PFI system by the use of sophisticated software functions based on high-resolution engine speed evaluation. In order to improve the performance of a system working without a MAP-sensor (manifold air pressure sensor) an air charge feature (ACFn) based on engine speed is introduced. It is shown by an experiment that ACFn allows to detect and adapt changes in manifold air pressure. Cross-influences on ACFn are analyzed by simulations and engine test bench measurements.

This study deals with reduced-order modeling of intake air dynamics in single-cylinder four-stroke naturally-aspirated spark-ignited engines without surge tanks. It provides an approximate calculation method for embedded micro computers to estimate intake manifold pressures in real time. The calculation method is also applicable to multi-cylinder engines with individual throttle bodies since the engines can be equated with parallelization of the single-cylinder engines. In this paper, we illustrate the intake air dynamics, describe a method to estimate the intake manifold pressures, and show experimental results of the method.

A commercial three-way catalyst (TWC) was evaluated for ammonia (NH3) generation on a 2.0-liter BMW lean burn gasoline direct injection engine as a component in a passive ammonia selective catalytic reduction (SCR) system. The passive NH3 SCR system is a potential low cost approach for controlling nitrogen oxides (NOX) emissions from lean burn gasoline engines. In this system, NH3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean, NOX passes through the TWC and is reduced by the stored NH3 on the SCR catalyst. NH3 generation was evaluated at different air-fuel equivalence ratios at multiple engine speed and load conditions. Near complete conversion of NOX to NH3 was achieved at λ=0.96 for nearly all conditions studied. At the λ=0.96 condition, HC emissions were relatively minimal, but CO emissions were significant.

The rotary engine provides high power density compared to piston engine, but one of its downside is higher oil consumption. A model of the oil seals is developed to calculate internal oil consumption (oil leakage from the crankcase through the oil seals) as a function of engine geometry and operating conditions. The deformation of the oil seals trying to conform to housing distortion is calculated to balance spring force, O-ring and groove friction, and asperity contact and hydrodynamic pressure at the interface. A control volume approach is used to track the oil over a cycle on the seals, the rotor and the housing as the seals are moving following the eccentric rotation of the rotor. The dominant cause of internal oil consumption is the non-conformability of the oil seals to the housing distortion generating net outward scraping, particularly next to the intake and exhaust port where the housing distortion valleys are deep and narrow.